Applied Physics A, Journal Year: 2024, Volume and Issue: 130(12)
Published: Nov. 15, 2024
Language: Английский
Applied Physics A, Journal Year: 2024, Volume and Issue: 130(12)
Published: Nov. 15, 2024
Language: Английский
Results in Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 104151 - 104151
Published: Jan. 1, 2025
Language: Английский
Citations
1Results in Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 103960 - 103960
Published: Jan. 1, 2025
Language: Английский
Citations
0Electrochemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 107874 - 107874
Published: Jan. 1, 2025
Citations
0Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114393 - 114393
Published: March 1, 2025
Language: Английский
Citations
0Applied Physics Letters, Journal Year: 2025, Volume and Issue: 126(13)
Published: March 1, 2025
Enhancing the energy density of flexible asymmetric supercapacitors (ASCs) necessitates developing and implementing high-performance anode materials for technological developments in wearable storage systems. Tungsten nitride (W2N) offers enormous potential as an material ASCs, ascribed to its substantial specific capacitance, massive electrical conductivity, extended negative window. In this work, we fabricated a durable coin cell ASC utilizing W2N/SSM fibrous nanograins TiN/SSM nanopyramids cathode, both deposited over stainless steel mesh (SSM) substrate using DC magnetron sputtering technique. The W2N/SSM//TiN/SSM device demonstrates high areal capacitance 21.3 mF cm−2, operating across wide stable electrochemical voltage window 1.3 V, with outstanding cycling robustness, demonstrating 89.09% retention 8000 charge–discharge cycles. Notably, achieved 34.33 mWh.cm−3 power 17.32 W.cm−3. persistent performance is mainly attributed dominance surface-controlled capacitive pseudocapacitive charge kinetics Na+ ions, comprehensively examined employing 3D Bode Dunn's techniques. shows remarkable mechanical stability 92.36% 500 bending This study establishes W2N high-energy material, revealing capability increase effectiveness portable miniaturized devices.
Language: Английский
Citations
0Langmuir, Journal Year: 2025, Volume and Issue: unknown
Published: April 8, 2025
The presence of slit nanopores in MXene materials inevitably influences the electrochemical performance supercapacitor electrodes. However, most studies focus on experimental approaches, lacking microscopic-scale analysis. Here, we performed molecular dynamics (MD) simulations to thoroughly analyze and predict ion transport pathways energy storage mechanisms MXene/ionic liquid (IL) supercapacitors with ultradeep nanopores. simulation results indicate that during charging process, counterions migrate from bulk region into electrode pores, forming a counterion layer near surface, while some co-ions gradually exit pores. When is completed, distinct layering structure emerges. As interlayer spacing varies, distribution pores exhibits regional characteristics: ordered region, stable electrical double-layer (EDL) maintained, whereas deeper mixed persistent co-ion significant disorder are observed. Dominated by total variation decreases as decreases, changes 8526.52, 7443.52, 6640.99 kJ·mol-1 at spacings 1.2, 1.0, 0.8 nm, respectively, representing reductions approximately 12.7 22.1% compared 1.2 nm. In after compensating for interaction between counterions, contribution increases decreasing spacing, reaching 123, 153, 176% respectively. An increasing amount offset interactions related co-ions, ultimately leading observed differences. These findings offer new insights impact nanopore provide theoretical guidance optimizing design.
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1010, P. 177459 - 177459
Published: Nov. 7, 2024
Language: Английский
Citations
2Inorganic Chemistry Communications, Journal Year: 2024, Volume and Issue: unknown, P. 113691 - 113691
Published: Dec. 1, 2024
Language: Английский
Citations
2Case Studies in Chemical and Environmental Engineering, Journal Year: 2024, Volume and Issue: unknown, P. 101042 - 101042
Published: Dec. 1, 2024
Citations
2Gels, Journal Year: 2024, Volume and Issue: 10(12), P. 803 - 803
Published: Dec. 6, 2024
Flexible solid-state-based supercapacitors are in demand for the soft components used electronics. The increased attention paid toward solid-state electrolytes could be due to their advantages, including no leakage, special separators, and improved safety. Gel polymer (GPEs) preferred energy storage field, likely owing safety, lack of compatibility with various separators as well higher ionic conductivity (IC) than traditional solid electrolytes. This review covers classification, properties, configurations different GPE-based recent advancements that have occurred this area storage. Ionic liquid (IL)-based materials popular GPEs electrochemical can prepare unprecedented flexible great IC wide potential range. A comparative assessment GPEs-based reveals a majority them, value specific capacitance is generally under 1000 F g−1, density reaches around 125 Wh kg−1, power seen less 1500 W kg−1. results research serve an essential reference upcoming scholars, significantly improve our comprehension efficacy GPE-containing supercapacitors.
Language: Английский
Citations
2