Unlocking the Role of the Bifacial Dipole of the Interlayer for High-Performance Perovskite Photovoltaics DOI
C. J. Fang,

Shiqi Shan,

Jiajun Wang

et al.

ACS Energy Letters, Journal Year: 2024, Volume and Issue: unknown, P. 78 - 84

Published: Dec. 12, 2024

An interlayer with a suitable dipole moment can effectively tune the energy structure of high-performance perovskite solar cells (PVSCs). Beyond electrode–interlayer interface, an additional layer also forms and influences interfacial band bending, which has been neglected at bottom interface. In this study, we access issue by employing amine- ammonium-containing polyelectrolytes to modify CsPbI2Br-based PVSC interfaces. The amine ammonium groups induce different orientations due their chemical bonds or substrate. We find that device performance is actually determined net across bifacial sides rather than any individual one. This validates significance formed between By precisely controlling these dipoles, achieved 17.6% efficiency, represents one best among PVSCs. work highlights importance dipoles offers insights into working mechanism interlayers for

Language: Английский

Development of lead-free perovskite solar cells: Opportunities, challenges, and future technologies DOI Creative Commons

Asir Eliet Magdalin,

P Nixon, Elangovan Jayaseelan

et al.

Results in Engineering, Journal Year: 2023, Volume and Issue: 20, P. 101438 - 101438

Published: Sept. 24, 2023

Despite notable advantages and power conversion efficiency achieved by perovskite solar cells (PSCs), they could not hit the market commercially as are bottlenecked toxicity issue caused metal lead. Lead has proven issues that can harm human beings ecological system to a significant extent. And so, researchers around world have started diving deep into revolutionary sustainable photovoltaics called non-toxic lead-free PSCs for safe environment. This is substitution of lead in with or less toxic substitute metals. review article revolves metals such tin (Sn), germanium (Ge), titanium (Ti), silver (Ag), bismuth (Bi) copper (Cu) their properties, sustainability challenges. also discusses ways undertaken overcome stability efficiency-related challenges encountered commercialization alteration fabrication methods introduction additives. Finally, recent advancements/technologies used predicts future perspective/technologies futuristic applications be implemented PSCs.

Language: Английский

Citations

55
A review of chalcogenide-based perovskites as the next novel materials: Solar cell and optoelectronic applications, catalysis and future perspectives DOI
George G. Njema, Joshua K. Kibet

Next Nanotechnology, Journal Year: 2024, Volume and Issue: 7, P. 100102 - 100102

Published: Sept. 11, 2024

Language: Английский

Citations

21
Recent Progress and Advances of Perovskite Crystallization in Carbon‐Based Printable Mesoscopic Solar Cells DOI Open Access
Junwei Xiang,

Chuanzhou Han,

Yanjie Cheng

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 15, 2025

Carbon-based printable mesoscopic solar cells (p-MPSCs) offer significant advantages for industrialization due to their simple fabrication process, low cost, and scalability. Recently, the certified power conversion efficiency of p-MPSCs has exceeded 22%, drawing considerable attention from community. However, key challenge in improving device performance is achieving uniform high-quality perovskite crystallization within mesoporous structure. This review highlights recent advancements p-MPSCs, with an emphasis on controlling kinetics regulating morphology confined mesopores. It first introduces offering a solid foundation understanding behavior. Additionally, summarizes mechanisms crystal nucleation growth, explaining how these processes influence quality perovskites. Furthermore, commonly applied strategies enhancing quality, such as additive engineering, solvent evaporation controlling, post-treatment techniques, are also explored. Finally, proposes several potential suggestions aimed at further refining crystallization, inspiring continued innovation address current limitations advance development p-MPSCs.

Language: Английский

Citations

2
Modeling lead-free double absorber perovskites CsSn0.5Ge0.5I3 and (FA)2BiCuI6 for efficient PSCs DOI
Nishi Bala,

Sanjeev Kumar Mallik

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 113953 - 113953

Published: Jan. 1, 2025

Citations

1
Challenges in Controlling the Crystallization Pathways and Kinetics for Highly Reproducible Solution-Processing of Metal Halide Perovskites DOI
Inchan Hwang

The Journal of Physical Chemistry C, Journal Year: 2023, Volume and Issue: 127(50), P. 24011 - 24026

Published: Dec. 11, 2023

Successful and reproducible conversion toward metal halide perovskites from the corresponding precursors through solution processing necessitates a comprehensive understanding of crystallization pathways kinetics. On contrary to straightforward preparation achieved by simply blending in solution, molecular complexations leading variety iodoplumbate species occur at early stages within each which dictates initial following distinct routes. Here, we first provide an overview preceding studies on coordination chemistry governing formation complexes, controlled excess iodide ions solvents choices. The environmental factors such as light illumination thermal annealing precursor solutions are also responsible for modulations equilibria. Following discussion relationship between structure complexes final crystal structures morphologies perovskites, with specific attention role monovalent cations, shift our focus interaction complexity determining stability intermediate is key fabrication high-quality perovskite films. Meticulous control conditions during every step completion highlighted perovskites. We believe that this Perspective will guidance general approach solution-processing throughout all stages, emphasizing precautions based delicately influencing crystallization.

Language: Английский

Citations

13
Anti-solvent engineering enables efficient ambient-processed halide perovskite solar cells DOI Creative Commons
Ivy M. Asuo, Arezo Mahdavi Varposhti, Enrique D. Gomez

et al.

