Green Analytical Chemistry,
Journal Year:
2024,
Volume and Issue:
10, P. 100132 - 100132
Published: July 27, 2024
Emerging
pollutants
pose
an
increasing
threat
to
environmental
quality
and
human
health,
necessitating
significant
advancements
in
analytical
methodologies.
Hydrophobic
deep
eutectic
solvent
(HDES)
functionalized
magnetic
nanoparticles
(MNP)
or
MHDES
represent
a
promising
advancement
the
field
of
micro-extraction
for
pollutant
detection
across
diverse
matrices.
This
review
explores
synthesis,
characterization,
application
as
sorbents
efficient
extraction
preconcentration
emerging
pollutants,
including
pharmaceuticals,
pesticides,
plasticizers,
heavy
metals.
The
functionalization
MNP
with
HDES
addresses
challenges
agglomeration
stability,
enhancing
their
performance
non-polar
compound
extraction.
Additionally,
AGREEprep
greenness
metric
tool
highlights
benefits
this
method,
emphasizing
reduced
usage,
lower
energy
consumption,
minimal
waste
production.
novel
approach
not
only
improves
efficacy
selectivity
but
also
broadens
applicability
monitoring
health
risk
assessment,
offering
greener
more
sustainable
solution
chemistry.
Frontiers in Microbiology,
Journal Year:
2025,
Volume and Issue:
15
Published: Jan. 15, 2025
Soil
salinization,
extreme
climate
conditions,
and
phytopathogens
are
abiotic
biotic
stressors
that
remarkably
reduce
agricultural
productivity.
Recently,
nanomaterials
have
gained
attention
as
effective
agents
for
applications
to
mitigate
such
stresses.
This
review
aims
critically
appraise
the
available
literature
on
interactions
involving
nanomaterials,
plants,
microorganisms.
explores
role
of
in
enhancing
plant
growth
mitigating
These
materials
can
be
synthesized
by
microbes,
algae,
they
applied
fertilizers
stress
amelioration
agents.
Nanomaterials
facilitate
nutrient
uptake,
improve
water
retention,
enhance
efficiency
active
ingredient
delivery.
strengthen
antioxidant
systems,
regulate
photosynthesis,
stabilize
hormonal
pathways.
Concurrently,
their
antimicrobial
protective
properties
provide
resilience
against
stressors,
including
pathogens
pests,
promoting
immune
responses
optimizing
microbial-plant
symbiosis.
The
synergistic
with
beneficial
microorganisms
optimize
under
conditions.
also
serve
carriers
nutrients,
regulators,
pesticides,
thus
acting
like
"smart
fertilizers.
While
nanotechnology
offers
great
promise,
addressing
potential
environmental
ecotoxicological
risks
associated
use
is
necessary.
outlines
pathways
leveraging
achieve
resilient,
sustainable,
climate-smart
systems
integrating
molecular
insights
practical
applications.
Bioanalysis,
Journal Year:
2025,
Volume and Issue:
unknown, P. 1 - 20
Published: March 24, 2025
Bioanalytical
laboratories
face
significant
challenges
in
sample
preparation
due
to
the
complexity
of
biological
matrices
and
low
concentrations
target
analytes.
This
review
focuses
on
advances
green
(GSP)
techniques
tailored
meet
these
while
promoting
sustainability.
Innovations
sorbents,
including
metal-organic
frameworks
(MOFs),
magnetic
nanoparticles
(MNPs),
sol-gel-based
materials,
molecularly
imprinted
polymers
(MIPs),
carbon-based
natural
sorbents
like
cellulose
kapok
fiber,
have
enhanced
extraction
efficiency
selectivity.
Green
solvents
such
as
deep
eutectic
(DES),
ionic
liquids
(ILs),
supramolecular
(SUPRAs),
switchable
hydrophilicity
(SHSs)
further
reduce
environmental
impact
by
minimizing
toxic
solvent
use.
highlights
their
use
drug
analysis,
emphasizing
roles
enhancing
efficiency,
selectivity,
Recent
applications
demonstrate
integration
into
bioanalytical
workflows,
significantly
improving
analytical
performance
adhering
Analytical
Chemistry
(GAC)
principles.
It
is
anticipated
that
this
comprehensive
will
aid
scholars
formulation
selective,
rapid,
environmentally
friendly,
straightforward,
sensitive,
precise
methodologies
for
bioanalysis,
thereby
innovation
sustainability
within
analysis
protocols.
