Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 124989 - 124989
Published: Dec. 1, 2024
Language: Английский
Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 124989 - 124989
Published: Dec. 1, 2024
Language: Английский
International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 277, P. 134136 - 134136
Published: July 31, 2024
Language: Английский
Citations
1Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(5), P. 113851 - 113851
Published: Aug. 15, 2024
Language: Английский
Citations
1Deleted Journal, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 12, 2024
A bio-based hydrogel is a complex compound that consists of natural biomaterials and widely applied for various therapeutic purposes. The modification from traditional to reformulated hydrogels has gained place at biomedical field due the growth benefits such as drug delivery, tissue engineering, regenerative medicine. Moreover, increasing global demand resulted in worldwide shortage mass formulations raised environmental awareness. By using instead synthetic ones, these minimize their negative effects on environment while simultaneously maximizing successful execution product. However, mechanisms governing degradation bioactivity hydrogels, which dictate release profiles, stability, effectiveness, are not yet comprehensively understood. Therefore, by analyzing recent progress ongoing challenges, this review will reveal how advanced quietly transforming future healthcare offering novel solutions pressing health problems.
Language: Английский
Citations
0ACS ES&T Engineering, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 22, 2024
Per- and polyfluoroalkyl substances (PFAS), persistent pollutants found in water sources worldwide, pose significant challenges to conventional remediation methods. This study presents a one-pot, high atom-economy synthesis of porphyrin-based cationic nanocages (oNCs) as selective, rapid efficient solution for PFAS removal, addressing critical gaps current treatment technologies. Using liquid chromatography–tandem mass spectrometry (LC-MS/MS), the nanocages─[oNC]8PF6, [Co2+-oNC]8PF6, [Co3+(N≡O)-oNC]8PF6─were evaluated their ability sorb mixture 38 PFAS, including emerging contaminants like GenX, from various matrices at concentration 50 ng/mL. The achieved exceptional removal efficiencies, with optimal results obtained when [oNC]8PF6 [Co2+-oNC]8PF6 were combined 1:4 ratio. created synergistic effect, enabling sorption both short- long-chain achieving average efficiencies 90% Nanopure groundwater, 80% influent sewage. nanocage consistently outperformed activated carbon, particularly complex such sewage, where carbon presented lower efficiency, especially perfluoroalkane sulfonamido substances. reached equilibrium within 15 min maintained performance across multiple methanolic regeneration cycles, highlighting operational durability. NMR spectroscopy computational studies revealed that occurs via hydrophobic electrostatic interactions, well partial intercalation, selectivity molecules bearing sulfonate sulfonamide head groups chain lengths five or more. Early stage eco-toxicological assessments confirmed environmental safety these nanocages, showing no adverse effects below 0.005 μM. By combining modular, scalable sustainable material synthesis, this sets new direction developing precise, environmentally responsible solutions.
Language: Английский
Citations
0Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 124989 - 124989
Published: Dec. 1, 2024
Language: Английский
Citations
0