Bis(phenylsulfonyl)sulfide as a Bifunctional Single‐Sulfur Source for the Rapid Assembly of Unsymmetric Diaryl Sulfides Enabled by Copper Catalyst

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(44)

Published: Nov. 1, 2024

Abstract Rapid access to unsymmetrical diaryl sulfides through a bifunctional single‐sulfur source is very attractive strategy. Here we report the utilization of bis(phenylsulfonyl)sulfide as bielectrophilic sulfide platform molecule for chemoselective and sequential installation two different aryl nucleophiles by twice copper‐catalyzed Chan–Lam‐type cross couplings diverse sulfides. This strategy demonstrates good tolerance wide range boronic acids under metal catalysts, functional group compatibility, well extension modification complex bioactive molecules.

Language: Английский

Advancements in Chan-Lam cross-coupling reactions utilizing copper and nickel salts, Cu/Ni-incorporated polymers, and nanocomposites

Inorganic Chemistry Communications, Journal Year: 2024, Volume and Issue: unknown, P. 113799 - 113799

Published: Dec. 1, 2024

Language: Английский