Influence of Biochar Amendment on the Binding Characteristics of Dissolved Organic Matter from Chicken Manure Compost with Cu(II): An Integrated Analysis using EEM-PARAFAC, 2D-COS, and HPSEC DOI
Xiaolong Liu, Ao Cheng, Xufang Yu

et al.

Waste and Biomass Valorization, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 14, 2024

Language: Английский

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Influence of biochar amendment on the binding characteristics of dissolved organic matter from chicken manure compost with Cu(II): an integrated analysis using EEM-PARAFAC, 2D-COS, and HPSEC DOI Creative Commons
Xiaolong Liu, Ao Cheng, Xufang Yu

et al.

Research Square (Research Square), Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 13, 2024

Abstract The addition of biochar (BC) during composting significantly influences the concentration and chemical structure dissolved organic matters (DOM), thereby affecting its binding properties with heavy metals (HMs). This study examines co-composting chicken manure varying BC dosages, specifically 0 wt% (CK), 1 (T1), 2 (T2), comparatively analyzes characteristics between compost-derived DOM copper ions (Cu(II)). EEM-PARAFAC analysis identified three primary components in DOM: fulvic acid-like (C1), humic (C2), protein-like (C3) components, each exhibiting distinct Cu(II) properties. complexation constants (logK) for these increased addition, whereas fraction bound sites (f values) decreased, indicating that BC-amended compost forms more stable DOM-Cu(II) complexes but fewer available sites. 2D-COS synchronous fluorescence spectra revealed fulvic-like peaks were sensitive to variations across all types, while humic-like substances exhibited a stronger preference binding. HPSEC results showed broad molecular weight (MW) distributions (100–300,000 Da) DOM, significant decrease medium MW regions (1000-30,000 as increased, suggesting fractions are particularly binding, leading higher weight-averaged values concentrations. provides new insights into how can influence behavior HMs, highlighting potential enhancing HMs immobilization compost-amended soils.

Language: Английский

Citations

0

Influence of Biochar Amendment on the Binding Characteristics of Dissolved Organic Matter from Chicken Manure Compost with Cu(II): An Integrated Analysis using EEM-PARAFAC, 2D-COS, and HPSEC DOI
Xiaolong Liu, Ao Cheng, Xufang Yu

et al.

Waste and Biomass Valorization, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 14, 2024

Language: Английский

Citations

0