Synthesis of 1,4-benzodioxepinones via electrochemical oxyselenenylation of 2-O-tethered alkenyl benzoic acid and diselenides
Junsheng Hou,
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Bingxin You,
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Ruitao Lv
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et al.
Tetrahedron Letters,
Journal Year:
2024,
Volume and Issue:
unknown, P. 155389 - 155389
Published: Nov. 1, 2024
Language: Английский
Amine-Promoted Three-Component Radical Selenofunctionalization for the Construction of β-Hydroxy Selenide Derivatives
Jiantao Zhang,
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Renhua Su,
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Peng Zhou
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et al.
The Journal of Organic Chemistry,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 28, 2024
An
amine-promoted
three-component
radical
selenofunctionalization
reaction
of
alkenes
with
TBHP
and
diselenide
is
disclosed.
The
conditions
are
mild
suitable
for
a
wide
range
substrates
(29
examples),
all
give
the
corresponding
hydroxyselenenylation
products
in
moderate
to
excellent
yields.
In
addition,
preliminary
studies
on
mechanism
reveal
that
current
method
might
proceed
via
pathway.
serves
as
both
initiator
source
hydroxyl
group.
Language: Английский