Journal of Materials Chemistry C, Journal Year: 2024, Volume and Issue: 12(21), P. 7562 - 7571

Published: Jan. 1, 2024

Ambient solution-processed halide perovskite thin films are susceptible to oxygen and moisture. Composition morphology control of the via anti-solvents treatment, i.e. , DCB, EtOH, CB affect their crystallization solar cell performance.

Language: Английский

Citations

5
Fabricating Planar Perovskite Solar Cells through a Greener Approach DOI Creative Commons
Sajid Sajid, Salem Alzahmi, Nouar Tabet

et al.

Nanomaterials, Journal Year: 2024, Volume and Issue: 14(7), P. 594 - 594

Published: March 28, 2024

High-quality perovskite thin films are typically produced via solvent engineering, which results in efficient solar cells (PSCs). Nevertheless, the use of hazardous solvents like precursor (N-Methyl-2-pyrrolidone (NMP), dimethyl sulfoxide (DMSO), dimethylformamide (DMF), gamma-butyrolactone (GBL)) and antisolvents (chlorobenzene (CB), dibutyl ether (DEE), diethyl (Et2O), etc.) is crucial to preparation solutions control film crystallization. The consumption poses an imminent threat both health manufacturers environment. Consequently, before PSCs commercialized, current concerns about toxicity must be addressed. In this study, we fabricated highly planar using a novel, environmentally friendly method. Initially, employed greener engineering approach that substituted with called triethyl phosphate (TEP). following stage, without antisolvent by employing two-step procedure. Of all techniques used fabricate PSCs, FTO/SnO2/MAFAPbI3/spiro-OMeTAD device configuration yielded highest PCE 20.98%. Therefore, work addresses fabrication procedure provides promising universal method for producing high efficiency. aforementioned might allow PSC on industrial scale future under sustainable conditions.

Language: Английский

Citations

4
Tailoring Wetting Properties of Organic Hole‐Transport Interlayers for Slot‐Die‐Coated Perovskite Solar Modules DOI
Thai Son Le, Irina A. Chuyko, Lev Luchnikov

et al.

Solar RRL, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 29, 2024

The strategy of incorporating self‐assembled monolayers (SAMs) with anchoring groups is an effective and promising method for interface engineering in perovskite solar cells metal oxide charge‐transporting layers. However, coating SAM layers upscaled modules (PSMs) using slot‐die challenging due to the low viscosity wettability solutions. In this study, a triphenylamine‐based polymer poly([{5‐[4‐(diphenylamino)phenyl]‐2‐thienyl}(4‐fluorophenyl)methylene]malononitrile) (pTPA)–TDP, blended based on 5‐[4‐[4‐(diphenylamino)phenyl]thiophene‐2‐carboxylic acid, integrated address these challenges. And, p– i –n‐oriented PSMs 50 × mm 2 substrates (12 sub‐cells) are fabricated NiO hole‐transport layer organic interlayers surface modification. Wetting angle mapping shows that ununiform regions slot‐die‐coated has extreme hydrophobicity, causing absorber thickness fluctuations macro‐defects at buried interfaces. interlayer NiO/perovskite junction homogenizes mitigates lattice strain, enabling use properties large surfaces. This improved energy level alignment, enhancing power conversion efficiency from 13.98% 15.83% stability (ISOS‐L‐2, T 80 period) 500 1630 h. results, complex effects slot‐die‐coating technology large‐scale photovoltaics highlighted.

Language: Английский

Citations

4
Comprehensive Review on Slot‐Die‐Based Perovskite Photovoltaics: Mechanisms, Materials, Methods, and Marketability DOI Creative Commons
Ko Ko Shin Thant, Chaowaphat Seriwattanachai,

Thantham Jittham

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 5, 2024

Abstract As the world edges closer to perovskite solar cell (PSC) commercialization, state‐of‐the‐art materials and processes become publicized a much lesser degree. From current insights into industry standards, slot‐die coating is number one method for fabricating layer. Other significant layers can be done using varying techniques. Hence, in this review article, all 115 existing slot‐die‐based PSC publications date together with related literature are crystallized set stages future scalable research. Through investigation of effects materials, processes, structures on performance, stability, cost presented. In end, power output x operating lifetime per most influential factor market consideration. The roll‐to‐roll compatibility low‐cost lean present cost‐effective strategy successful commercialization.

Language: Английский

Citations

4
Investigating the effects of a high boiling point solvent in slot die‐coated halide perovskite solar cells DOI Open Access
Sung Joon Park,

J. Eng,

Shreyas Dinesh Pethe

et al.

ChemSusChem, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 31, 2025

To commercialize perovskite solar cells and advance beyond lab-scale comparisons, understanding large-area film formation using slot-die coating is essential to improve homogeneity. Adding high-boiling-point solvents like N-methyl-2-Pyrrolidone (NMP) the ink extends film's processing window, but effects of varying NMP levels on gas-quenched coatings remain unclear. This article examines how different ratios impact quality, showing that a moderate amount as co-solvent reduces defects, observed through photoluminescence, hyperspectral absorbance, back-illuminated optical absorptions. However, decreased vapor pressure with addition impairs crystallization coverage, highlighting need for balanced amounts. X-ray diffraction (XRD) scanning electron microscopy (SEM) analysis indicate most volatile option tested at Dimethylformamide (DMF) : ratio 8 1 yields homogeneous compact films. Slot-die-coated devices fabricated this optimized were subsequently compared an additive increase volatility inks further. The method demonstrates improved performance uniformity, suggesting minimizing maintain supports effective fabrication cells. Furthermore, provides insights important metrics narrow down suitable coatings.

Language: Английский

Citations

0