Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 493, P. 152460 - 152460
Published: May 22, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 493, P. 152460 - 152460
Published: May 22, 2024
Language: Английский
Published: June 21, 2024
Green and sustainable electrocatalytic conversion of nitrogen-containing compounds to ammonia are currently in high demand order replace the eco-unfriendly Haber-Bosch process. Model catalysts for nitrate reduction reaction were obtained by electrodeposition metal Co, Fe bimetallic Fe/Co nanoparticles from aqueous solutions onto a graphite substrate. The samples characterized following methods: SEM, XRD, XPS, UV-vis spectroscopy, cyclic (and linear) voltammetry, chronoamperometry electrochemical impedance spectroscopy. Besides, determination electrochemically active surface was also performed all electrocatalysts. best electrocatalyst sample containing Fe-nanoparticles on layer Co-nanoparticles, which showed Faradaic efficiency 58.2% (E=-0.785 V vs. RHE) at yield rate 14.6 μmol h-1 cm-2. An opinion expressed elucidation mechanism coordinated action electrocatalyst. This work can serve primarily as starting point future investigations reactions using model proposed type.
Language: Английский
Citations
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Published: Jan. 11, 2024
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5Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 493, P. 152460 - 152460
Published: May 22, 2024
Language: Английский
Citations
5