Coordination-driven innovations in low-energy catalytic processes: Advancing sustainability in chemical production

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 514, P. 215900 - 215900

Published: May 8, 2024

Catalysis stands as a cornerstone in chemical synthesis, pivotal advancing sustainable manufacturing pathways. The evolution from energy-intensive to catalytic processes has marked transformative shift, notably exemplified by low-energy methods. These processes, operating under milder conditions and emphasizing selectivity recyclability, represent the forefront of chemistry. This review navigates through an array reactions, highlighting their diverse applications culminating exploration recent strides within processes. For example, explores uses such enzyme mimicking, biodiesel production, carbon dioxide capture, organic synthesis. Additionally, it covers enzymatic catalysis photocatalysis for transformations, energy applications, water treatment. Notably, emphasizes capabilities single-atom (SAC) diatomic catalysts (DACs), recognizing exceptional performance catalyzing reactions at minimal activation energies while maintaining high efficiency mild conditions. By elucidating modulation electronic structure offering microelectronic perspective, aims elucidate mechanisms underlying activity SAC DACs. Emphasizing interplay between coordination chemistry principles efficacy, elucidates indispensable role complexes fortifying sustainability these spotlighting fusion with catalysis, this underscore collective influence shaping landscape production.

Language: Английский

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Sustainable Aerobic Allylic C–H Bond Oxidation with Heterogeneous Iron Catalyst

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(4), P. 2769 - 2778

Published: Jan. 19, 2024

Emerging techniques are revolutionizing the realm of chemical synthesis by introducing new avenues for C–H bond functionalization, which have been exploited pharmaceuticals, natural compounds, and functional materials. Allylic oxidation alkenes serves as possibly most employed functionalization reaction. However, sustainable selective approaches remain scarce, majority existing conditions still hinge on hazardous oxidants or costly metal catalysts. In this context, we introduce a heterogeneous iron catalyst that addresses above-mentioned concerns showcasing aerobic steroids, terpenes, simple olefins to corresponding enone products. This novel method provides powerful tool arsenal allylic while minimizing environmental concerns.

Language: Английский

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Efficient synthesis and molecular docking analysis of quinazoline and azole hybrid derivatives as promising agents for anti-cancer and anti-tuberculosis activities

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1310, P. 138289 - 138289

Published: April 9, 2024

Language: Английский

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Application of Functionalized Zn-Based Metal–Organic Frameworks (Zn-MOFs) with CuO in Heterocycle Synthesis via Azide–Alkyne Cycloaddition

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(11), P. 4898 - 4914

Published: Jan. 31, 2024

The main goal of this article is to discuss the expansion click chemistry. A new catalyst composed CuO nanoparticles embedded in Zn-MOF with ligand 2,4,6-tris(4-carboxyphenoxy)-1,3,5-triazine (H3L) presented. incorporation into structure led desirable morphology and catalytic properties. designed was evaluated for its role multicomponent reaction copper-catalyzed azide–alkyne cycloaddition (CuAAC) preparation triazole rings 80–91% yield. demonstrated an appealing architecture exhibited robustness, high efficiency, environmental friendliness. Characterization performed using various techniques, including Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission microscopes (TEM), high-resolution (HRTEM), X-ray photoelectron (XPS), energy-dispersive (EDX), elemental mapping, diffraction (XRD). results suggest that novel has potential be a valuable tool development synthetic approaches wide range applications.

Language: Английский

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Advanced Functionalized Nanoclusters (Cu, Ag, and Au) as Effective Catalyst for Organic Transformation Reactions

Chemistry - An Asian Journal, Journal Year: 2024, Volume and Issue: 19(9)

Published: Feb. 22, 2024

A considerable amount of research has been carried out in recent years on synthesizing metal nanoclusters (NCs), which have wide applications the field optical materials with non-linear properties, bio-sensing, and catalysis. Aside from being structurally accurate, atomically precise NCs possess well-defined compositions due to significant tailoring, both at surface core, for certain functionalities. To illustrate importance catalytic processes, this review emphasizes 1) work Cu, Ag, Au their synthesis, 2) parameters affecting activity selectivity catalysis, 3) discussion potential these NCs. Additionally, will facilitate design extremely active selective catalysts reactions by elucidating mechanisms atomic molecular levels. Future advancements science catalysis are expected come level.

Language: Английский

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Zinc Oxide Nanoparticles as Efficient Heterogeneous Catalyst for Synthesis of Bio‐active Heterocyclic Compounds

ChemistrySelect, Journal Year: 2023, Volume and Issue: 8(41)

Published: Nov. 2, 2023

Abstract Among the most effective recoverable catalytic systems, metal‐oxide nanoparticles (NPs) are well known for their extensive uses in a broad range of industries, pharmaceuticals, and nano‐biotechnology. In addition, heterogeneous catalysis clearly defined materials which present an new possibilities research production innovative catalysts that help to solve world's energy environmental problems. ZnO‐NPs have been used as nanocatalysts according literature various kinds organic reactions. The advantages over bulk suggest this is promising field further research. This review article provides in‐depth overview several reported catalyse transformations including bio‐active compounds like benzofuran, coumarin, imidazole, indole, pyrazole, pyridine pyrimidine, thiazole, diazepine, azoles derivatives. Recent synthetic routes modifying functionalizing increase efficacy were also addressed, illustrated with schematics. development novel, highly effective, reusable modified catalysts, would clear way establishment greener sustainable technologies, key future catalysis. Researchers attempting synthesise functionalized will find informative.

Language: Английский

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Anticancer potential of ferrocene-containing derivatives: Current and future prospective

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1319, P. 139589 - 139589

Published: Aug. 9, 2024

Language: Английский

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Review on the recent advances in catalytic conversion of carbon dioxide for synthesis of cyclic propylene carbonate

Molecular Catalysis, Journal Year: 2023, Volume and Issue: 553, P. 113720 - 113720

Published: Dec. 8, 2023

Language: Английский

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Emerging strategies for synthesis of heterocyclic compounds enabled by titanium oxide nanoparticles as heterogeneous catalyst

Tetrahedron, Journal Year: 2024, Volume and Issue: 160, P. 134039 - 134039

Published: May 16, 2024

Language: Английский

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Experimental and theoretical investigations of CO2 sorption by microporous Ca–MOF with an open Ca2+ site

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162531 - 162531

Published: Jan. 1, 2025

Language: Английский

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