ACS ES&T Water,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 16, 2024
Antibiotics
(ANTs)
deep
purification
using
pyrolytic
carbons
(PyCs)
has
been
demonstrated
as
a
promising
strategy.
Since
PyCs
structural
modification
is
the
key
to
enhancing
their
capacity,
underlying
mechanisms
need
be
further
clarified.
Here,
three
nitrogen-doped
porous
with
solid-sphere,
hollow-sphere,
and
bowl-shape
were
prepared
soft-template-KHCO3
copyrolysis
method.
The
bowl-shaped
bNPyC,
BET/micropore
surface
area
of
2072.79/1415.9
cm2/g,
showed
highest
adsorption
capacity
for
sulfamethoxazole
(SMZ,
Qfitted,
max
=
5.44)
ciprofloxacin
(CIP,
3.23
mmol/g)
rapid
equilibrium.
Despite
slight
N
doping
(0.69%),
SMZ/CIP
on
bNPyC
improved
significantly
48.6%/64.2%.
Additionally,
outperformed
other
reported
in
Q/N
exposure
value.
exhibited
excellent
performance
ANTs
across
wide
pH
range
2–10,
particularly
CIP.
interactions
semiquantitatively
identified
by
probe
competition
experiments
confirmed
spectra
characterizations
density
functional
theory
calculations.
Mechanism
analysis
revealed
that
facilitates
not
only
π–π
EDA
but
also
charge-assisted
H-bond
between
ANTs.
anti-interference
properties,
recyclability,
universality
removal
demonstrated.
These
findings
may
guide
design
deepen
our
understanding
structure–property
mechanism
ANT
PyCs.
Nanomaterials,
Journal Year:
2024,
Volume and Issue:
14(23), P. 1933 - 1933
Published: Nov. 30, 2024
With
the
growth
of
global
population
and
acceleration
industrialization,
problem
water
pollution
has
become
increasingly
serious,
posing
a
major
threat
to
ecosystem
human
health.
Traditional
treatment
technologies
make
it
difficult
cope
with
complex
pollution,
so
scientific
community
is
actively
exploring
new
efficient
methods.
Biochar
(BC),
as
low-cost,
green
carbon-based
material,
exhibits
good
adsorption
catalytic
properties
in
due
its
porous
structure
abundant
active
functional
groups.
However,
BC's
pure
or
capacity
limited,
researchers
have
dramatically
enhanced
performance
through
modification
means,
such
loading
metals
heteroatoms.
In
this
paper,
we
systematically
review
recent
applications
BC
modified
materials
for
adsorption,
Fenton-like,
electrocatalytic,
photocatalytic,
sonocatalytic
systems,
discuss
their
adsorption/catalytic
mechanisms.
most
research
field
at
laboratory
simulation
stage
still
needs
much
improvement
before
can
be
applied
large-scale
wastewater
treatment.
This
improves
understanding
pollutant
mechanisms
BC-based
materials,
analyzes
limitations
current
studies,
investigates
future
directions.
Water,
Journal Year:
2024,
Volume and Issue:
16(17), P. 2379 - 2379
Published: Aug. 24, 2024
Olive
mill
waste
(olive
pomace,
OP,
and
olive
stone,
OS)
was
used
in
this
work
to
produce
adsorbents
for
the
removal
of
five
phenolic
acids
typically
found
wastewater.
OP
OS
were
subjected
different
treatments
(combined
or
not)
that
chemically
modified
(NaOH)
physically
by
two
methods,
incipient
wetness
impregnation
(IWI)
hydrothermal
deposition
(HD),
even
biochar
production
obtaining
a
total
16
materials.
The
materials
characterized
analytical
techniques
such
as
N2
absorption,
scanning
electron
microscopy,
infrared
spectroscopy,
pH
zero-potential
charge.
mixture
evaluate
batch
conditions
adsorption
capacity
prepared
with
IWI
(OSM-IWI)
HD
(BOS-HD)
presented
better
at
157.1
163.6
mg/g
acids,
respectively,
from
200
mg/g.
For
some
materials,
surface
area
cannot
be
correlated
capacity,
unlike
pHzpc,
where
high
values
fit
rates.
spectroscopy
profile
indicates
presence
O-H
N-H
functional
groups
and,
last
one,
red-shifted
preparation
compared
one.
In
addition
this,
material
can
suitably
compounds.
ACS ES&T Water,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 16, 2024
Antibiotics
(ANTs)
deep
purification
using
pyrolytic
carbons
(PyCs)
has
been
demonstrated
as
a
promising
strategy.
Since
PyCs
structural
modification
is
the
key
to
enhancing
their
capacity,
underlying
mechanisms
need
be
further
clarified.
Here,
three
nitrogen-doped
porous
with
solid-sphere,
hollow-sphere,
and
bowl-shape
were
prepared
soft-template-KHCO3
copyrolysis
method.
The
bowl-shaped
bNPyC,
BET/micropore
surface
area
of
2072.79/1415.9
cm2/g,
showed
highest
adsorption
capacity
for
sulfamethoxazole
(SMZ,
Qfitted,
max
=
5.44)
ciprofloxacin
(CIP,
3.23
mmol/g)
rapid
equilibrium.
Despite
slight
N
doping
(0.69%),
SMZ/CIP
on
bNPyC
improved
significantly
48.6%/64.2%.
Additionally,
outperformed
other
reported
in
Q/N
exposure
value.
exhibited
excellent
performance
ANTs
across
wide
pH
range
2–10,
particularly
CIP.
interactions
semiquantitatively
identified
by
probe
competition
experiments
confirmed
spectra
characterizations
density
functional
theory
calculations.
Mechanism
analysis
revealed
that
facilitates
not
only
π–π
EDA
but
also
charge-assisted
H-bond
between
ANTs.
anti-interference
properties,
recyclability,
universality
removal
demonstrated.
These
findings
may
guide
design
deepen
our
understanding
structure–property
mechanism
ANT
PyCs.
