Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 671, P. 664 - 679
Published: May 27, 2024
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 671, P. 664 - 679
Published: May 27, 2024
Language: Английский
International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: unknown, P. 140340 - 140340
Published: Jan. 1, 2025
Language: Английский
Citations
2Colloids and Surfaces C Environmental Aspects, Journal Year: 2025, Volume and Issue: unknown, P. 100055 - 100055
Published: Jan. 1, 2025
Language: Английский
Citations
0International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: unknown, P. 142175 - 142175
Published: March 1, 2025
Language: Английский
Citations
0ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(17)
Published: April 29, 2025
Abstract Small‐sized palladium nanoparticles (PdNPs) are highly active nanocatalysts and have attracted great interest for many years. However, preparing size‐controllable PdNPs is still challenging. Here, ultrafine air‐stable PdNPs‐1/2 (2.0 ± 0.3/1.2 0.4 nm) stabilized by multiple nucleophilic ligands (phosphines, thiols, anions) were prepared, their sizes could be successfully regulated simply varying anionic (SbF 6 − or BF 4 ). We further investigated catalytic activities compared them with identically ligated tri‐palladium clusters [Pd 3 ] + ‐1/2 . These homogeneous presented superior both the Suzuki–Miyaura cross‐coupling (SMCC) 4‐nitrophenol reduction reactions. The PdNPs‐1 exhibited highest activity reactions good applicability to different substrates, reaction rate constant reached 1.10 × 10 −2 S −1 reduction. results revealed that employment of significantly affects size synergistic activities. This work will open possibilities controllable size, dispersity, stability a broad range applications.
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 671, P. 664 - 679
Published: May 27, 2024
Language: Английский
Citations
1