Breaking through Electrospinning Limitations: Liquid-Assisted Ultrahigh-Speed Production of Polyacrylonitrile Nanofibers DOI Creative Commons

John Schossig,

Qiangjun Hao,

Tyler Davide

et al.

ACS Applied Engineering Materials, Journal Year: 2024, Volume and Issue: 2(12), P. 2970 - 2983

Published: Dec. 3, 2024

Carbon-based nanofibers are critical materials with broad applications in industries such as energy, filtration, and biomedical devices. Polyacrylonitrile (PAN) is a primary precursor for carbon nanofibers, but conventional electrospinning techniques typically operate at low production rates of 0.1-1 mL/h from single spinneret, limiting scalability. In this study, we introduce novel liquid-assisted ultrahigh-speed (LAUHS-ES) technique that achieved actual over 220 times faster than methods. This dramatic increase throughput through Taylor cone stabilization using thin layer liquid sheath, allowing without compromising the structural integrity or uniformity nanofibers. Comprehensive characterization, including scanning electron microscopy (SEM), atomic force (AFM), Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), confirmed high quality, consistency, crystallinity produced Our results demonstrate PAN nanofiber fabrication can be scaled up significantly while maintaining precise control fiber morphology performance. advancement holds substantial promise large-scale industrial applications, enabling more efficient cost-effective carbon-based

Language: Английский

Bioinspired Metafabric with Dual‐Gradient Janus Design for Personal Radiative and Evaporative Cooling DOI
Zhen Yan, Guanghao Zhu,

D. D. Fan

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 12, 2024

Abstract Personal radiative cooling fabrics are a promising zero‐energy solution for creating cool and comfortable microclimate outdoor crowds. Despite significant progress, achieving efficient under some extreme situations, such as thermal shock intensive physical activity, remains challenge. Herein, bioinspired metafabric with dual‐gradient Janus design is reported personal evaporative cooling. The hierarchical fiber structure allows an excellent solar reflectance of 99.4% mid‐infrared emittance 0.94, inducing skin temperature drop 17.8 °C intense sunlight. Mesoporous silica nanoparticles fixed in the fibrous network can store capacity by atmospheric moisture‐absorption mild humid nighttime release moisture‐desorption hot daytime, providing additional 2.5 °C. Dual‐gradient endows outstanding sweat‐wicking effect high‐performance sweat capacity. In steady‐state evaporation tests, maximum consumption only 0.5 ml h −1 to temperature, preventing harmful excessive sweating. Additionally, also possesses favorable wearability color expansibility. Given these first‐rate features, will pave way development advanced functional fabrics.

Language: Английский

Citations

16

Boosting thermoelectric generator (TEG) performance with tandem radiative/evaporative/phase change cooler DOI

Yahui Du,

Yuxi Chen, Junwei Liu

et al.

Nano Energy, Journal Year: 2024, Volume and Issue: 128, P. 109909 - 109909

Published: June 19, 2024

Language: Английский

Citations

10

Radiative Cooling Nanohybrids with Room-Temperature Switching DOI
Yuqiang Dai, Yibo Zhang, Zhiwei Ye

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 12, 2025

Recent advancements in radiative cooling technologies have highlighted their potential as sustainable and environmentally friendly solutions. However, while this method offers significant energy savings during hot seasons, it may incur losses (overcooling leads to a waste of energy) colder conditions. The current solution has the problems complex process or easy leakage materials. To address challenge, we synthesized SiO2 nanohybrid (a nanoparticle with elongated polymer chains grafted onto its surface), which modifies thermoresponsive behavior composites. Upon incorporation these nanohybrids into matrix, will display morphological changes response temperature variations, leading emissivity resulting composite film. What's more, reflectivity film was enhanced from 57.26 89.37%, increasing performance by 4 °C weather. Results confirmed that maintained structural integrity without leakage, demonstrating robust durability. Overall, work offer valuable insights for advancing applications.

