Ionic liquid containing high-density polyethylene supported tungstate: a novel, efficient, and highly recoverable catalyst DOI Creative Commons

Farideh Mousavi,

Dawood Elhamifar, Shiva Kargar

et al.

Frontiers in Chemistry, Journal Year: 2024, Volume and Issue: 12

Published: Feb. 29, 2024

Synthesis and catalytic application of polymeric-based nanocomposites are important subjects among researchers due to their high lipophilicity as well chemical mechanical stability. In the present work, a novel nanocomposite material involving ionic liquid high-density polyethylene supported tungstate (PE/IL-WO 4 = ) is synthesized, characterized its investigated. The coacervation method was used incorporate 1-methyl-3-octylimidazolium bromide ([MOIm] [Br]) in polyethylene, resulting PE/IL composite. Subsequently, anchored on give PE/IL-WO catalyst. PXRD, FT-IR, EDX, TGA, SEM analyses were characterize This demonstrated efficiency synthesis bioactive tetrahydrobenzo[a]xanthen-11-ones under green conditions. recoverability leching tests performed investigate stability durability designed catalyst applied

Language: Английский

Micro/Nanorobotics in Environmental Water Governance: Nanoengineering Strategies for Pollution Control DOI Creative Commons

Y. Gan,

Bin Wang, Yuan Lu

et al.

Small Structures, Journal Year: 2025, Volume and Issue: unknown

Published: April 6, 2025

The significance of micro/nanorobotics in environmental water governance is underscored by the escalating challenge pollution, demanding innovative solutions for efficient and selective pollutant removal. These tiny yet powerful devices, with their ability to detect, capture, degrade pollutants, signify a groundbreaking shift from traditional treatment methods more precise, efficient, sustainable approaches. This review delineates advancements micro/nanorobotics, emphasizing diverse propulsion mechanisms functionalities tailored specific tasks, including degradation microplastics, organic inactivation harmful microorganisms. With focus on integration photocatalytic, magnetic, self‐propelled capabilities, text highlights potential these robots revolutionize processes. Furthermore, it acknowledges challenges faced scalability, cost‐effectiveness, compatibility, urging future research toward developing adaptable, eco‐friendly, robotic systems. not only elucidates current but also charts course where intelligent, dynamically controlled systems become central management, offering crucial insights guiding next wave innovations field.

Language: Английский

Citations

0

Clay-polymer nanocomposites for advanced packaging materials: A material synthesis and characterization study DOI
Sanjay Modi, N.C. Mishra, Prabhakar Bhandari

et al.

AIP conference proceedings, Journal Year: 2025, Volume and Issue: 3157, P. 120021 - 120021

Published: Jan. 1, 2025

Language: Английский

Citations

0

Functionalized Cyclotriphosphazene-Based Cobalt Coordination Polymer: Synthesis, Characterization, and Catalytic Efficiency Evaluation DOI Creative Commons

Ayşen Orhan Erkovan,

Azam Seifi, Alireza Khataee

et al.

Journal of Inorganic and Organometallic Polymers and Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 1, 2025

Language: Английский

Citations

0

Rethinking strategies to attenuate organic pollutants: Mechanisms and challenges of catalytic pollutants polymerization DOI
Shiyu Zuo, Yan Wang, Jinquan Wan

et al.

Critical Reviews in Environmental Science and Technology, Journal Year: 2024, Volume and Issue: unknown, P. 1 - 21

Published: Aug. 24, 2024

There exist two distinct pathways for the migration and conversion of organic pollutants in natural water, namely degradation polymerization. From perspective carbon cycle water purification process, compared with pollutants, oxidative poly­merization could directly convert matter into solid polymers, which can not only realize recovery but also solve problem high energy consumption emissions degradation, demonstrating its great potential development application. Here, we summarize nature polymerization ­pollutants transport-based techniques, focusing on principles reaction, pollutant pathways, catalytic methods catalysts. For first time elaborated ROS electron transfer as core reaction mechanism. Finally, current problems challenges are highlighted future research goals trends pollution discussed. This concludes that, from migration, has significant advantages over terms reducing chemical inputs CO2 emissions, achieving efficient removal refractory recovering carbon, thus a highly competitive application neutrality remediation (such concentrations industrial wastewater). However, growing applications treatment technologies inextricably linked to substantial quantity preliminary basic research, hence critical need related work.

Language: Английский

Citations

3

Continuous-flow electrooxidation for scalable biomass upgrading over copper-supported CoFe Prussian blue analogues DOI Open Access
Bowen Zhang, Tian‐Tian Xiao, Cejun Hu

et al.

