In-tip-fabric phase sorptive extraction (In-tip-FPSE): A proof of concept study for on-site and in-laboratory sample preparation of antidepressants and benzodiazepines DOI
Rajeev Jain, B.D. Jain, Abhishek Ghosh

et al.

Microchemical Journal, Journal Year: 2024, Volume and Issue: 203, P. 110851 - 110851

Published: June 1, 2024

Language: Английский

A total scoring system and software for complex modified GAPI (ComplexMoGAPI) application in the assessment of method greenness DOI Creative Commons
Fotouh R. Mansour, Khalid M. Omer, Justyna Płotka‐Wasylka

et al.

Green Analytical Chemistry, Journal Year: 2024, Volume and Issue: 10, P. 100126 - 100126

Published: June 27, 2024

Evaluating analytical methods with innovative metrics is essential to ensure the effectiveness of procedures. Various approaches have been proposed assess performance an method and its environmental consequences, as sustainable environment green chemistry ideology are high importance nowadays. Considering greenness evaluation developed procedures, Green Analytical Procedure Index (GAPI), one these metrics, utilizes five distinct colored pentagons evaluate footprint process at different stages. An additional tool named Complementary (ComplexGAPI) was introduced expand on GAPI by adding fields pertaining processes performed prior procedure itself. Nevertheless, existing ComplexGAPI lacks a comprehensive scoring system for individual methods, which would allow even easier comparison procedures using this tool. In response queries from users, study introduces refined ComplexMoGAPI, merging visual appeal precise total scores. The accompanying software streamlines application, facilitating quicker simpler evaluations. This available open source bit.ly/ComplexMoGAPI. We believe that, following success, ComplexMoGAPI will also gain attention eventually trust acceptance chemical community.

Language: Английский

Citations

72
Modified GAPI (MoGAPI) Tool and Software for the Assessment of Method Greenness: Case Studies and Applications DOI Creative Commons
Fotouh R. Mansour, Justyna Płotka‐Wasylka, Marcello Locatelli

et al.

Analytica—A Journal of Analytical Chemistry and Chemical Analysis, Journal Year: 2024, Volume and Issue: 5(3), P. 451 - 457

Published: Sept. 6, 2024

Abstract: The green analytical procedure index (GAPI) has been widely used to assess the greenness of different steps in methodology. In GAPI index, stages chemical analysis process are depicted using five pentagrams divided subsections, labeled green, yellow, or red according degree greenness. This tool provides a quick overview environmental impact and safety procedure. However, there is no total score that can be calculated from metric enable comparison between methods. this work, modified (MoGAPI) software have developed applied address limitations current metric. presented offers more precise assessment greenness, while simplifies expedites its application. It also combines advantages Eco-Scale with merits was successfully calculate few case studies applications show applicability for MoGAPI freely available (open source) at bit.ly/MoGAPI facilitate application method comparison. represent significant advancement assessment, providing researchers robust user-friendly means evaluate compare

Language: Английский

Citations

69
Green analytical chemistry metrics for evaluating the greenness of analytical procedures DOI Creative Commons

Lei Yin,

Luyao Yu,

Yingxia Guo

et al.

Journal of Pharmaceutical Analysis, Journal Year: 2024, Volume and Issue: 14(11), P. 101013 - 101013

Published: May 25, 2024

Green analytical chemistry (GAC) focuses on mitigating the adverse effects of activities human safety, health, and environment. In addition to 12 principles GAC, proper GAC tools should be developed employed assess greenness different assays. The 15 widely used metrics, i.e., national environmental methods index (NEMI), advanced NEMI, assessment green profile (AGP), chloroform-oriented toxicity estimation scale (ChlorTox Scale), Analytical Eco-Scale, Certificate Modified method score (AMGS), procedure (GAPI), ComplexGAPI, red-green-blue (RGB) additive color model, RGB algorithm, calculator (AGREE), AGREE preparation (AGREEprep), HEXAGON, blue applicability grade (BAGI), are selected as typical tools. This article comprehensively presents elucidates principles, characteristics, merits, demerits review is helpful for researchers use current metrics sustainability

Language: Английский

Citations

39
Greenness, blueness and whiteness evaluated-chemometric approach enhanced by Latin hypercube technique for the analysis of lidocaine, diclofenac and carcinogenic impurity 2,6-dimethylaniline DOI
Michael K. Halim,

Osama M. Badran,

Ahmed Emad F. Abbas

et al.

