DFT study on the mechanism and structural aspects of iron(II)-catalyzed condensation of epichlorohydrin and CO2 DOI

Alejandro Yañez-Cabrera,

Mario Sánchez,

Berenice Sampayo-Andrade

et al.

Journal of Organometallic Chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 123446 - 123446

Published: Nov. 1, 2024

Language: Английский

CO2 fixation: cycloaddition of CO2 to epoxides by practical metal-free recyclable catalysts DOI

Wuttichai Natongchai,

Daniel Crespy, Valerio D’Elia

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 25, 2024

Recent works on practical and recyclable catalysts for the cycloaddition of CO 2 to epoxides are reviewed with an eye use inexpensive, readily-available, non-toxic materials future emerging designs.

Language: Английский

Citations

6
Boron Compounds as Key Drivers of Innovation: Exploring Their Role in Environmental Remediation, Sustainable Agriculture, Advanced Biomedical Applications, and Green Chemistry DOI
Metin Yıldırım, Mehmet Erşatır, Mohammed Saleh

et al.

Journal of Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 1035, P. 123688 - 123688

Published: April 28, 2025

Language: Английский

Citations

0
Graphene oxide-based probe for detecting deltamethrin and emamectin benzoate pesticides in agricultural run-off DOI
Suryyia Manzoor, Muhammad Qasim Hayat, Hina Raza

et al.

Environmental Science Water Research & Technology, Journal Year: 2024, Volume and Issue: 10(9), P. 2162 - 2176

Published: Jan. 1, 2024

Insecticides adversely affect aquatic ecosystems due to prolonged exposure, persistent nature, and bioaccumulation.

Language: Английский

Citations

3
Efficient green solvent-free CO2/epoxide cycloaddition catalyzed by a β-cyclodextrin-imidazolium-based ionic liquid DOI Creative Commons

Elisabetta Grazia Tomarchio,

Chiara Zagni, Rita Turnaturi

et al.

Journal of Industrial and Engineering Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 1, 2024

Language: Английский

Citations

2
Research progress in catalytic conversion of CO2 and epoxides based on ionic liquids to cyclic carbonates DOI
Heng Liu,

Xiaohuan Chang,

Ting Yan

et al.

Nano Energy, Journal Year: 2024, Volume and Issue: unknown, P. 110596 - 110596

Published: Dec. 1, 2024

Language: Английский

Citations

1
Formation of bio-based cyclic carbonates from CO2 and renewable feedstocks via porous poly(azomethine) -based heterogeneous catalysts approach DOI Creative Commons
Marcelo Echeverri, Eva M. Maya, David Muñoz

et al.

Journal of CO2 Utilization, Journal Year: 2024, Volume and Issue: 90, P. 102977 - 102977

Published: Nov. 20, 2024

Language: Английский

Citations

0
Deep Eutectic Solvent Engineered Dendritic Fibrous Nano‐Silica Catalyst for Sustainable Fixation of CO2 Into Value‐Added Product at Atmospheric Condition DOI Open Access

Sarat Chandra Alla,

Allwin Sudhakaran,

Omkar B. Bembalge

et al.

Applied Organometallic Chemistry, Journal Year: 2024, Volume and Issue: 39(1)

Published: Dec. 15, 2024

ABSTRACT Developing efficient carbon dioxide (CO 2 ) capture and conversion methods is vital for climate change mitigation. Cycloaddition of CO with epoxides to form cyclic carbonates a promising utilization method. In this study, deep eutectic solvent‐modified dendritic fibrous nano‐silica (DES@DFNS) catalyst was synthesized by functionalizing DFNS DES. This used the cycloaddition styrene oxide produce carbonate. The material's morphology properties were characterized using various analytical techniques, revealing high surface area, good porosity, significant concentrations Lewis acidic basic sites. Rietveld refinement analysis provided insights into its phase composition, crystallite size, microstrain, stress, other microstructural properties. Despite lower DES@DFNS demonstrated superior catalytic activity. interaction between DES showed that physically adsorbed onto surface, contributing enhanced performance. Factors such as smaller higher increased dislocation density, improved elastic more active sites greater mechanical stability, boosting overall efficiency durability. achieved 99% 96% selectivity 95% yield carbonate at 120 °C 10 h under solvent‐free, atmospheric conditions. synergistic effect on supported activity moderate Additionally, reusability, maintaining performance up six cycles without loss activity, making it candidate sustainable fixation valorization processes.

Language: Английский

Citations

0
DFT study on the mechanism and structural aspects of iron(II)-catalyzed condensation of epichlorohydrin and CO2 DOI

Alejandro Yañez-Cabrera,

Mario Sánchez,

Berenice Sampayo-Andrade

et al.

Journal of Organometallic Chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 123446 - 123446

Published: Nov. 1, 2024

Language: Английский

Citations

0