Biochar-Derived Persistent Free Radicals: A Plethora of Environmental Applications in a Light and Shadows Scenario DOI Creative Commons
Silvana Alfei, Omar Pandoli

Toxics, Journal Year: 2024, Volume and Issue: 12(4), P. 245 - 245

Published: March 27, 2024

Biochar (BC) is a carbonaceous material obtained by pyrolysis at 200–1000 °C in the limited presence of O2 from different vegetable and animal biomass feedstocks. BC has demonstrated great potential, mainly environmental applications, due to its high sorption ability persistent free radicals (PFRs) content. These characteristics enable carry out direct PFRs-mediated removal/degradation organic inorganic contaminants. The types PFRs that are possibly present depend on temperature kind pristine biomass. Since they can also cause ecological human damage, systematic evaluation behavior, risks, or management techniques BC-derived urgent. generally consist mixture carbon- oxygen-centered oxygenated carbon-centered radicals, depending pyrolytic conditions. Here, promote more productive beneficial use related stimulate further studies make them environmentally safer less hazardous humans, we have first reviewed most common methods used produce BC, main primary mechanisms which remove xenobiotics, as well reported for PFR formation BC. Secondly, discussed migration transformation PFRs; PFR-mediated application degrade pollutants, potential correlated possible strategies limit them.

Language: Английский

Degradation of organic pollutants from water by biochar-assisted advanced oxidation processes: Mechanisms and applications DOI
Tao Jiang, Bing Wang, Bin Gao

et al.

Journal of Hazardous Materials, Journal Year: 2022, Volume and Issue: 442, P. 130075 - 130075

Published: Sept. 29, 2022

Language: Английский

Citations

161

Robust PVA/GO@MOF membrane with fast photothermal self-cleaning property for oily wastewater purification DOI
Bin Xiang,

Jingling Gong,

Yuqing Sun

et al.

Journal of Hazardous Materials, Journal Year: 2023, Volume and Issue: 462, P. 132803 - 132803

Published: Oct. 18, 2023

Language: Английский

Citations

104

Integrating K and P co-doped g-C3N4 with ZnFe2O4 and graphene oxide for S-scheme-based enhanced adsorption coupled photocatalytic real wastewater treatment DOI Open Access
Rohit Kumar, Anita Sudhaik,

Sonu Sonu

et al.

Chemosphere, Journal Year: 2023, Volume and Issue: 337, P. 139267 - 139267

Published: June 19, 2023

Language: Английский

Citations

93

Recent advances in visible light-activated photocatalysts for degradation of dyes: A comprehensive review DOI
Lasithya Vishoda Samarasinghe, Shobha Muthukumaran, Kanagaratnam Baskaran

et al.

Chemosphere, Journal Year: 2023, Volume and Issue: 349, P. 140818 - 140818

Published: Dec. 4, 2023

Language: Английский

Citations

53

Biochar-based nanocomposites for industrial wastewater treatment via adsorption and photocatalytic degradation and the parameters affecting these processes DOI Creative Commons
Enas Amdeha

Biomass Conversion and Biorefinery, Journal Year: 2023, Volume and Issue: 14(19), P. 23293 - 23318

Published: July 4, 2023

Abstract The preparation of biochar (BC) as a useful substance generated from biomass valorization via pyrolysis has attracted much attention in recent years. Moreover, widespread worries about water pollution and the issues brought on by producing releasing massive volumes industrial effluents have sparked research initiatives to examine practical affordable solutions these problems. Dyes, heavy metals, pharmaceutical compounds are main hazardous pollutants wastewater. As result, (BC)/biochar (BC)-based nanocomposites been presented potential alternative handle wastewater with both adsorption photocatalytic degradation processes. Such nanocomposite materials benefit synergistic effect photocatalysis attain improved removal Therefore, this review aims describe different methods for biochar-based nanocomposites. Furthermore, differences between processes discussed. BC-based emerged promising adsorbents photocatalysts treatment applications. To maximize efficiency processes, an overview parameters affecting is reviewed, where dose, initial pollutant concentration, pH, temperature, time, presence anions, recycling discovered significant impact their performance. Finally, future recommendations directions provided help shape applications This offers comprehensive evaluation use new environmental material capable removing Graphical

Language: Английский

Citations

51

Reactive Oxygen Species (ROS)-Mediated Antibacterial Oxidative Therapies: Available Methods to Generate ROS and a Novel Option Proposal DOI Open Access
Silvana Alfei,

Gian Carlo Schito,

Anna Maria Schito

et al.

International Journal of Molecular Sciences, Journal Year: 2024, Volume and Issue: 25(13), P. 7182 - 7182

Published: June 29, 2024

The increasing emergence of multidrug-resistant (MDR) pathogens causes difficult-to-treat infections with long-term hospitalizations and a high incidence death, thus representing global public health problem. To manage MDR bacteria bugs, new antimicrobial strategies are necessary, their introduction in practice is daily challenge for scientists the field. An extensively studied approach to treating consists inducing levels reactive oxygen species (ROS) by several methods. Although further clinical investigations mandatory on possible toxic effects ROS mammalian cells, evaluations extremely promising, topical use treat infected wounds ulcers, also presence biofilm, already clinically approved. Biochar (BC) carbonaceous material obtained pyrolysis different vegetable animal biomass feedstocks at 200–1000 °C limited O2. Recently, it has been demonstrated that BC’s capability removing organic inorganic xenobiotics mainly due persistent free radicals (PFRs), which can activate oxygen, H2O2, or persulfate absence transition metals electron transfer, generating ROS, turn degrade pollutants advanced oxidation processes (AOPs). In this context, antibacterial BC-containing PFRs have some authors against Escherichia coli Staphylococcus aureus, giving birth our idea BC-derived as novel method capable generation oxidative therapy. Here, general aspects concerning physiological pathological production regulation mechanism they could exert reviewed. methods currently adopted induce therapy discussed. Finally, first time, BC-related proposed source via AOPs.

Language: Английский

Citations

48

Recent advances over the doped g-C3N4 in photocatalysis: A review DOI
Muhammad Asim Khan, Sadaf Mutahir,

Imrana Shaheen

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 522, P. 216227 - 216227

Published: Sept. 19, 2024

Language: Английский

Citations

45

Nitrogen-doped carbon skeleton loaded with PDI/MZO S-scheme photocatalyst with enhanced adsorption and photocatalysis activity DOI
Yaru Wang,

Xunxun Li,

Wanjun Xu

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 348, P. 123839 - 123839

Published: April 24, 2024

Language: Английский

Citations

36

Rapid degradation of anionic azo dye from water using visible light-enabled binary metal-organic framework DOI
Faisal Suleiman Mustafa, Akeem Adeyemi Oladipo

Journal of Water Process Engineering, Journal Year: 2024, Volume and Issue: 64, P. 105686 - 105686

Published: June 25, 2024

Language: Английский

Citations

30

Recent advances in sorption-based photocatalytic materials for the degradation of antibiotics DOI

Jiaomei Yang,

Shufang Tian,

Zhen Song

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216257 - 216257

Published: Oct. 11, 2024

Language: Английский

Citations

28