Mesoscopic Simulation on Centrifugal Melt Electrospinning of Polyetherimide and Polyarylethernitrile DOI Open Access
Han Guo, Yuzhe Huang, Jia Chen

et al.

Journal of Composites Science, Journal Year: 2024, Volume and Issue: 8(11), P. 480 - 480

Published: Nov. 19, 2024

Polyetherimide (PEI) and polyarylethernitrile (PEN) are high–performance materials for various applications. By optimizing their fiber morphology, performance can be further enhanced, leading to an expanded range of applications in carbon composites. However, developing processes stable efficient production remains challenging. This research aims simulate the preparation ultrafine PEI or PEN fibers using electrospinning. A mesoscopic simulation model centrifugal melt electrospinning was constructed compare analyze changes molecular chain orientation, unfolding, diameter, yield under high-voltage electrostatic fields. The results showed that temperature electric field force had a particular impact on diameter fibers. Changes rotational speed negligible effects both Additionally, due different structures, PEN, which have lengths, exhibit varied spinning trends. study established dynamic foundation producing high-performance provided theoretical guidance future experiments.

Language: Английский

Transitioning to Microplastic-Free Seed Coatings: Challenges and Solutions DOI Open Access

Rozenn Langlet,

Romain Valentin,

Marie Morard

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(14), P. 1969 - 1969

Published: July 10, 2024

This review addresses the issue of replacing manufactured microplastics in seed coatings used agriculture. Firstly, it focuses on policy and regulatory actions taken at a global level. There is no consensus within scientific community definition microplastic and, more generally, classification plastic debris. Nevertheless, several decision schemes have been proposed an attempt to define notion microplastics. The different criteria relevant this definition, such as size, physical state, chemical structure, origin, persistence microplastics, are discussed, with comparison being made between REACH regulation literature. Seed production processing also functions explained order gain better understanding properties be considered substitution strategy for currently main challenges multiple; substitutes must provide same performance microplastics: (i) improving adherence treatment seed, (ii) distributing evenly over (iii) reducing amount dust-off when handling treated (iv) flowability, which particularly important during sowing stage, all while preserving physiological seed. Substitute polymers according desired functional properties: two families biopolymers were identified literature: polysaccharides proteins. Among them, 13 6 polymers, respectively, complied regulation, demonstrating adhesion, dust reduction performances, preservation quality particular. work aims guide future studies coatings, highlight research needs area. It based analysis discussion literature, identifying listing potential substitutes.

Language: Английский

Citations

4

Emissions of water-soluble polymers from household products to the environment: a prioritization study DOI Creative Commons
Hattie Brunning, J. Brett Sallach, Alistair B.A. Boxall

et al.

Environmental Toxicology and Chemistry, Journal Year: 2025, Volume and Issue: 44(2), P. 563 - 588

Published: Jan. 6, 2025

Water-soluble polymers (WSPs) are widely used in household products, including cleaning and personal care products. However, unlike insoluble plastic polymers, the environmental risks of WSPs poorly understood. This study was performed to identify use characterize their emissions environment key data gaps for prioritization. An inventory developed these were broadly grouped based on structure. Information from patents combined with literature estimate down-the-drain each polymer. For highest emissions, predicted concentrations surface water soil estimated. A total 339 individual identified categorized into 26 groups. The sodium laureth sulfate (1.6-3.4 g capita-1 day-1), styrene/acrylates copolymer (0.1-0.8 monoethanolamine-laureth (0.4-0.8 day-1). analysis available fate ecotoxicity 30 high-emission indicated that several lacking data. In particular, no found polyethylene glycol/vinyl acetate, polyquaterniums polyol ethoxylate esters has been understudied, particularly light hazard potential. a lack reporting polymer properties hinders analysis. We recommend increased transparency identities moving forward as well experimental work determining fate, removal, prioritized

Language: Английский

Citations

0

Microplastics and organic contaminants DOI
Milica Balaban, Dejana Savić, Sanja Pržulj

et al.

Elsevier eBooks, Journal Year: 2025, Volume and Issue: unknown, P. 327 - 365

Published: Jan. 1, 2025

Language: Английский

Citations

0

Plastic problem solved? Environmental implications of synthetic hydrophilic polymers across ecosystem boundaries DOI Creative Commons
Zacharias Steinmetz,

Christian Plicht,

Christian Buchmann

et al.

TrAC Trends in Analytical Chemistry, Journal Year: 2024, Volume and Issue: 181, P. 118000 - 118000

Published: Oct. 9, 2024

Language: Английский

Citations

1

Mesoscopic Simulation on Centrifugal Melt Electrospinning of Polyetherimide and Polyarylethernitrile DOI Open Access
Han Guo, Yuzhe Huang, Jia Chen

et al.

Journal of Composites Science, Journal Year: 2024, Volume and Issue: 8(11), P. 480 - 480

Published: Nov. 19, 2024

Polyetherimide (PEI) and polyarylethernitrile (PEN) are high–performance materials for various applications. By optimizing their fiber morphology, performance can be further enhanced, leading to an expanded range of applications in carbon composites. However, developing processes stable efficient production remains challenging. This research aims simulate the preparation ultrafine PEI or PEN fibers using electrospinning. A mesoscopic simulation model centrifugal melt electrospinning was constructed compare analyze changes molecular chain orientation, unfolding, diameter, yield under high-voltage electrostatic fields. The results showed that temperature electric field force had a particular impact on diameter fibers. Changes rotational speed negligible effects both Additionally, due different structures, PEN, which have lengths, exhibit varied spinning trends. study established dynamic foundation producing high-performance provided theoretical guidance future experiments.

Language: Английский

Citations

0