Chemical Papers, Journal Year: 2024, Volume and Issue: 78(12), P. 6821 - 6841
Published: July 7, 2024
Language: Английский
Chemical Papers, Journal Year: 2024, Volume and Issue: 78(12), P. 6821 - 6841
Published: July 7, 2024
Language: Английский
Progress in heterocyclic chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 211 - 257
Published: Jan. 1, 2024
Language: Английский
Citations
0Asian Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 13(4)
Published: Feb. 24, 2024
Abstract Mono ‐ and bis ‐pyridinium, phosphonium sulfonium allylic salts, containing adamantane fragment, have been obtained from the substitution reaction in 1,4‐dibromo‐2‐butene. It was found, that attack of triethylamine undergoes sterically less hindered side, leading to deprotonation subsequent elimination molecular fragment with formation a new salt diene structure. Quantum chemical calculations were used confirm structure one products by correlation analysis experimental calculated NMR data confirmed s‐cisoid conformation diene. dienes may be as substrates Diels‐Alder despite their high sterical hinderance.
Language: Английский
Citations
0Chemical Papers, Journal Year: 2024, Volume and Issue: 78(12), P. 6821 - 6841
Published: July 7, 2024
Language: Английский
Citations
0