Evidence of Oxidative Stress as a Mechanism of Pharmaceutical-Induced Toxicity in Amphibians DOI Creative Commons

Jesús Daniel Cardoso-Vera,

Hariz Islas‐Flores, Itzayana Pérez-Álvarez

et al.

Antioxidants, Journal Year: 2024, Volume and Issue: 13(11), P. 1399 - 1399

Published: Nov. 15, 2024

Amphibians, which are essential components of ecosystems, susceptible to pharmaceutical contamination, a phenomenon increasing concern owing the widespread consumption and detection compounds in environmental matrices. This review investigates oxidative stress (OS) as primary mechanism drug toxicity these organisms. The evidence gathered reveals that various pharmaceuticals, from antibiotics anesthetics, induce OS by altering biomarkers damage antioxidant defense. These findings underscore deleterious effects pharmaceuticals on amphibian health development emphasize necessity incorporating into ecotoxicological risk assessments. Although further studies diverse species, mixtures, field required, offer valuable tools for identifying sublethal risks. Furthermore, more refined will facilitate early adverse effects, crucial protecting amphibians their ecosystems. Ultimately, this calls continued research mitigation strategies safeguard biodiversity contamination.

Language: Английский

Magnetic Graphene based materials for removal of pharmaceutical compounds – Review on applications and machine learning approaches DOI

Sankar Sudharsan Rameshwar,

Natarajan Rajamohan

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: 1328, P. 141309 - 141309

Published: Jan. 1, 2025

Language: Английский

Citations

0

Theoretical exploration of fullerene-based X-Y@C80 (X = in, Sb, Te) nanomaterials as sensors for Thioguanine DOI
Idongesit J. Mbonu,

Peter O. Ajala,

Chidiogo Rita Okonkwo

et al.

Diamond and Related Materials, Journal Year: 2025, Volume and Issue: unknown, P. 112012 - 112012

Published: Feb. 1, 2025

Language: Английский

Citations

0

Immobilization of Phospholipase D on Fe3O4@SiO2-Graphene Oxide Nanocomposites: A Strategy to Improve Catalytic Stability and Reusability in the Efficient Production of Phosphatidylserine DOI Creative Commons
Huiyi Shang,

Juntan Wang,

Bishan Guo

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(4), P. 912 - 912

Published: Feb. 16, 2025

Phospholipase D (PLD) plays a pivotal role in the biosynthesis of phosphatidylserine (PS), but its practical application is constrained by limitations stability and reusability. In this study, we successfully fabricated Fe3O4@SiO2-graphene oxide (GO) nanocomposite chemical binding Fe3O4@SiO2 GO. Subsequently, PLD was immobilized onto via physical adsorption, with aim enhancing catalytic stability, reducing mass transfer resistance, improving Under optimal conditions, immobilization efficiency reached 84.4%, loading capacity 111.4 mg/gsupport. The pH for PS production shifted from 6.0 to 6.5, while temperature increased 45 °C 50 °C. Notably, demonstrated shorter reaction time higher yield, achieving 95.4% yield within 90 min, compared free (78.1% 150 min), representing 1.04-fold improvement efficiency. Furthermore, exhibited outstanding storage thermal along remarkable Even after being reused 10 cycles, still stays as high 78.3%. These findings strongly suggest that Fe3O4@SiO2-GO has potential efficient PS.

Language: Английский

Citations

0

Pineapple leaf-derived TEMPO-oxidized cellulose nanospheres and graphene oxide composite: a green solution for ciprofloxacin adsorption DOI
Nhung T. T. Nguyen,

Minh-Anh Phan-Huynh,

Khoa Le Anh

et al.

Cellulose, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 26, 2025

Language: Английский

Citations

0

Design, synthesis, and optimization of a novel ternary photocatalyst for degradation of cephalexin antibiotic in aqueous solutions DOI Creative Commons

Zeynab Abdeyazdan,

Mohammad Rahmati,

Arjomand Mehrabani‐Zeinabad

et al.