Chemical Synthesis, Journal Year: 2025, Volume and Issue: 5(1)

Published: Jan. 9, 2025

Electrochemical biomass upgrading is a promising substitute for oxygen evolution reaction (OER) to generate valuable chemicals in conjunction with hydrogen generation. Pursuing highly efficient and durable electrocatalysts significant concentration levels (≥ 50 mM) of electrooxidation remains an enduring challenge. Herein, we introduce robust Cu-supported CoFe Prussian blue analogue (CoFe PBA/CF) electrocatalyst, adept at facilitating high-concentration (50 5-hydroxymethylfurfural (HMF) oxidation into 2,5-furandicarboxylic acid (FDCA), achieving exceptional HMF conversion (100%) notable FDCA yield 98.4%. The influence copper substrate adsorption energy are therefore discussed. Impressively, the PBA/CF electrode sustains considerable durability continuous-flow electrochemical reactor designed consecutive production, showcasing yields 100/94% flow rates 0.4/0.8 mL·min-1 over 60 h’ uninterrupted electrolysis. This work provides strategy develop production high-value products coupled green H2 production.

Language: Английский

Citations

0

Development of catalysts and reactor designs for CO2 electroreduction towards C2+ products DOI Open Access

Joonhee Ma,

Soo Young Kim

Energy Materials, Journal Year: 2025, Volume and Issue: 5(5)

Published: Feb. 25, 2025

Recent research on the electrocatalytic CO2 reduction reaction (eCO2RR) has garnered significant attention given its capability to address environmental issues associated with emissions while harnessing clean energy produce high-value-added products. Compared C1 products, C2+ products provide greater densities and are highly sought after as chemical feedstocks. However, formation of C-C bond is challenging due competition H-H C-H bonds. Therefore, elevate selectivity yield fuels, it essential develop more advanced electrocatalysts optimize design electrochemical cell configurations. Of materials investigated for CO2RR, Cu-based stand out their wide availability, affordability, compatibility. Moreover, catalysts exhibit promising capabilities in adsorption activation, facilitating compounds via coupling. This review examines recent both cells electroreduction compounds, introducing core principles eCO2RR pathways involved generating A key focus categorization catalyst designs, including defect engineering, surface modification, nanostructure tandem catalysis. By analyzing studies catalysts, we aim elucidate mechanisms behind enhanced compounds. Additionally, various types electrolytic discussed. Lastly, prospects limitations utilizing highlighted future research.

Language: Английский

Citations

0

Wastewater Remediation Treatments Aimed at Water Reuse: Recent Outcomes from Pilot- and Full-Scale Tests DOI Creative Commons
Elida Nora Ferri, Luca Bolelli

Applied Sciences, Journal Year: 2025, Volume and Issue: 15(5), P. 2448 - 2448

Published: Feb. 25, 2025

Remediated water reuse is becoming vital for sustainable management, reducing the strain on freshwater resources, particularly in agriculture and industrial activities. Behind application irrigating crops processes, treated should be employed indirect direct potable use. In latter case, traditional approaches to wastewater treatment have been found inefficient, especially concerning biological contamination, persistent organic pollutants (POPs) and/or contaminants of emerging concern (CECs). Given that, according its origin foreseen use, each needs a specific treatment. A plethora new or improved materials, combinations different treatments check analyses are continuously developed tested at laboratory scale, first, necessary but not sufficient, step towards solution. Various innovative were pilot reduced number procedures applied full resulting significant production remediated desired quality. The present review focuses most recent outcomes obtained from remediation both scales discusses gaps which still hinder exploitation solutions advancements real-scale application.

Language: Английский

Citations

0

Thermal resistance of CuxS rich composites based on carboxylic cation exchangers-synthesis and thermogravimetric studies DOI
Elżbieta Kociołek‐Balawejder, Irena Jacukowicz‐Sobala, I. Muchá

et al.

Journal of Thermal Analysis and Calorimetry, Journal Year: 2025, Volume and Issue: unknown

Published: April 10, 2025

Language: Английский

Citations

0

Composite Materials for Bio-Energy DOI
Rahul Gautam,

Hariome Sharan Gupta,

Amit Chauhan

et al.

Published: Jan. 1, 2024

In the present scenario of energy scarcity around world and current geopolitical tensions have pushed scientific community for green renewable sources. Hunt sustainability has tossed Bio-electrochemical systems bioenergy. These wide applications ranging from wastewater treatment to bio-energy production. The chapter explores advancements in field polymeric composites, their roles various bioenergy applications. materials are explored as electrode attachment biofilm over them, electron transportation different end products at cathode. Also, these composites play a crucial role proton exchange membranes also anti-fouling agent membranes. This discusses Polymeric composites-based BES treatment, waste management, contaminants removal, etc.

Language: Английский

Citations

2

Electrochemical degradation of small molecule dyes by TiO2-decorated polyacrylonitrile nanofiber membranes with superior properties DOI

Xiuying Yang,

Chennan Zhao,

Zezhou Zhang

et al.

Journal of Membrane Science, Journal Year: 2024, Volume and Issue: 709, P. 123132 - 123132

Published: July 24, 2024

Language: Английский

Citations

2