2D Membranes Interlayered with Bimetallic Metal–Organic Frameworks for Lithium Separation from Brines DOI

Furong Yuan,

Qifeng Gao,

Zixiao Lv

et al.

Nano Letters, Journal Year: 2024, Volume and Issue: 24(45), P. 14346 - 14354

Published: Oct. 29, 2024

Efficient lithium extraction from salt lakes is essential for a sustainable resource supply. This study tackles the challenge of separating Li+ Mg2+ in complex brines by innovatively integrating two-dimensional (2D) graphene oxide (GO) with bimetallic metal–organic frameworks (MOFs). Zn2+ and Co2+ ions are confined within GO interlayers through an situ synthesis, forming 2D Zn-Co MOFs/GO membrane (Zn-Co-GOM). design exploits unique advantages MOFs, including enhanced structural stability superior ion separation capabilities due to synergistic effects Zn Co. The Zn-Co-GOM demonstrates impressive factor 191 over Mg2+, significantly surpassing traditional membranes. exceptional selectivity achieved combination size exclusion transport energy barriers. Our approach not only enhances practical application technology but also provides valuable insights into underlying mechanisms.

Language: Английский

Lignosulfonate-based adsorbents for selective Mg2+ removal from Mg2+/Li+ mixture in water with high efficiency and reusability DOI

Estefanía Oyarce,

Plinio Cantero-López, Maritza Páez

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 131828 - 131828

Published: Jan. 1, 2025

Language: Английский

Citations

1

DFT calculation and experiments for Li+/H+ ion-exchange on titanium-based lithium ion-sieves DOI

Mengxiang Lu,

Miao Yao, Ying Yang

et al.

Chemical Engineering Science, Journal Year: 2024, Volume and Issue: 300, P. 120619 - 120619

Published: Aug. 15, 2024

Language: Английский

Citations

4

Factors affecting the efficiency of electrochemical lithium extraction: A systematic review from materials to processes technology DOI
Junyi Zhang,

Tiandong Chen,

Luxiang Ma

et al.

Desalination, Journal Year: 2025, Volume and Issue: unknown, P. 118570 - 118570

Published: Jan. 1, 2025

Language: Английский

Citations

0

Ionic liquid-assisted highly selective lithium extraction from magnesium-rich brines using phenyl phosphate DOI

Yaoxian Hu,

Hui Su, Wensen Liu

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132245 - 132245

Published: Feb. 1, 2025

Language: Английский

Citations

0

Solid Wastes from Geothermal Energy Production and Implications for Direct Lithium Extraction DOI Creative Commons
William T. Stringfellow, Mary Kay Camarillo

Energies, Journal Year: 2025, Volume and Issue: 18(6), P. 1359 - 1359

Published: March 10, 2025

Direct lithium extraction (DLE) of brines after geothermal power production offers opportunities to produce environmentally benign “green” lithium; however, some environmental impact is inevitable. We examined solid waste at plants in southern California that are also locations for planned DLE facilities. Currently, the this region approximately 79,800 metric tons (wet weight) per year waste, which represents about 28 GWh net electricity or 500 mg solids kg brine. Approximately 15% requires management as hazardous waste. Solids produced during represent 0.2% total dissolved Lithium will require removal silica, iron, and other metals part process. Using a mass balance approach, we calculate precipitation silica could up an additional 6800 Calcium occurs very high concentrations, amount disposed landfills be dependent on calcium removed recovery. Our analysis shows evaluation brine chemistry context process useful evaluating potential impacts producing from brines.

Language: Английский

Citations

0

Covalent Organic Framework Membranes for Lithium Extraction: Facilitated Ion Transport Strategies to Enhance Selectivity DOI

Da Lei,

Yongjie Zhu, Lan‐Lan Lou

et al.

Materials Horizons, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Mechanistic design of COF membranes enables high-selectivity ion transport for lithium extraction via diffusion and electrodialysis.

Language: Английский

Citations

0

Applications of crown ether-based materials for enhancing lithium recovery from brines DOI
Xiaochun Yin, Pei Xu, Huiyao Wang

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 133093 - 133093

Published: April 1, 2025

Language: Английский

Citations

0

Inaccuracy principle and dissolution mechanism of lithium iron phosphate for selective lithium extraction from brines DOI
Shiyu Zhou,

Penglin Wang,

Siyuan Tang

et al.

Desalination, Journal Year: 2024, Volume and Issue: unknown, P. 118153 - 118153

Published: Sept. 1, 2024

Language: Английский

Citations

3

Life-Cycle Analysis of Lithium Chemical Production in the United States DOI Creative Commons
Rakesh Iyer, Jarod C. Kelly

RSC Sustainability, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

The life-cycle carbon emissions of Li-chemical production from alternative clays and low Li-content brines in the United States lie between impacts its two conventional sources: Salar spodumene ores.

Language: Английский

Citations

3

Preparation of zirconium-doped titanium ion sieve composites and lithium adsorption from salt-lake brine DOI

Zhongyi Shen,

Shumao Qi,

Chenxiao Hong

et al.

Desalination, Journal Year: 2025, Volume and Issue: unknown, P. 118618 - 118618

Published: Jan. 1, 2025

Language: Английский

Citations

0