Scientific Reports, Journal Year: 2025, Volume and Issue: 15(1)

Published: March 14, 2025

Language: Английский

Citations

0

Multifunctional Magnetic Nanoparticles in Water and Wastewater Treatment DOI
Emiliano F. Fiorentini, Eliana S. Lemos, Estefanía B. Ingrassia

et al.

Royal Society of Chemistry eBooks, Journal Year: 2025, Volume and Issue: unknown, P. 244 - 272

Published: May 7, 2025

Currently, scientists worldwide are facing the challenge of solving problem water pollution. Pollutants coming mainly from industrial activity, including toxic metals, dyes and antibiotics, reach bodies, resulting in their contamination. In this context, environmental remediation is key to preserving environment, for which various technologies have been used over years, present drawbacks based on times, efficiencies costs. recent development nanomaterials applied treatment has allowed resolving limitations conventional technologies. Among them, use magnetic nanoparticles highlighted easy manipulation, thanks intrinsic magnetism, especially those formed by metal oxides. The tendency oxides agglomerate resolved through surface modification chemical functionalization, turn allows removal specific analytes selective interactions with certain functional groups. Based above, book chapter proposes a review most advances (2020–2023) functionalized metals organic compounds wastewater samples. Different parameters discussed, us understand processes, along capacity reuse, synthesis characterization, addressing current challenges future perspectives.

Language: Английский

Citations

0

Graphene oxide nanocellulose composite as a highly efficient substrate-free room temperature gas sensor DOI Creative Commons
Manel Azlouk, Mohamed A. Basyooni, Yasin Ramazan Eker

et al.

Results in Engineering, Journal Year: 2024, Volume and Issue: 22, P. 102228 - 102228

Published: May 9, 2024

This study introduces the development of novel, flexible gas sensors operating at room temperature (RT), utilizing a graphene oxide (GO) via modified Hummers method and bacterial nanocellulose (BNC) composite to enhance detection in industrial environmental settings. The materials, denoted as GO@BNC, were synthesized with varying GO concentrations ranging from 2 % 30 %, aiming investigate their responsiveness gases such carbon dioxide (CO2), oxygen (O2), acetone (Ac), ethanol (Eth). prepared nanomaterials characterized using FT-IR, Raman, TGA, SEM, AFM techniques. bandgap Go ranges 4.19, 3.47, 3.16, 2.79, 2.48 eV for 2, 5, 10, 20, concentrations, respectively. Notably, sensor containing wt 20 concentration exhibited remarkable sensitivity Ac, achieving 270 increase resistance 250 μL/L. Conversely, 30% composition showed superior Eth, 420% signal enhancement under similar conditions. Further modification GO@BNC through mild reduction resulted formation reduced (rGO@BNC) composites intended assess functional groups' impact on sensing performance. Our findings underscore potential sustainable efficient materials fabricating eco-friendly devices detecting organic compounds.

Language: Английский

Citations

3

Polymer-assisted synthesis of ternary magnetic graphene oxide nanocomposite for the adsorptive removal of Cr(VI) and Pb(II) ions DOI Creative Commons

Qaisar Manzoor,

Muhammad Akhyar Farrukh, Muhammad Tahir ul Qamar

et al.

Heliyon, Journal Year: 2024, Volume and Issue: 10(15), P. e35204 - e35204

Published: July 26, 2024

The presence of chromium [Cr(VI)] and lead [Pb(II)] ions in the water bodies have adverse effects on humans aquatic life. Graphene oxide-based magnetic nanocomposites synthesized chitosan (mGO/CS) or polyaniline (mGO/PA) as potential adsorbents for removal Cr(VI) Pb(II) ions. FTIR (Fourier transform infrared spectroscopy), EDX (Energy dispersive X-ray), XRD (X-ray diffraction) SEM (Scanning electron microscopy) were employed to investigate chemical composition, structural, elemental analysis, crystalline size morphology nanocomposites. results confirmed synthesis by detecting peaks specific functional groups. average crystallite sizes mGO, mGO/CS, mGO/PA 17, 25, 23 (nm), respectively, determined Debye-Scherrer equation from data. Batch adsorption experiments conducted varying variables like pH, concentration metal contact time. Box Behnken design (BBD) was used optimize parameters. Under optimum conditions, mGO/CS showed maximum percentages (%R) 92.36 98.7 Pb(II), 85.25 93.08 Cr(VI), respectively. capacities 110.84 118.44 mg/g 87.74 111.7 obtained mGO/PA, pseudo-second-order kinetic model Langmuir isotherm fitted well experimental data explain mechanism nanocomposite materials both

