CuI nanoparticle-immobilized on a hybrid material composed of IRMOF-3 and a sulfonamide-based porous organic polymer as an efficient nanocatalyst for one-pot synthesis of 2,4-diaryl-quinolines DOI Creative Commons

Samaneh Koosha,

Sedigheh Alavinia,

Ramin Ghorbani‐Vaghei

et al.

RSC Advances, Journal Year: 2023, Volume and Issue: 13(17), P. 11480 - 11494

Published: Jan. 1, 2023

As a significant class of synthetic and natural products with multiple biological activities, quinolines are used in medical electronic devices.

Language: Английский

Flexible Curcumin-Loaded Zn-MOF Hydrogel for Long-Term Drug Release and Antibacterial Activities DOI Open Access
Jiaxin Li,

Yachao Yan,

Yingzhi Chen

et al.

International Journal of Molecular Sciences, Journal Year: 2023, Volume and Issue: 24(14), P. 11439 - 11439

Published: July 14, 2023

Management of chronic inflammation and wounds has always been a key issue in the pharmaceutical healthcare sectors. Curcumin (CCM) is an active ingredient extracted from turmeric rhizomes with antioxidant, anti-inflammatory, antibacterial activities, thus showing significant effectiveness toward wound healing. However, its shortcomings, such as poor water solubility, chemical stability, fast metabolic rate, limit bioavailability long-term use. In this context, hydrogels appear to be versatile matrix for carrying stabilizing drugs due their biomimetic structure, soft porous microarchitecture, favorable biomechanical properties. The drug loading/releasing efficiencies can also controlled via using highly crystalline metal-organic frameworks (MOFs). Herein, flexible hydrogel composed sodium alginate (SA) CCM-loaded MOFs was constructed release activity. morphology physicochemical properties composite were analyzed by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), ultraviolet-visible (UV-Vis), Raman spectroscopy, mechanical property tests. results showed that twistable bendable comply human skin mechanically. as-prepared could capture efficient CCM slow effectively kill bacteria. Therefore, expected provide new management system dressings.

Language: Английский

Citations

26

Adsorption and photocatalytic applications of porphyrin-based materials for environmental separation processes: A review DOI
Despina A. Gkika, Kalliopi Ladomenou, M. Bououdina

et al.

The Science of The Total Environment, Journal Year: 2023, Volume and Issue: 908, P. 168293 - 168293

Published: Nov. 4, 2023

Language: Английский

Citations

26

Cutting-edge in the green synthesis of MIL-101(Cr) MOF based on organic and inorganic waste recycling with extraordinary removal for anionic dye DOI
Basem E. Keshta, Haojie Yu, Li Wang

et al.

Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 332, P. 125744 - 125744

Published: Nov. 17, 2023

Language: Английский

Citations

23

MOF synthesis using waste PET for applications of adsorption, catalysis and energy storage DOI Creative Commons
Hongmei Li, Jinming Lei, Liying Zhu

et al.

Green Energy & Environment, Journal Year: 2024, Volume and Issue: 9(11), P. 1650 - 1665

Published: June 10, 2024

Polyethylene terephthalate (PET) as one of non-degradable wastes has become a huge threat to the environment and human health. Chemical Recycle PET is an sustainable way release1,4-benzenedicarboxylic acid (BDC) monomer common used organic linker for synthesis functional Metal–organic-frameworks (PET-derived MOFs) such UiO-66, MIL-101, etc. This cost-effective "Waste-to-MOFs" model great significant be intensively investigated in past years. Attributes substantial porosity, specific surface area, exposed metal centers, uniform structure, flexible morphology render PET-derived MOFs are well-suited applications adsorption, energy storage, catalysis, among others. Herein, present work, we have summarized recent advances using ex-situ in-situ methods typical catalysis storage. Despite those improvements potential applications, challenges still remain development green economical routes fully utilize waste massive manufacture valuable MOF materials chemicals. review provides insights into conversion value-added materials, further suggests promising perspectives develop addressing environmental pollution crises.

Language: Английский

Citations

14

Multifunctional 3D-printed composites based on biopolymeric matrices and tomato plant (Solanum lycopersicum) waste for contextual fertilizer release and Cu(II) ions removal DOI Creative Commons
Roberto Scaffaro, Emmanuel Fortunato Gulino, Maria Clara Citarrella

et al.

Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 7(3)

Published: May 21, 2024

Abstract The production of tomatoes faces significant challenges, including the high amount waste generated during harvest stage and copper-contaminated soil due to pesticide use. To address these issues promote a more sustainable agriculture, innovative biodegradable green composites for contextual controlled fertilization Cu removal were produced by 3D-printing technology. These made incorporating NPK fertilizer flour tomato plant particles (SLP) into three different polymeric matrices: polylactic acid (PLA); commercial blend co-polyesters (Mater-Bi®, MB) their (MB/PLA, 50:50). Rheological characterization suggested potential processability all FDM. Morphological analysis printed samples confirmed good dispersion both filler fertilizer, which also acted as reinforcement MB MB/PLA composites. SLP moduli evaluated powder nanoindentation and, almost composites, theoretical Halpin-Tsai model satisfactorily fitted actual tensile moduli. decrease in release rate increase Cu(II) efficiency achieved using whole 3D-printed By selecting appropriate matrix particles, it was possible tune achieve copper absorption efficiency. Notably, containing displayed fastest highest Graphical abstract

Language: Английский

Citations

13

Adsorptive removal of heavy metals from wastewater using Cobalt-diphenylamine (Co-DPA) complex DOI Creative Commons

Mesfin Yimer,

Shagufi Naz Ansari,

Biniyam Abdu Berehe

et al.

BMC Chemistry, Journal Year: 2024, Volume and Issue: 18(1)

Published: Jan. 29, 2024

Abstract Heavy metals like Cadmium, Lead, and Chromium are the pollutants emitted into environment through industrial development. In this work, a new diphenylamine coordinated cobalt complex (Co-DPA) has been synthesized tested for its efficiency in removing heavy from wastewater, adsorption capacity was investigated. The effectiveness of removal by Co-DPA evaluated adjusting parameters, such as adsorbent dose, pH, initial concentration, period. metal concentrations real sample were 0.267, 0.075, 0.125 mg/L Cd 2+ , Pb Cr 3+ before using as-synthesized to treat wastewater. After being treated with concentration reduced 0.0129, 0.00028, 0.00054 respectively, 80 min. 95.6%, 99.5%, 99.5% respective metals. process fitted satisfactorily Freundlich isotherm R 2 (0.999, 0.997, 0.995) respectively. kinetic data obeyed pseudo-second order pseudo-first . Based on results obtained within framework study, it is concluded that good eliminate ions wastewater solution. general, promising material water. Graphical

Language: Английский

Citations

12

Wastewater treatment using Metal-Organic Frameworks (MOFs) DOI

Muhammad Husnain Manzoor,

Namisa Naz,

Syyeda Maimoona Ghayyoor Naqvi

et al.

Applied Materials Today, Journal Year: 2024, Volume and Issue: 40, P. 102358 - 102358

Published: Aug. 3, 2024

Language: Английский

Citations

12

Highlights in Interface of Wastewater Treatment by Utilizing Metal Organic Frameworks: Purification and Adsorption Kinetics DOI

Praveen Kumar,

Zahir Abbas,

Pawan Kumar

et al.

Langmuir, Journal Year: 2024, Volume and Issue: 40(10), P. 5040 - 5059

Published: Feb. 28, 2024

Polluted water has become a concern for the scientific community as it causes many severe threats to living beings. Detection or removal of contaminants present in wastewater and attaining purity that can be used various purposes are primary responsibility. Different treatment methods have already been purification sewage. There is need low-cost, highly selective, reusable materials efficiently remove pollutants purify contaminated water. In this regard, MOFs shown significant potential applications such supercapacitors, drug delivery, gas storage, pollutant adsorption, etc. The outstanding structural diversity, substantial surface areas, adjustable pore sizes make them superior candidates treatment. This Review provides an overview interaction science engineering (kinetic thermodynamic aspects with interactions) underpinning purification. First, fundamental strategies synthesis MOFs, different categories, their applicability summarized, followed by detailed explanation mechanisms. Finally, current challenges future outlooks research on MOF toward adsorption hazardous components discussed. A new avenue modifying characteristics separation materials, which will undoubtedly direct work, also summarized.

Language: Английский

Citations

11

Heterostructural covalent organic framework/polymer composite materials: Recent advances in multidisciplinary applications DOI
Minh Kim Nguyen,

Jin Seog Gwag,

Lam Nguyen‐Dinh

et al.

Nano Today, Journal Year: 2024, Volume and Issue: 55, P. 102211 - 102211

Published: March 4, 2024

Language: Английский

Citations

10

Synergistic sorption strategies: Ionic liquids-modified MOF matrices for adsorption processes DOI

Maryam Chafiq,

Siti Fatimah, Abdelkarim Chaouiki

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 351, P. 128056 - 128056

Published: May 22, 2024

Language: Английский

Citations

10