Hybrid System of Polystyrene and Semiconductor for Organic Electronic Applications DOI Open Access
Zhengran He, Sheng Bi, Kyeiwaa Asare‐Yeboah

et al.

Processes, Journal Year: 2024, Volume and Issue: 12(9), P. 1944 - 1944

Published: Sept. 10, 2024

While organic semiconductors hold significant promise for the development of flexible, lightweight electronic devices such as thin-film transistors (OTFTs), photodetectors, and gas sensors, their widespread application is often limited by intrinsic challenges. In this article, we first review these challenges in electronics, including low charge carrier mobility, susceptibility to environmental degradation, difficulties achieving uniform film morphology crystallinity, well issues related poor interface quality, scalability, reproducibility that further hinder commercial viability. Next, focus on reviewing hybrid system comprising an semiconductor polystyrene (PS) address By examining interactions PS a polymer additive with several benchmark pentacene, rubrene, 6,13-bis(triisopropylsilylethynyl) pentacene (TIPS pentacene), 2,8-difluoro-5,11-bis(triethylsilylethynyl) anthradithiophene (diF-TES-ADT), 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT), showcase versatility enhancing crystallization, thin morphology, phase segregation, electrical performance devices. This aims highlight potential semiconductor/PS overcome key thereby paving way broader adoption next-generation

Language: Английский

Polymer Materials for Optoelectronics and Energy Applications DOI Open Access
Ju Won Lim

Materials, Journal Year: 2024, Volume and Issue: 17(15), P. 3698 - 3698

Published: July 26, 2024

This review comprehensively addresses the developments and applications of polymer materials in optoelectronics. Especially, this introduces how absorb, emit, transfer charges, including exciton–vibrational coupling, nonradiative radiative processes, Förster Resonance Energy Transfer (FRET), energy dynamics. Furthermore, it outlines charge trapping recombination draws corresponding practical implications. The following section focuses on application organic optoelectronics devices highlights detailed structure, operational principle, performance metrics photovoltaic cells (OPVs), light-emitting diodes (OLEDs), photodetectors, transistors detail. Finally, study underscores transformative impact evolution optoelectronics, providing a comprehensive understanding their properties, mechanisms, diverse that contribute to advancing innovative technologies field.

Language: Английский

Citations

10
A Low-Voltage Solution-Processed Organic Small Molecule Memristor Based on TIPS Pentacene DOI

Nikhitha Rajan,

Indranil Maity, Samayun Saikh

et al.

ACS Applied Electronic Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 7, 2025

Organic small molecule-based memristors offer the advantage of low-cost, large-area fabrication. Despite this advantage, uncertainty in electrical switching mechanisms and device reproducibility coupled with stability issues different operating environments impede further development these organic memory devices. Moreover, potential barrier height at interface between electrode active material is crucial controlling charge dynamics. In report, an environmentally stable, solution-processed, molecule 6,13-bis(triisopropylsilylethynyl) pentacene (TIPS Pentacene)-based memristor has been fabricated two top electrodes Au Ag. Ag as a shown characteristics bipolar nonvolatile low set voltage around 0.5 V. Besides lower voltage, exhibits high retention (>104 s) good ON/OFF ratio. contrast, devices showed no resistive behavior. The mechanism also investigated, it found to be governed by trapping/detrapping conjunction trap-controlled space-charge-limited-conduction model. finding supported capacitance measurements on device. These results indicate strong solution-processed TIPS Pentacene for non-volatile applications pave way power consumption data storage electronics.

Language: Английский

Citations

0
Organic Room‐Temperature Phosphorescent Materials for High‐Performance Floating Gate Photomemory and Synaptic Phototransistor Applications DOI Creative Commons

Pin‐Hsuan Huang,

Yi‐Hsun Weng,

Ya‐Shuan Wu

et al.

