Journal of Analytical Chemistry, Journal Year: 2020, Volume and Issue: 75(10), P. 1237 - 1251
Published: Oct. 1, 2020
Language: Английский
Microchemical Journal, Journal Year: 2019, Volume and Issue: 152, P. 104384 - 104384
Published: Nov. 1, 2019
Over the past decade, deep eutectic solvents (DES) have been widely studied and applied in sample preparation techniques. Until recently, most of synthesized DES were hydrophilic, which prevented their use extraction aqueous samples. However, after 2015 studies on synthesis application hydrophobic (HDES) has rapidly expanded. Due to unique properties HDES i.e. density, viscosity, acidity or basicity, polarity volatility, good extractabilities for various target analytes, could be altered by careful selection hydrogen bond donor (HBD) acceptor (HBA) components, are promising alternatives traditional organic employed preparation. Moreover, possibility non-toxic ingredients, makes meet all standards green analytical chemistry. Practical applications include conventional liquid-liquid extraction, several types liquid-phase microextraction, as well solid phase extraction. The present review covers a comprehensive summarizing available literature data important physicochemical playing key role methods, limitations challenges this area, perspective future described.
Language: Английский
Citations
354
Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2019, Volume and Issue: 586, P. 124195 - 124195
Published: Nov. 4, 2019
Language: Английский
Citations
179
TrAC Trends in Analytical Chemistry, Journal Year: 2019, Volume and Issue: 120, P. 115651 - 115651
Published: Sept. 7, 2019
Language: Английский
Citations
165
TrAC Trends in Analytical Chemistry, Journal Year: 2019, Volume and Issue: 119, P. 115633 - 115633
Published: Aug. 21, 2019
Language: Английский
Citations
154
Environmental Science & Technology, Journal Year: 2021, Volume and Issue: 55(3), P. 1419 - 1435
Published: Jan. 12, 2021
Ionic liquids (ILs) as novel functional desulfurization materials have attracted increasing attentions. Metal-based ionic (MILs) are classified into three types of metal chloride ILs, oxide and complex ILs based on the definition basic structure MILs in this critical review. On basis properties such designability, super dissolution performance, good thermal chemical stability, nonflammability, wide electrochemical window, exhibit unique advantages hydrophobicity, oxidation Brönsted-Lewis acidity. Therefore, possess both absorption centers for intramolecular adsorption to improve oxidative (ODS) process. During nonaqueous wet process (Nasil), H2S can be oxidized elemental sulfur with hydrophobic MILs, which regenerated by oxygen recycle, solve problems low capacity, quality, severe secondary pollution aqueous Lo-Cat Another outstanding feature ODS is biomimetic catalysis, has function activating molecular improving performance. Metal used combination hydrogen peroxide or existing water generate a Fenton-like reaction convert organic SO2 hydrophilic sulfoxide/sulfone acid, respectively. However, corrosion Cl- equipment emulsification phenomenon extraction separation still need further study. Furthermore, promising strategies construct highly efficient green processes large-scale applications provided.
Language: Английский
Citations
140
Fuel, Journal Year: 2023, Volume and Issue: 344, P. 128102 - 128102
Published: March 15, 2023
Global warming triggered by greenhouse gas (GHG) emissions, particularly carbon dioxide (CO2), significantly influences climate change and has become a common environmental issue recently. The current amine-based technologies (ABTs) for CO2 capture (CAPCO2) have high energy demand, low absorption, desorption rates, are less environmentally sustainable due to emissions of volatile solvents. Therefore, the development friendly CAPCO2 materials and/or processes is growing area research. utilization ionic liquids (ILs) recently attracted attention. unique characteristics ILs, such as their vapor pressure affinity well volatility make them viable substitute existing processes. This work provides comprehensive overview accomplishments challenges during use ILs CAPCO2. Review also outlines mechanisms with at molecular level, properties characterization CO2/IL systems, effect operating conditions on uptake (UPCO2) capacity ILs. It emphasizes impact cations, anions, functional groups solubility ((SCO2)) in biodegradability toxicity Additionally, recent advances IL membrane technology considered. Lastly, contribution simulations create assess was reviewed. Protic aprotic shown outstanding efficiency UPCO2. interactions between anionic part enhance UPCO2 outperform traditional organic Functionalized (FUNILs) tuned groups, supported membranes (SILMs) reversible (RILs) improved promising capturing process from industrial streams even under partial pressure. relative importance chemical breakdown constituents (cation–anion interfacial structuring) different temperatures unclear, more research this required better inform design new review proper/systematic guideline help manufacturers engineers high-capacity appropriate
Language: Английский
Citations
108
TrAC Trends in Analytical Chemistry, Journal Year: 2022, Volume and Issue: 152, P. 116636 - 116636
Published: April 12, 2022
Language: Английский
Citations
83
Separation and Purification Technology, Journal Year: 2022, Volume and Issue: 305, P. 122453 - 122453
Published: Oct. 26, 2022
Language: Английский
Citations
72
Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 341, P. 126979 - 126979
Published: March 3, 2024
Language: Английский
Citations
27
Green Chemistry, Journal Year: 2024, Volume and Issue: 26(5), P. 2421 - 2453
Published: Jan. 1, 2024
Metal salt-based deep eutectic solvents (MSDESs) have recently developed a torrent of leading-edge applications in endless areas chemistry.
Language: Английский
Citations
21