Validation and Application of Diffusive Gradient in Thin-Film (Dgt) Equipped Novel Cyclodextrin Polymer Gels for Monitoring Endocrine Disrupting Chemicals (Edcs) and Environmental Risk Assessment in the Taihu Lake Basin DOI

Xingqi Zhu,

Lu Jiang, Xiaowen Ji

et al.

SSRN Electronic Journal, Journal Year: 2021, Volume and Issue: unknown

Published: Jan. 1, 2021

Taihu Lake is the most important drinking water source of major cities in Yangtze River Delta. The pollution endocrine disruptors (EDCs)in has been increasing recently, accurate determination an guide for predicting its health risks and developing appropriate controls. Monitoring organic pollutants using diffusive gradient thin film technique (DGT) attracted much attention due to more accuracy convenience than grab sampling methods. In this study, a novel cyclodextrin polymer (CDP) synthesized by simple green method was taken as adsorbent binding gel. Four endocrine-disrupting chemicals (EDCs), bisphenol A (BPA), 17α-ethinylestradiol (EE2), 17β-estradiol (E2), estriol (E3), were models determine diffusion coefficients (4.68×10-6, 3.38×10-6, 3.34×10-6 4.31×10-6 cm2/s) test performance DGT, such adsorption capacity deployment time (1-5 day). assembled CDP-DGT adopted four EDCs simulated environment (3-9 pH, 0.001-0.5M ionic strength (IS), dissolved matter (DOM) 0-20mg/L). ability verified Jiuxiang carried out large-scale field application situ basin. results show that total concentration range estradiol equivalent concentrations (EEQ) main rivers are 2.78 ng/L 11.08 2.62 10.91 ng/L, respectively. risk quotients (RQs) all sites region greater 1, indicating pose serious threat aquatic organisms area. Therefore, monitoring basin should be further strengthened.

Language: Английский

Development and validation of an imprinted polymer based DGT for monitoring β-blocker drugs in wastewater surveillance DOI
Yanying Li,

Mingzhe Wu,

Xinyu Yin

et al.

Journal of Hazardous Materials, Journal Year: 2024, Volume and Issue: 479, P. 135753 - 135753

Published: Sept. 6, 2024

Language: Английский

Citations

2
The Application of Passive Sampling Devices in Wastewater Surveillance DOI Open Access
Andreana G. Shakallis, Howard Fallowfield, Kirstin Ross

et al.

Water, Journal Year: 2022, Volume and Issue: 14(21), P. 3478 - 3478

Published: Oct. 31, 2022

Wastewater-based epidemiology (WBE) is a surveillance approach used to examine chemical and biological targets within population. Historically, the most common approaches wastewater sampling include grab composite sampling, which can be performed manually or using an automated sampler. However, there are inherent flaws with these methods. They miss analytes due fluctuation events in have high cost labour implications. Alternately, passive technique that involves medium stay aqueous matrix for extended periods of time provide greater temporal coverage. This literature review examines current devices general contaminants they targeting. The polar organic integrated sampler, Chemcatcher®, diffusive gradients thin films sampler semipermeable membrane were among frequently deployed samplers matrices. Chemical pharmaceuticals identified as targets. Passive has received recent attention SARS-CoV-2; however, overall, lack critical knowledge relating deployment associated variability Notwithstanding, ability capture make it useful pathogens community. Future research should focus on addressing gaps optimise use devices.

Language: Английский

Citations

11
A Review on Polyethersulfone Membranes in Polar Organic Chemical Integrative Samplers: Preparation, Characterization and Innovation DOI
Henry MacKeown, Barbara Benedetti, Chiara Scapuzzi

et al.

Critical Reviews in Analytical Chemistry, Journal Year: 2022, Volume and Issue: 54(6), P. 1758 - 1774

Published: Oct. 20, 2022

The membranes in polar organic chemical integrative samplers (POCIS) enclose the receiving sorbent and protect it from coming into direct contact with environmental matrix. They have a crucial role extending kinetic regime of contaminant uptake, by slowing down their diffusion between water phase phase. drive to improve passive sampling requires better design enhanced performances. In this review, preparation standard polyethersulfone (PES) for POCIS is presented, as well methods evaluate composition, morphology, structure, performance. Generally, only supplier-related morphological structural data are provided, such membrane type, thickness, surface area, pore diameter. issues related use PES applications exposed. Finally, alternative also discussed, although no has yet been developed. This review highlights urge more characterization details comprehension mechanisms which underlay behavior performance, selection optimize sampler development.

Language: Английский

Citations

9
Development and validation of diffusive gradients in thin-films for in situ monitoring of ionic liquids in waters DOI
Sisi Liu, Shibao Chen, Yubo Yue

et al.

Analytical Methods, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

The “PFAS-like” ionic liquids (ILs) represent a new challenge for the environmental monitoring community, DGT technique can provide robust solution.