Published: March 24, 2025

Room‐temperature phosphorescent (RTP) materials, owing to their long‐lived triplet exciton characteristics, exhibit significant potential for applications in photomemory and artificial photosynapses. However, fluorescent materials are often constrained by nonradiative losses stability issues, limiting feasibility high‐performance applications. To address these challenges, this study employs electron‐deficient RTP 3,3′, 4,4′‐diphenyl sulfone tetracarboxylic dianhydride (DPS), 4,4′‐benzophenone (BTDA), combined with the insulating polymer of polystyrene, as floating gate layer. The memory devices photosynaptic systems phenomenon exceptional photoresponse. results demonstrate that DPS BTDA achieve ≈10 5 10 6 ratios under light‐assisted programming. Furthermore, system exhibits superior paired‐pulse facilitation image recognition accuracy, underscoring its neural network After 100 learning epochs processing through two denoising arrays ( n = 2), achieved a significantly improved accuracy 88.3%. These findings highlight high‐efficiency performance provide promising avenue synaptic phototransistors.

Language: Английский

Citations

0
Influence of surface passivation aiming towards enhancing the performance of organic phototransistor fabricated using oriented thin films of PFO-DBT DOI

Sidhi G. Ramer,

Kumar Gaurav,

I. A. Palani

et al.

Synthetic Metals, Journal Year: 2025, Volume and Issue: unknown, P. 117869 - 117869

Published: March 1, 2025

Language: Английский

Citations

0
Study on the ground-state to excited-state charge characteristics of bipolar and n-type bisisoindigo-based D-A conjugated polymers DOI

Kaiqiang Huang,

William Ka Kei Wu, Yingying Cheng

et al.

Pigment & Resin Technology, Journal Year: 2025, Volume and Issue: unknown

Published: April 23, 2025

Purpose Electronic excitation and charge transfer processes are fundamentally interconnected, critically determining the optoelectronic performance of organic semiconductors. The purpose this study is to systematically examine donor–acceptor (D-A) conjugated polymers at molecular level, with particular focus on elucidating distribution patterns transition mechanisms establish advanced design principles for these materials. Design/methodology/approach A series bipolar n-type bisisoindigo (BIID)-based D-A were investigated from a perspective using density functional theory time-dependent methods. ground excited state characteristics analyzed correlate structures electronic properties. Findings This demonstrates that aza-incorporation fluoro-substitution have relatively minor effects structure, latter causing only slight increase in n-p* transitions. In marked contrast, oxa-incorporation shows substantial impact by significantly expanding electron hole vinyl region. modification effectively establishes p-electron bridge between receptor units while simultaneously enhancing both structural fragments. Originality/value investigation introduces methodologically significant approach expedited rigorous screening high-performance, air-stable devices.

Language: Английский

Citations

0
Hybrid System of Polystyrene and Semiconductor for Organic Electronic Applications DOI Open Access
Zhengran He, Sheng Bi, Kyeiwaa Asare‐Yeboah

et al.

Processes, Journal Year: 2024, Volume and Issue: 12(9), P. 1944 - 1944

Published: Sept. 10, 2024

While organic semiconductors hold significant promise for the development of flexible, lightweight electronic devices such as thin-film transistors (OTFTs), photodetectors, and gas sensors, their widespread application is often limited by intrinsic challenges. In this article, we first review these challenges in electronics, including low charge carrier mobility, susceptibility to environmental degradation, difficulties achieving uniform film morphology crystallinity, well issues related poor interface quality, scalability, reproducibility that further hinder commercial viability. Next, focus on reviewing hybrid system comprising an semiconductor polystyrene (PS) address By examining interactions PS a polymer additive with several benchmark pentacene, rubrene, 6,13-bis(triisopropylsilylethynyl) pentacene (TIPS pentacene), 2,8-difluoro-5,11-bis(triethylsilylethynyl) anthradithiophene (diF-TES-ADT), 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT), showcase versatility enhancing crystallization, thin morphology, phase segregation, electrical performance devices. This aims highlight potential semiconductor/PS overcome key thereby paving way broader adoption next-generation

Language: Английский

Citations

3