Language: Английский

Citations

1

Superhydrophobic and recyclable passive daytime radiative cooling fabric prepared via electrospinning DOI
Mingyu Xu, Jing Li, Jun Ren

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: 509, P. 161274 - 161274

Published: March 6, 2025

Language: Английский

Citations

1

Hybrid passive cooling: towards the next breakthrough of radiative sky cooling technology DOI

Yahui Du,

Yuxi Chen, Xueqing Yang

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(33), P. 21490 - 21514

Published: Jan. 1, 2024

A critical review of the regulatory mechanisms, structural design, cooling performance, and applications hybrid to advance its commercial use in passive cooling.

Language: Английский

Citations

5

Recent advance of adsorbent materials for indoor dehumidification DOI

Yuechao Chao,

Cheng Wang, Zhihua Zhou

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 130096 - 130096

Published: Oct. 1, 2024

Language: Английский

Citations

5

Preparation and Optimization of Electrospun Nylon‐6 Fiber‐Reinforced High Strength and Toughness Thermoplastic Polyurethane Composites for Potential Use in Prosthetic Heart Valves DOI Creative Commons
Gaigai Duan,

Xiuling Yang,

Minmin Ding

et al.

Macromolecular Materials and Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 27, 2025

Abstract The interfacial aspects of fiber composites are widely favored. Here, three composite strategies based on hot‐pressing, electrospinning, and impregnation PA6 fibers presented for the preparation fiber‐reinforced thermoplastic polyurethane (PA6/TPU) composites. morphologies electrospun fiber/matrix interface mechanical properties PA6/TPU investigated. Under optimal conditions, tensile strength, Young's modulus, toughness H‐PA6/TPU respectively 29.45 ± 1.477 MPa, 47.28 2.61 38.03 1.996 MJ m −3 . E‐PA6/TPU 28.03 1.411 73.81 4.16 24.12 1.265 , respectively. I‐PA6/TPU elongation at break is ≈240%. Moreover, without loss TPU properties, method effectively improves adhesion between matrix, significantly improved even if content low. simple to operate can be extended other polymers

Language: Английский

Citations

0

Reversible solar heating and radiative cooling coupled with latent heat for self-adaptive thermoregulation DOI
Qin Ye, Na Guo, Meijie Chen

et al.

Applied Physics Letters, Journal Year: 2025, Volume and Issue: 126(11)

Published: March 1, 2025

Passive solar heating and radiative cooling attracted lots of attention in global energy consumption reduction due to their unique electricity-free advantage. However, static single radiation or would lead over-cooling over-heating cold hot weather, respectively. How achieve effective self-adaptive thermoregulation is critical for dynamic thermal management. Hence, this work, a strategy was designed by coupling latent heat storage release with reversible cooling. A commercial memory alloy could realize at the temperature between high reflectance R¯solar = 0.95 emittance ε¯LWIR 0.93, absorptance α¯solar 0.92 low ε¯IR 0.08. High conductive phase change material further improve performance ∼136 J g−1, conductivity 3.4 W m−1 K−1, resulting superior than (39.9 vs 36.9 °C) (33.8 35.5 °C). The maximum increase be 12.7 °C situation, drop 8.3 situation. Energy calculation showed that sample save 68%–90% annual compared common roof, indicating spectral regulation can greatly total

Language: Английский

Citations

0

Orange pigment with high near-infrared reflectivity based on Ce-doped Bi2MoO6 DOI

Ruiying Zhai,

Sisi Chen,

Jiahao Lu

et al.

Applied Materials Today, Journal Year: 2025, Volume and Issue: 44, P. 102713 - 102713

Published: April 8, 2025

Language: Английский

Citations

0

Utilizing micro-nano dual-sized particles to enhance solar reflection in constructing energy-saving hydrogel for daytime passive cooling DOI
Shuai Zhao, Hao Tu, Jianjun Zhang

et al.

Renewable Energy, Journal Year: 2025, Volume and Issue: unknown, P. 123273 - 123273

Published: April 1, 2025

Language: Английский

Citations

0