Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132127 - 132127
Published: Feb. 1, 2025
Language: Английский
Citations
3Materials Today Communications, Journal Year: 2024, Volume and Issue: 41, P. 110913 - 110913
Published: Nov. 6, 2024
Language: Английский
Citations
4Polymers, Journal Year: 2025, Volume and Issue: 17(3), P. 334 - 334
Published: Jan. 26, 2025
Vacancy defect graphitic carbon nitride (g-C3N4) and conjugated polyimide (PI) polymer photocatalysts have become increasingly recognized as metal-free featuring an appropriate bandgap. The narrow absorption spectrum of visible light the rapid recombination rate photoexcited charge carriers in PI polymers g-C3N4 impede its photocatalytic performance. presence oxygen vacancies (OVs) photocatalysts, well nitrogen (NVs) (CVs) g-C3N4, can significantly enhance migration photogenerated electrons. Adding to improve electronic structure band gap width greatly efficiency g-C3N4. Defect engineering is important for increasing ability PI-polymer There remains a notable absence thorough review papers covering synthesis, characterization, applications vacancy-rich photocatalysis. This paper examines roles OVs PI-polymer, NVs, CVs thoroughly summarizes preparation approaches employed before after, during polymerization. scrutinizes spectroscopic characterization techniques, such EPR, XPS, PAS, XRD, FTIR, NMR, vacancy analysis. We also reviewed role vacancies, which include absorption, carrier separation, transfer dynamics. could serve comprehensive understanding, vacancy-engineered design framework, practical guide synthesizing characterizing.
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 133041 - 133041
Published: April 1, 2025
Language: Английский
Citations
0Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 116745 - 116745
Published: April 1, 2025
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 682, P. 446 - 459
Published: Dec. 1, 2024
Language: Английский
Citations
2Catalysts, Journal Year: 2024, Volume and Issue: 14(9), P. 636 - 636
Published: Sept. 19, 2024
Semiconductors with visible light catalytic characteristics can realize the degradation of pollutants, CO2 reduction, and hydrogen preparation in sunlight. They have huge application value fields environmental repair green energy. Graphite phase nitride (g-C3N4, CN) is widely used various such as photocatalytic pollutants due to its suitable gap width, easy preparation, low cost, fast response, rich surface activity sites. However, absorption rate ordinary CN on low, carriers are recombination, making lower optical activity. Therefore, order improve CN, it necessary make modification. This article first introduces several main methods for current modification including size regulation, catalyst embedding, defect introduction, heterostructure construction, etc., then summarizes related mechanisms CN. Finally, some challenges development prospects applications proposed.
Language: Английский
Citations
1Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 130928 - 130928
Published: Dec. 1, 2024
Language: Английский
Citations
1Journal of Chemical Technology & Biotechnology, Journal Year: 2024, Volume and Issue: 99(11), P. 2339 - 2350
Published: Aug. 7, 2024
Abstract BACKGROUND The presence of pharmaceutical active substances such as diclofenac (DCF) and clofibric acid (CA) in aquatic environments poses significant ecological threats. Existing treatments have not fully explored the impact CA on DCF removal efficiency. This research introduces nZVI/CTAB‐SBE@C, a novel adsorbent developed from industrial spent bleaching earth (SBE), modified with cetyltrimethylammonium bromide (CTAB) nano zero‐valent iron (nZVI), enhancing both adsorption degradation CA. RESULTS study investigated capabilities nZVI/CTAB‐SBE@C for coexisting system. Systematic examinations were conducted effects various parameters, including reaction time, dosage, temperature, actual wastewater, humic content ions. Results indicated that significantly enhanced efficiency, achieving an optimal rate 87.3% under conditions time 2 h, dosage 5 g L −1 temperature 25 °C. Moreover, interactions between Al 3+ ions matrix notably improved efficiencies Analysis revealed facilitated new pathways DCF, hydroxylation decarboxylation reactions. Additionally, reduced toxicity intermediates, environmental safety compared to systems containing only DCF. CONCLUSION effectively transforms waste into efficient adsorbent. boosts efficiency but also promotes its safer degradation, thereby reducing contaminants. © 2024 Society Chemical Industry (SCI).
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 130855 - 130855
Published: Dec. 1, 2024
Language: Английский
Citations
0