Language: Английский

Citations

1
The influence mechanism of environmental factors on DGT adsorbing sulfonamides and the migration between water and sediment DOI
Peng Zhang,

Jingfeng Yan,

Hao Ji

et al.

Journal of Environmental Sciences, Journal Year: 2024, Volume and Issue: 151, P. 347 - 359

Published: April 8, 2024

Language: Английский

Citations

1
Validation and application of diffusive gradient in thin-film (DGT) equipped novel cyclodextrin polymer gels for monitoring endocrine disrupting chemicals (EDCs) and environmental risk assessment in the Taihu lake basin DOI Creative Commons

Xingqi Zhu,

Lu Jiang, Yinfeng Wang

et al.

Environmental Research, Journal Year: 2022, Volume and Issue: 212, P. 113391 - 113391

Published: May 18, 2022

Language: Английский

Citations

6
DGT method for the in situ measurement of triazines and the desorption kinetics of atrazine in soil DOI

Siheng Zheng,

Sheng Feng,

Cheng Gu

et al.

Environmental Science and Pollution Research, Journal Year: 2023, Volume and Issue: 30(17), P. 51061 - 51074

Published: Feb. 18, 2023

Language: Английский

Citations

2
Selective Separation of Thyroid-Hormone-Receptor-Binding Substances Using Molecularly Imprinted Polymers DOI
Takuya Kubo, Shuhei Yamamoto,

Yoshiyuki Watabe

et al.

ACS Applied Bio Materials, Journal Year: 2022, Volume and Issue: 5(11), P. 5210 - 5217

Published: Oct. 19, 2022

To date, an identification protocol for endocrine disruptors that bind to the thyroid hormone receptor (TR) has not been established. A method screening and identifying TR-binding substances is highly required due existence of unknown from environment. Here, we conceived a chromatographic using molecularly imprinted polymer (MIP) create novel disruptors. receptor-imitating MIP was prepared N-acetylthyroxine (AcetylT4) 4-vinylpyridine as pseudo-template functional monomer, respectively, based on existing molecular recognition mechanism TR. The provided ability all were employed in this study. MIPs packed into high-performance liquid chromatography column simultaneous analysis non-binding substances. former strongly retained, while latter not. presence or absence TR-binding/non-binding activity resulted successful dichotomous separation. Additionally, surface imprinting technique applied improve separation performance packing material. MIP-coated uniformly sized silica-based particles 5 μm successfully prepared, silica enabled more efficient

Language: Английский

Citations

3
Development of diffusive gradients in thin-films with mixed binding gels for in situ monitoring of artificial sweeteners in waters DOI Creative Commons
Ijaz Hussain,

Jinxin Zi,

Sisi Liu

et al.

Environmental Science Advances, Journal Year: 2023, Volume and Issue: 2(6), P. 837 - 847

Published: Jan. 1, 2023

The extensive use of artificial sweeteners (ASs) has raised concerns regarding their presence, fate, and detrimental effects in water resources.

Language: Английский

Citations

1
Validation and Application of Diffusive Gradient in Thin-Film (Dgt) Equipped Novel Cyclodextrin Polymer Gels for Monitoring Endocrine Disrupting Chemicals (Edcs) and Environmental Risk Assessment in the Taihu Lake Basin DOI

Xingqi Zhu,

Lu Jiang, Yinfeng Wang

et al.

SSRN Electronic Journal, Journal Year: 2022, Volume and Issue: unknown

Published: Jan. 1, 2022

Taihu Lake is the most important drinking water source of major cities in Yangtze River Delta. The pollution endocrine disruptors (EDCs)in has been increasing recently, accurate determination an guide for predicting its health risks and developing appropriate controls. Monitoring organic pollutants using diffusive gradient thin film technique (DGT) attracted much attention due to more accuracy convenience than grab sampling methods. In this study, a novel cyclodextrin polymer (CDP) synthesized by simple green method was taken as adsorbent binding gel. Four endocrine-disrupting chemicals (EDCs), bisphenol A (BPA), 17α-ethinylestradiol (EE2), 17β-estradiol (E2), estriol (E3), were models determine diffusion coefficients (4.68×10-6, 3.38×10-6, 3.34×10-6 4.31×10-6 cm2/s) test performance DGT, such adsorption capacity deployment time (1-5 day). assembled CDP-DGT adopted four EDCs simulated environment (3-9 pH, 0.001-0.5 M ionic strength (IS), dissolved matter (DOM) 0-20 mg/L). ability verified Jiuxiang carried out large-scale field application situ basin. results show that total concentration range estradiol equivalent concentrations (EEQ) main rivers are 2.78 ng/L 11.08 2.62 10.91 ng/L, respectively. risk quotients (RQs) all sites region greater 1, indicating pose serious threat aquatic organisms area. Therefore, monitoring basin should be further strengthened.

Language: Английский

Citations

1