Preparation of ionic porous polymers for extraction of four phenolic endocrine disrupting chemicals from fish and water samples

Food Chemistry, Journal Year: 2024, Volume and Issue: 449, P. 139270 - 139270

Published: April 10, 2024

Language: Английский

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Recoverable and recyclable porous polymer for extraction of trace endocrine disrupting compounds from seafood products prior to LC /MS analysis

Food Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 143129 - 143129

Published: Jan. 1, 2025

Language: Английский

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Cyano-functionalized porous hyper-crosslinked cationic polymers for efficient preconcentration and detection of phenolic endocrine disruptors in fresh water and fish

Talanta, Journal Year: 2024, Volume and Issue: 281, P. 126822 - 126822

Published: Sept. 10, 2024

Language: Английский

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Recent advances and applications of ionic covalent organic frameworks in food analysis

Journal of Chromatography A, Journal Year: 2024, Volume and Issue: 1730, P. 465113 - 465113

Published: June 24, 2024

Language: Английский

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Covalent organic Frameworks: Multifunctional material in analytical chemistry

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 497, P. 154915 - 154915

Published: Aug. 17, 2024

Language: Английский

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Electrochemical Synthesis of Polyaniline@Nano Zinc Oxide/Modified Multiwalled Carbon Nanotubes Nanocomposite Coating for Solid Phase Microextraction of Some Polycyclic Aromatic Hydrocarbons in Coffee and Grilled Meat

Journal of Separation Science, Journal Year: 2025, Volume and Issue: 48(1)

Published: Jan. 1, 2025

ABSTRACT Polycyclic aromatic hydrocarbons (PAHs) are carcinogenic compounds resulting from incomplete burning of organic materials. This work describes the successful layer‐by‐layer fabrication a novel zinc oxide nanocomposite made nanoparticles, aniline, sodium dodecyl sulfate, and modified multi‐walled carbon nanotubes on stainless steel wire by electrodeposition. The coating extraction conditions were screened, optimized, validated using factorial design central composite design, respectively. prepared nanocomposites characterized Fourier‐transform infrared spectroscopy, field‐emission scanning electron microscopy, X‐ray diffraction analysis, Brunauer‐Emmett‐Teller techniques. It featured porous structure, excellent heat stability, high capacity. also adhered well to surface. Extracting PAHs was optimized through experimental design. optimal obtained for 60 min, 30%, 30°C time, amount salt, temperature, method generally showed linear range between 0.01 1.50 µg/mL with linearity (R 2 ) 0.9902–0.9992, limits detection less than 0.003 µg/mL, limit quantification lower 0.010 relative standard deviation percent 45. Recovery values analytes in food samples varied 53.4% 110.1%. proposed employed determination some while naphthalene, anthracene, phenanthrene, benzo[a]pyrene, benz[a]anthracene detected certain samples. Overall, our research suggests as potential fiber that enables high‐capacity PAH extraction.

Language: Английский

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Quercetin‐Based Magnetic Porous Organic Polymers for Efficient Adsorption of Phenolic Pollutants

Macromolecular Chemistry and Physics, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 17, 2025

Abstract Phenolic wastewater poses a significant threat to public health, highlighting the urgent need for development of effective and efficient treatment methods. Porous organic polymers, renowned their high structural stability, large surface area, diverse physicochemical properties, have gained widespread application in adsorption‐based technologies. Therefore, novel adsorbent materials remains crucial area scientific research. In this study, porous polymer is synthesized using quercetin, derived from biomass, as key precursor. To facilitate separation reusability, magnetic Fe 3 O 4 @SiO₂ nano‐particle nanoparticles (MNPs) are integrated into matrix. The resulting adsorbents exhibited outstanding adsorption capacity phenolic contaminants, along with excellent recoverability reusability. Additionally, mechanism systematically investigated verified through series characterization techniques.

Language: Английский

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Preparation of covalent organic framework coated on copper foam as sorbent for thin film microextraction phthalate esters besides their quantification via gas chromatography

Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113575 - 113575

Published: April 1, 2025

Language: Английский

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Recent advancements in synthesis and applications of covalent organic frameworks

Applied Materials Today, Journal Year: 2025, Volume and Issue: 44, P. 102694 - 102694

Published: April 12, 2025

Language: Английский

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Novel Room‐Temperature‐Prepared Covalent Organic Framework as Adsorbent for Rapid Extraction of Aromatic Esters in Baijiu

Journal of Food Science, Journal Year: 2025, Volume and Issue: 90(4)

Published: April 1, 2025

ABSTRACT Developing a rapid, efficient, and environmentally friendly analytical methodology for the determination of aromatic esters (AREs) in Baijiu presents significant challenge. In this study, we developed room‐temperature method to synthesize core‐shell Fe 3 O 4 @TPB‐Dha 1 h using pre‐prepared nanoparticles, enabling rapid sensitive detection AREs. The demonstrated exceptional adsorption capabilities (52.63–58.82 mg/g) with brief duration (4 min) four AREs as magnetic solid phase extraction (MSPE) adsorbent. Moreover, density functional theory (DFT) calculations revealed key mechanisms be hydrogen bonds, van der Waals forces, π–π interactions. Ultimately, enabled accurate quantification real samples, concentrations spanning from 0.17 ± 6 × 10 −4 2.40 0.03 mg/L, exhibited relative standard deviations below 6.57% ( n = 3). These findings suggest that holds promise an effective adsorbent efficient precise Baijiu.

Language: Английский

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