Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 683, P. 546 - 554
Published: Dec. 26, 2024
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 683, P. 546 - 554
Published: Dec. 26, 2024
Language: Английский
Surfaces and Interfaces, Journal Year: 2024, Volume and Issue: 54, P. 105009 - 105009
Published: Sept. 1, 2024
Language: Английский
Citations
5Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 158655 - 158655
Published: Dec. 1, 2024
Language: Английский
Citations
5Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 359, P. 130797 - 130797
Published: Nov. 26, 2024
Language: Английский
Citations
4Next Materials, Journal Year: 2025, Volume and Issue: 6, P. 100503 - 100503
Published: Jan. 1, 2025
Language: Английский
Citations
0Small, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 31, 2025
Chemocatalytic synthesis of lactic acid (LA) from biomass sugars involves heat-absorbing multistep cascade reactions mediated by different active sites, often encountering unsatisfactory selectivity. Here, a hole-localized carbon nitride-based photocatalyst (C-CNN) is constructed covalent binding heptazine and triazole skeleton via C─N bonds further conjugated interaction with activated carbon, achieving the complete conversion various to LA (up 98.6% selectivity) at room temperature for 2 h. The introduced electron donor in C-CNN can not only enhance adsorption sugar enhanced aldose-to-ketose isomerization over localized hole (Lewis acid) on skeleton, but also modulate valence band oxidation circumvent formation •OH •O2 ‒ selective C3‒C4 cleavage ketose, thus realizing exclusive LA. Moreover, near-infrared light absorption endowed supply sufficient interface photothermal effect ambient production. Life cycle assessment shows that photocatalytic system has good prospects industrialization terms both energy environment. This work offers novel insights into multidirectional utilization solar value-added through rational modulation sites.
Language: Английский
Citations
0Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 115802 - 115802
Published: Feb. 1, 2025
Language: Английский
Citations
0Small, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 18, 2025
Abstract Utilizing polymeric catalysts to generate hydrogen peroxide (H 2 O ) via photocatalysis for various industrial applications is a promising avenue, but the application potential constrained by their low charge separation efficiency and capacity oxygen adsorption activation. Herein, catalyst (NiRF) modified with Ni metal sites on resorcinol‐formaldehyde (RF) resin presented, which can efficiently produce H through in pure water. The optimal NiRF‐5 exhibits an impressive generation rate of up 31.75 m g −1 h under visible light irradiation, significantly outperforming most reported date. Experimental results coupled theoretical calculations simulation, indicate that incorporation nickel ions modulates band structure NiRF provides active conducive transformation oxygen. regulate ensure suitable configuration energy. This work novel design concept RF‐based photocatalysts offers approach development methods efficient photocatalytic production .
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132523 - 132523
Published: March 1, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162184 - 162184
Published: April 1, 2025
Language: Английский
Citations
0Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 116745 - 116745
Published: April 1, 2025
Language: Английский
Citations
0