New Methods for the Synthesis of Highly Fluorescently Substituted Heterocyclic Boranils: Structural Identification and Photophysical Properties DOI Creative Commons
Soumaya Agren, Jamal El Haskouri, Emmanuel Beyou

et al.

Applied Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 39(3)

Published: Feb. 17, 2025

ABSTRACT We report the synthesis, structural, thermal, and photophysical properties of six boranils ((A‐F)‐BF2). Compounds (A‐C)‐BF2 were synthesized at low temperature, while nitro pyridine derivatives obtained 80°C with yields up to 66%. Tert‐butyl chloro‐substituted showed thermal stability 300 °C. All fluorescent, tuned by phenyl substitution boron difluoride complexation. The lowest energetic gap (2.210 eV) was found in (D‐BF2), which exhibited a remarkable red‐shift absorption emission due charge transfer between donor acceptor groups. This work is part ongoing studies on metal cation detection photocatalysis.

Language: Английский

Insights into antimicrobial potential of functionalized thiazoles: In vitro and in silico analysis DOI
Hamid Aziz

Journal of Molecular Liquids, Journal Year: 2025, Volume and Issue: unknown, P. 127064 - 127064

Published: Feb. 1, 2025

Language: Английский

Citations

1
New Methods for the Synthesis of Highly Fluorescently Substituted Heterocyclic Boranils: Structural Identification and Photophysical Properties DOI Creative Commons
Soumaya Agren, Jamal El Haskouri, Emmanuel Beyou

et al.

Applied Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 39(3)

Published: Feb. 17, 2025

ABSTRACT We report the synthesis, structural, thermal, and photophysical properties of six boranils ((A‐F)‐BF2). Compounds (A‐C)‐BF2 were synthesized at low temperature, while nitro pyridine derivatives obtained 80°C with yields up to 66%. Tert‐butyl chloro‐substituted showed thermal stability 300 °C. All fluorescent, tuned by phenyl substitution boron difluoride complexation. The lowest energetic gap (2.210 eV) was found in (D‐BF2), which exhibited a remarkable red‐shift absorption emission due charge transfer between donor acceptor groups. This work is part ongoing studies on metal cation detection photocatalysis.

Language: Английский

Citations

1