Physical Chemistry Chemical Physics,
Journal Year:
2024,
Volume and Issue:
26(13), P. 9891 - 9905
Published: Jan. 1, 2024
According
to
circular
bioeconomy
principles,
the
use
of
kiwi
peels
remove
Direct
Blue
78
(DB)
from
water
is
investigated
during
this
work,
proposing
food
waste
as
a
recyclable
adsorbent
substrate.
ACS ES&T Engineering,
Journal Year:
2024,
Volume and Issue:
4(2), P. 250 - 268
Published: Jan. 23, 2024
Nuclear
power
provides
a
chance
for
the
decarbonization
of
global
energy-related
emissions.
However,
spent
fuel
produced
by
nuclear
reactors
contains
various
radionuclides,
which
require
further
disposal
and
treatment.
Therefore,
enrichment
separation
radionuclides
are
great
significance
recycling
utilization
resources.
Organic
polymer
materials
have
attracted
attention
due
to
their
excellent
physicochemical
properties
rapid
kinetics,
high
adsorption
capacity,
selectivity,
diverse
functionalization.
This
review
an
overview
use
pristine
polymers,
functionalized
polymer-based
composites
highly
efficient
different
kinds
(i.e.,
U,
Tc,
I).
The
synthesis
strategy,
ability,
related
mechanism
comprehensively
summarized.
structure–property
relationships
in
that
underpin
outstanding
environmental
remediation
performance
also
illustrated.
Finally,
challenges
perspectives
future
radionuclide
legacy
waste
management
reasonably
proposed,
aiming
design
functional
polymers
task-specific
applications.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 16, 2025
Abstract
Zeolitic
imidazolate
framework‐67
(ZIF‐67)
membranes
hold
great
promise
in
efficiently
separating
propene/propane
mixtures.
However,
achieving
highly
permselective
ZIF‐67
remains
challenging
due
to
unruly
crystal
nucleation
and
poor
grain
boundary
structure.
Herein,
a
magnetic‐field‐driven
approach
is
reported
fabricating
high‐quality
on
anodized
aluminum
oxide
substrates
at
room
temperature.
The
presence
of
magnetic
field
increases
the
rates
by
shortening
induction
period,
facilitates
orderly
rapid
migration
Co
2+
ions,
optimizes
crystallites
substrate,
inhibits
excessive
growth
grains.
These
factors
collectively
contribute
improving
structure
suppressing
inter‐grain
defects
MOF
membranes.
resulting
membranes,
with
thickness
less
than
480
nm,
exhibit
superior
propylene/propane
separation
performance,
featuring
factor
135
propylene
permeance
2.3
×
10
−8
mol
m
−2
s
−1
Pa
.
expected
greatly
promote
development
for
efficient
energy‐saving
separations.
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(9), P. 4185 - 4195
Published: Feb. 16, 2024
Posttreatment
of
pristine
metal–organic
frameworks
(MOFs)
with
suitable
vapor
may
be
an
effective
way
to
regulate
their
structures
and
properties
but
has
been
less
explored.
Herein,
we
report
interesting
example
in
which
a
crystalline
nonporous
Eu(III)-MOF
was
transferred
porous
amorphous
MOF
(aMOF)
via
iodine
adsorption–desorption
posttreatment,
the
resulting
aMOF
showed
improved
turn-on
sensing
respect
Ag+
ions.
The
Eu-MOF,
namely,
Eu-IPDA,
assembled
from
Eu(III)
4,4′-{4-[4-(1H-imidazol-1-yl)phenyl]pyridine-2,6-diyl}dibenzoic
acid
(H2IPDA)
exhibited
two-dimensional
(2D)
coordination
network
based
on
one-dimensional
secondary
building
blocks.
close
packing
2D
networks
gives
rise
three-dimensional
supramolecular
framework
without
any
significant
pores.
Interestingly,
Eu-IPDA
could
absorb
molecules
when
crystals
were
placed
at
85
°C,
adsorption
capacity
1.90
g/g,
is
comparable
those
many
MOFs
large
BET
surfaces.
attributed
strong
interactions
among
molecule,
carboxy
group,
N-containing
group
leads
amorphization
framework.
After
immersion
iodine-loaded
EtOH,
approximately
89.7%
removed,
MOF,
denoted
as
a-Eu-IPDA.
In
addition,
remaining
a-Eu-IPDA
causes
luminescent
quenching
fluorescence
emission
region
center
compared
that
Eu-IPDA.
luminescence
intensity
water
suspensions
significantly
enhanced
ions
added,
detection
limit
4.76
×
10–6
M,
1000
times
It
also
anti-interference
ability
over
common
competitive
metal
potential
sense
natural
bodies
traditional
Chinese
medicine
preparations.
A
mechanistic
study
between
absorbed
iodine,
carboxylate
N
atoms
all
contribute
performance
Langmuir,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Aug. 13, 2024
Heavy
metal
ion
wastewater
is
a
pressing
and
inescapable
issue
that
closely
related
to
human
health
ecological
security
due
its
toxicity,
carcinogenicity,
the
unmanageable
property
of
this
type
wastewater.
Metal–Organic
Frameworks
(MOFs)
are
class
crystalline
nanoporous
materials
with
flexible
designability
controllability,
showing
great
potential
in
field
adsorption
purification
heavy
metals
In
Perspective,
we
first
discuss
harm
different
ions
briefly
expound
virtues
MOFs
for
pollutant
adsorption.
Then,
mainly
summarize
recent
advances
construction
metal-based
(Zr-based,
Zn-based,
Co-based,
Al-based,
etc.)
their
research
progress
Furthermore,
various
types
MOF
additives
can
often
be
effectively
applied
by
functional
modification
or
other
composition.
Additionally,
several
commonly
used
kinetics
isotherm
models
also
detailed
help
an
in-depth
understanding
mechanism.
Finally,
challenges
opportunities
additionally
discussed,
review
may
provide
new
insight
water
applications.