ACS Sensors,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 25, 2025
Perfluoroisobutyronitrile
(C4F7N),
an
eco-friendly
insulating
gas,
has
been
extensively
utilized
in
diverse
gas-insulated
equipment
(GIE)
to
replace
the
most
potent
greenhouse
gas
SF6.
Nonetheless,
given
low
toxicity
of
C4F7N,
potential
leakage
risk
at
a
high-pressure
operational
environment
cannot
be
overlooked,
making
development
highly
sensitive
sensors
for
leak
detection
essential.
Herein,
Co3O4
was
selected
as
specific
sensing
material
C4F7N
based
on
density
functional
theory
screening.
The
Co3O4-based
sensor
prepared,
and
its
response
performance
systematically
evaluated.
interaction
mechanism
between
also
examined
by
oxygen
vacancy
theory.
demonstrates
limit
0.15
ppm
optimal
operating
temperature
300
°C,
exhibiting
exceptional
selectivity
repeatability,
with
stability
time
55.5
s
recovery
1478
s.
sensor's
application
under
actual
working
settings
validated
using
simulated
test.
Relevant
results
provide
guidance
monitoring
C4F7N-based
GIE.
Sensors,
Journal Year:
2025,
Volume and Issue:
25(5), P. 1415 - 1415
Published: Feb. 26, 2025
Transition
metal
oxides
(e.g.,
MnOx)
can
effectively
promote
the
redox
reactions
of
heavy
ions
through
abundant
valence
changes.
However,
relatively
few
studies
have
been
conducted
on
application
MnOx
for
detection
Cd2+
without
pre-enrichment
conditions.
For
this
reason,
in
study,
was
grown
situ
a
carbon
cloth
substrate
by
one-step
electrodeposition.
The
effect
composition
and
its
variation
performance
systematically
investigated.
morphology,
structure,
chemical
materials
were
fully
characterized
scanning
electron
microscopy
(SEM),
X-ray
diffraction
(XRD),
photoelectron
spectroscopy
(XPS).
results
show
that
deposition
not
only
significantly
increased
active
surface
area
electrodes
but
also
facilitated
transfer
transition
Mn2+/Mn3+↔Mn3+/Mn4+.
water
samples
be
successfully
achieved
pre-enrichment,
electrode
has
good
stability
reproducibility.
This
study
provides
new
design
idea
applying
reference
further
optimization
electrochemical
sensors.
ACS Sensors,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 25, 2025
Perfluoroisobutyronitrile
(C4F7N),
an
eco-friendly
insulating
gas,
has
been
extensively
utilized
in
diverse
gas-insulated
equipment
(GIE)
to
replace
the
most
potent
greenhouse
gas
SF6.
Nonetheless,
given
low
toxicity
of
C4F7N,
potential
leakage
risk
at
a
high-pressure
operational
environment
cannot
be
overlooked,
making
development
highly
sensitive
sensors
for
leak
detection
essential.
Herein,
Co3O4
was
selected
as
specific
sensing
material
C4F7N
based
on
density
functional
theory
screening.
The
Co3O4-based
sensor
prepared,
and
its
response
performance
systematically
evaluated.
interaction
mechanism
between
also
examined
by
oxygen
vacancy
theory.
demonstrates
limit
0.15
ppm
optimal
operating
temperature
300
°C,
exhibiting
exceptional
selectivity
repeatability,
with
stability
time
55.5
s
recovery
1478
s.
sensor's
application
under
actual
working
settings
validated
using
simulated
test.
Relevant
results
provide
guidance
monitoring
C4F7N-based
GIE.