Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 28, 2025

Abstract CH 3 OH is the most desired product of photocatalytic 4 conversion. The prominent metal‐decorated photocatalyst challenging in both high yield and selectivity for products due to over‐oxidation by •OH mechanism. Here, interstitial Zn fabricated into i O induce formation atom island rapid single electron reduction 2 •OOH instead selective combination with methyl OOH. AuPd alloy simultaneously decorated on surface tuning OOH adsorption OH. synergy achieve a tandem reaction pathway (CH →CH OOH→CH OH) an unprecedented 2444 mmol g −1 h (or 8800 µmol cat ) 98.3% selectivity, which bypasses mechanism An apparent quantum efficiency 18.53% at 370 nm conversion are super reported systems. Thus, this work provides new strategy synergetic metal photocatalysts through mediate oxidation

Language: Английский