Language: Английский

Citations

3

Study of controlled pulsed illumination (CPI) efficiency in the homogeneous UV-LED/S2O82− process for the removal of organic dye from contaminated water DOI Creative Commons

Ismael Hajimiri,

Mohammad Hossein Rasoulifard, Mir Saeed Seyed Dorraji

et al.

Results in Engineering, Journal Year: 2024, Volume and Issue: 21, P. 101792 - 101792

Published: Jan. 15, 2024

The present investigation aims to shed light on the efficiency of irradiation-based advanced oxidation processes using controlled pulsed illumination (CPI) in a homogeneous process. A more in-depth emphasis has been applied considering ultraviolet-light emitting diodes/persulfate (LED/S2O82−) system. Irradiation-driven can unexpected behaviour under irradiation compered continuous irradiation. This be explained by Parrando's paradox concept. removal organic dyes source was compared CPI system employing UV-LED/S2O82− photoreactor explore performance. UV-LED/PS method investigated three as model pollutants and duty cycle pulse period parameters source. have crucial impact efficiencies, which were studied values 10 %, 25 50 75 90 99 % for periods from 1 ms (ms) few hundred current study. For all experiments, electrical energy consumption (EEO) calculated, values. According results, cycles (10 800 ms), with EEO amounts 58.29, 120.65, 29.62 kWh per order showed best performance dyes, respect other experiments terms saving energy. Besides, game theory collision hypothesis scrutinized justify achieved results.

Language: Английский

Citations

2

Removal of Cephalexin-Antibiotic from Drinking Water by Designing CaCl2 Incorporated Chitosan Co- Tragacanth Gum Composite Hydrogel DOI Creative Commons

Sundas Noureen,

Safia Safia,

Fatima Javed

et al.

Journal of Health and Rehabilitation Research, Journal Year: 2024, Volume and Issue: 4(1), P. 1442 - 1449

Published: March 21, 2024

Background: The prevalence of antibiotic contaminants in aquatic environments presents a critical challenge to public health, necessitating the development efficient removal methods. Emerging pollutants, especially antibiotics, have been implicated rise antibiotic-resistant bacteria, threatening ecological balance and human well-being. Objective: This study aims synthesize evaluate efficacy CaCl2-based composite hydrogel using chitosan as biopolymer for adsorption pollutants from water, targeting improvement water purification technologies healthcare settings. Methods: Chitosan-based hydrogels were synthesized via free radical polymerization, incorporating CaCl2 utilizing techniques such Field Emission Scanning Electron Microscopy (FESEM) morphology analysis, Energy-dispersive X-ray (EDX) analysis elemental verification, Fourier-transform infrared spectroscopy (FTIR) functional group identification, diffraction (XRD) determine crystallinity. Physicochemical parameters, including contact time, pH, temperature, reusability, swelling behavior various media, systematically assessed ascertain hydrogel's adsorptive performance. Results: demonstrated porous rough surface ideal adsorption, with an initial rate 80% within 30 minutes time. FTIR confirmed presence groups corresponding absorption bands at 1053, 1415, 1601, 2600, 2900, 3300, 3500 cm-1. EDX XRD analyses affirmed incorporation CaCl2, crystalline phase characterized by sharp peaks. maximum efficiency reached 95% optimized adsorbent dose 0.05 g. Conclusion: exhibits significant potential suggesting viable approach mitigate environmental impact pharmaceutical enhance health reducing spread resistance.

Language: Английский

Citations

1