Incorporating Mixed-Ligand Zeolitic Imidazolate Framework into Polydimethyldiethoxysilane (PDMDES) Membrane for Enhancing Alcohol Pervaporation Recovery DOI
Xiaole Chen, Qulan Zhou, Yafei Zhang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 19, 2024

In the present study, a zeolitic imidazolate framework with mixed ligands, ZIF-8-90, was synthesized and embedded into an ultrathin polydimethyldiethoxysilane (PDMDES) matrix to prepare ZIF-8-90/PDMDES membrane (MMM) for enhanced recovery of alcohols from dilute aqueous solutions via pervaporation, using facile solution coating method. The ZIF-8-90 particles demonstrated superior hydrophobicity thermal stability compared those both ZIF-8 ZIF-90 particles. Furthermore, hydrophobicity, stability, sorption ability MMM were significantly improved, attributed incorporation mixed-ligand ZIF-8-90. Notably, MMMs displayed two distinct cross-sectional morphologies: (1) enveloped by PDMDES polymer forming filler bulges (2) accumulation resembling brick-wall-like structure. incorporating 2.5 wt % exhibited optimal performance among fabricated various loadings, spanning 0 3.2 %. effects feed concentrations operation temperatures systematically investigated. best pervaporation achieved ZIF-8-90-filled MMM, effectively separating 5.0 ethanol/water mixture at 60 °C, yielding distinguished total flux 7.70 kg·m–2·h–1, improved separation factor 9.96, extraordinarily high PSI 68.99 kg·m–2·h–1. Comparative analyses highlighted over ZIF-8/PDMDES ZIF-90/PDMDES other MMMs, underscoring its potential practical applications in alcohol recovery.

Language: Английский

One-pot synthesis of necklace-like MOF@CNTs: a universal strategy for enhancing molecular separation performance in mixed-matrix membranes DOI Creative Commons
Xuemeng Jia, Ziqi Song,

Qiaomei Li

et al.

RSC Applied Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A simple one-pot synthesis strategy that prepares necklace-like MOF@CNTs. CNTs as a “lead wire” with substantial aspect ratios were used to induce the self-assembly growth of MOFs “beads” along CNTs' longitudinal axis.

Language: Английский

Citations

0
Bioethanol production from cassava fed-batch fermentation in pervaporation membrane bioreactor with permeate fractional condensation DOI

Haoji Jiang,

Lu Han,

Wenda Liu

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 128807 - 128807

Published: July 14, 2024

Language: Английский

Citations

1
Modification Methods Categorization of Polymeric Membranes for Pervaporation: A Review DOI

Milad Nouri,

Ali Poorkhalil, Hasan Farrokhzad

et al.

Polymer Reviews, Journal Year: 2024, Volume and Issue: unknown, P. 1 - 28

Published: Aug. 27, 2024

The membrane, a core element in pervaporation technology, is of utmost importance for its advancement. Membrane modification one the most effective means achieving an efficient which crucial progress this technology. High selectivity and flux can be achieved by modifying membrane or polymer changing properties such as surface energy, roughness, arrangement chains, network. Hence, recent publications on various methods polymeric membranes context applications are meticulously summarized categorized, aging fouling factors have been mentioned review. This evaluation provided thorough summary benefits drawbacks each method. Among numerous techniques, mixing, crosslinking, commonly employed to modify specifically tailored processes.

Language: Английский

Citations

1
Incorporating Mixed-Ligand Zeolitic Imidazolate Framework into Polydimethyldiethoxysilane (PDMDES) Membrane for Enhancing Alcohol Pervaporation Recovery DOI
Xiaole Chen, Qulan Zhou, Yafei Zhang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 19, 2024

In the present study, a zeolitic imidazolate framework with mixed ligands, ZIF-8-90, was synthesized and embedded into an ultrathin polydimethyldiethoxysilane (PDMDES) matrix to prepare ZIF-8-90/PDMDES membrane (MMM) for enhanced recovery of alcohols from dilute aqueous solutions via pervaporation, using facile solution coating method. The ZIF-8-90 particles demonstrated superior hydrophobicity thermal stability compared those both ZIF-8 ZIF-90 particles. Furthermore, hydrophobicity, stability, sorption ability MMM were significantly improved, attributed incorporation mixed-ligand ZIF-8-90. Notably, MMMs displayed two distinct cross-sectional morphologies: (1) enveloped by PDMDES polymer forming filler bulges (2) accumulation resembling brick-wall-like structure. incorporating 2.5 wt % exhibited optimal performance among fabricated various loadings, spanning 0 3.2 %. effects feed concentrations operation temperatures systematically investigated. best pervaporation achieved ZIF-8-90-filled MMM, effectively separating 5.0 ethanol/water mixture at 60 °C, yielding distinguished total flux 7.70 kg·m–2·h–1, improved separation factor 9.96, extraordinarily high PSI 68.99 kg·m–2·h–1. Comparative analyses highlighted over ZIF-8/PDMDES ZIF-90/PDMDES other MMMs, underscoring its potential practical applications in alcohol recovery.

Language: Английский

Citations

0