Comprehensive thermal properties, kinetic, and thermodynamic analyses of biomass waste pyrolysis via TGA and coats-redfern methodologies

Energy Conversion and Management X, Journal Year: 2024, Volume and Issue: unknown, P. 100723 - 100723

Published: Sept. 1, 2024

Language: Английский

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Pyrolysis kinetics, reaction mechanisms, and thermodynamic parameter analysis of teff straw as a bioenergy potential resource in Ethiopia

Biomass Conversion and Biorefinery, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 13, 2025

Language: Английский

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Catalytic co-pyrolysis of PET/PP plastics and olive pomace biomass with marble sludge catalyst

Turkish Journal of Analytical Chemistry, Journal Year: 2025, Volume and Issue: 7(1), P. 33 - 45

Published: Jan. 31, 2025

Sustainable and efficient waste management requires involvement of symbiotic solutions to various types wastes, so achieve circular economy. Through this motivation, in study, combined thermochemical conversion (pyrolysis) plastics, biomass marble processing effluents physicochemical treatment sludge (K1) were studied. In combination, plastics petroleum-based synthetic aromatic (PET) aliphatic (PP) organics, while olive pomace-OP was natural agricultural residue. K1 mineral product, which first introduced the literature as pyrolysis catalyst by authors. co-pyrolysis polymers catalyzed containing CaCO3. The effect plastic type pyrolyzed material mixture ratio on fractions investigated. Moreover, recovery potential from discussed. catalytic co-pyrolysis, increasing mixture, pyrolytic liquid oligomer fraction increased solid (char) gas decreased. For 70%PP+15%OP+15%K1 product dominant, whereas with 60%PET+20%OP+20%K1 much more produced. thermal degradation char products did not exceed 2-3% up 600°C stability continues approximately 700°C reveals be used alternative areas a high resistance. contain alkanes, alkenes, acids, phenols, benzene, aldehydes, esters, alcohols, ketones. Benzene, acid alcohol groups dominant liquids, alkane, alkene alkyne gases.

Language: Английский

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Pyrolysis kinetics, thermodynamics, and reaction performance of wheat straw and water hyacinth using TGA‐DTG analysis: Bioenergy potential in Ethiopia

Biofuels Bioproducts and Biorefining, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 2, 2025

Abstract The kinetics and thermodynamics of biomass pyrolysis are crucial for its design, optimization, industrial application. In this study, proximate analysis, together with higher heating value (HHV) kinetic thermodynamic studies water hyacinth (WH) wheat straw (WS) were performed. Nonisothermal thermogravimetric analysis (TGA) at rates 15, 20, 25 °C min −1 employed to investigate their experimentally. Detailed results from the HHV measurements both biomasses documented analyzed. Iso‐conversional revealed that effective activation energy varied significantly reacted fraction. For WS, average values 63.67 kJ mol 45.74 based on Flynn–Wall–Ozawa (FWO) Kissinger–Akahira–Sunose (KAS) methods, respectively. WH, corresponding 118.58 114.09 . Coats–Redfern model demonstrated TGA data obtained in an inert environment best described by a second‐order reaction mechanism ‘D3c’ three‐way diffusion model. Thermodynamic indicated WH WS is not spontaneous requires external input thermal decomposition. Both processes identified as endothermic, reactivity increasing advanced. comprehensive index (CPI) increased rates, suggesting elevated more favorable these biomasses. These findings contribute better understanding mechanisms highlight potential bioenergy production.

Language: Английский

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Conversion of lignin with polystyrene into high-value aromatics through co-pyrolysis and post-plasma refining

Energy, Journal Year: 2025, Volume and Issue: unknown, P. 134893 - 134893

Published: Feb. 1, 2025

Language: Английский

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Utilization of co-substrates in municipal sewage sludge co-pyrolysis: yields and characterization of biochar, bio-oil, and syngas, with economic feasibility analysis

Journal of Analytical and Applied Pyrolysis, Journal Year: 2025, Volume and Issue: unknown, P. 107091 - 107091

Published: March 1, 2025

Language: Английский

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Pyrolysis depolymerization of fresh natural rubber into liquid medium-chain bio-hydrocarbon products: Investigation of volatile-state kinetics approach and mechanism reaction analysis

Biomass and Bioenergy, Journal Year: 2025, Volume and Issue: 197, P. 107840 - 107840

Published: April 3, 2025

Language: Английский

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Utilization of stone apple seed biomass and discarded X-ray film blend for kinetic and thermodynamic attribute analysis for efficient energy refinery

Biomass Conversion and Biorefinery, Journal Year: 2025, Volume and Issue: unknown

Published: April 4, 2025

Language: Английский

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Impact of CO2 on the Pyrolysis of Mixed Polymer Wastes into Combustible Fuel: A Case Study for Footwear Waste

Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: 183, P. 106810 - 106810

Published: Oct. 1, 2024

Language: Английский

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Thermogravimetric Assessment of Biomass: Unravelling Kinetic, Chemical Composition and Combustion Profiles

Fire, Journal Year: 2024, Volume and Issue: 7(11), P. 396 - 396

Published: Oct. 31, 2024

Thermogravimetric analysis (TGA) was performed on six samples of pine wood, poplar sawdust and olive residue, the kinetic parameters were evaluated by using isoconversional models. The hemicellulose, cellulose lignin contents also estimated Fraser–Suzuki deconvolution method. In addition, a range thermodynamic combustion indices calculated. Significant correlations found between kinetic, parameters. ignition index showed an inverse relationship with activation energy, whereas burnout correlated enthalpy values for most samples. Higher heating rates during TGA increased efficiencies but decreased stability. Differences in behaviour detected residues, which had much higher content (51.2–56.9%), woody biomass (24.2–29.2%). Moreover, sample highest ash exhibited some distinctive characteristics, including lowest high value index, coupled indicating less favourable than other particle size to be critical both efficiency safety.

Language: Английский

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