Water Research, Journal Year: 2024, Volume and Issue: 271, P. 122898 - 122898
Published: Nov. 30, 2024
Language: Английский
Water Research, Journal Year: 2024, Volume and Issue: 271, P. 122898 - 122898
Published: Nov. 30, 2024
Language: Английский
Environmental Science & Technology, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 13, 2025
The sandy subterranean estuary (STE) connecting fresh groundwater to saline sea water is characterized by strong geochemical (salinity, redox, and pH) gradients, with evidence emerging for its role as a hot spot consumption of labile substrates. This inspired us conduct study evaluate whether this holds true dissolved organic matter (DOM), especially given the still mysterious origin marine recalcitrant DOM. Here, characterization DOM 21 samples (depth 1-13 m, salinity 3.9‰ 32.4‰) across 65 m transect an STE located in coastal Guangdong, China, has found systematic biotransformation toward "recalcitrant" carboxyl-rich alicyclic molecules (CRAM). fraction CRAM (%CRAM) increases from 33.1% 76.7% increasing degree degradation salinity. Further, processing DOM, including more "biolabile" lower %CRAM released aquitard, active under oxic conditions than reducing conditions. Given large quantities that recirculates through STEs globally, amount (RDOM) entering ocean after likely be considerable. While studies are needed, can gain CRAM-like compounds way.
Language: Английский
Citations
2Marine Environmental Research, Journal Year: 2025, Volume and Issue: 205, P. 107020 - 107020
Published: Feb. 18, 2025
Language: Английский
Citations
0Environmental Research, Journal Year: 2024, Volume and Issue: 252, P. 119040 - 119040
Published: April 29, 2024
Language: Английский
Citations
2Journal of Geophysical Research Biogeosciences, Journal Year: 2024, Volume and Issue: 129(9)
Published: Sept. 1, 2024
Abstract The export of dissolved organic matter (DOM) from rivers is essential for linking terrestrial and marine carbon reservoirs in the global cycle. However, there limited knowledge regarding how molecular composition riverine DOM changes under different hydrological conditions, especially during extreme rainfall events. Moreover, factors beyond hydrology that impact have not been well defined. To address these gaps, samples were collected a human‐impacted medium‐sized subtropical monsoonal river across various conditions throughout complete Utilizing high‐resolution mass spectrometry, it was discovered solid‐phase extractable (SPE‐DOM) high‐flow (1 < runoff (Q): annual mean (Q m ) 3) extreme‐rain (Q:Q > periods exhibited higher number formulae, lower H/C, O/C, proportion carboxylic‐rich alicyclic molecules compared to low‐flow period (LFP) 1). These alterations attributed input more diverse sources, particularly greater soil with oxidation degrees. Additionally, P‐containing formulae enriched period, likely agricultural lands sediment release. Conversely, fraction S‐containing significantly LFP, possibly due amplified influence anthropogenic input. Furthermore, aromaticity did fluctuate but associated temperature. In summary, study indicated varied temperature activities identified as crucial influencing export.
Language: Английский
Citations
0Chemical Geology, Journal Year: 2024, Volume and Issue: 671, P. 122495 - 122495
Published: Nov. 14, 2024
Language: Английский
Citations
0Water Research, Journal Year: 2024, Volume and Issue: 271, P. 122898 - 122898
Published: Nov. 30, 2024
Language: Английский
Citations
0