Sustainable Chemistry and Pharmacy, Journal Year: 2024, Volume and Issue: 38, P. 101463 - 101463

Published: Feb. 2, 2024

Language: Английский

Citations

21
Ultrasensitive spectrofluorimetric approach for quantitation of the novel antiparkinsonian drug safinamide in different matrices at nanogram levels: Assessment of greenness and whiteness profiles DOI
Galal Magdy, Aya Saad Radwan, Heba Elmansi

et al.

Sustainable Chemistry and Pharmacy, Journal Year: 2024, Volume and Issue: 38, P. 101448 - 101448

Published: Jan. 19, 2024

Language: Английский

Citations

20
Four chemometric models enhanced by Latin hypercube sampling design for quantification of anti-COVID drugs: sustainability profiling through multiple greenness, carbon footprint, blueness, and whiteness metrics DOI Creative Commons

Noha S. Katamesh,

Ahmed Emad F. Abbas, Shimaa A. Mahmoud

et al.

BMC Chemistry, Journal Year: 2024, Volume and Issue: 18(1)

Published: March 18, 2024

Abstract Montelukast sodium (MLK) and Levocetirizine dihydrochloride (LCZ) are widely prescribed medications with promising therapeutic potential against COVID-19. However, existing analytical methods for their quantification unsustainable, relying on toxic solvents expensive instrumentation. Herein, we pioneer a green, cost-effective chemometrics approach MLK LCZ analysis using UV spectroscopy intelligent multivariate calibration. Following multilevel multifactor experimental design, spectral data was acquired 25 synthetic mixtures modeled via classical least squares (CLS), principal component regression (PCR), partial (PLS), genetic algorithm-PLS (GA-PLS) techniques. Latin hypercube sampling (LHS) strategically constructed an optimal validation set of 13 unbiased predictive performance assessment. optimization the models regarding latent variables (LVs) wavelength region, optimum root mean square error cross-validation (RMSECV) attained at 2 LVs 210–400 nm range (191 points). The GA-PLS model demonstrated superb accuracy, recovery percentages (R%) from 98 to 102% both analytes, calibration (RMSEC) prediction (RMSEP) (0.0943, 0.1872) (0.1926, 0.1779) LCZ, respectively, as well bias-corrected (BCMSEP) -0.0029 0.0176, relative (RRMSEP) reaching 0.7516 0.6585, limits detection (LOD) 0.0813 0.2273 respectively. Practical pharmaceutical sample successfully confirmed standard additions. We further conducted pioneering multidimensional sustainability evaluations state-of-the-art greenness, blueness, whiteness tools. method favorable environmental metrics across all assessment obtained Green National Environmental Method Index (NEMI), Complementary Analytical Procedure (ComplexGAPI) quadrants affirmed green principles. Additionally, had high Greenness Metric (AGREE) score (0.90) low carbon footprint (0.021), indicating friendliness. also applied blueness assessments Blue Applicability Grade (BAGI) Red–Green–Blue 12 (RGB 12) algorithms. BAGI (90) RGB (90.8) scores method's strong applicability, cost-effectiveness, sustainability. This work puts forward optimal, economically viable chemistry paradigm quality control aligned sustainable development goals.

Language: Английский

Citations

20
Fabrication of robust and efficient boronic acid-functionalized porphyrin-based metal–organic framework for selective adsorption of adenosine DOI
Juan Zhang, Ting Zou,

Furong Tang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160919 - 160919

Published: Feb. 1, 2025

Language: Английский

Citations

2
Evolution of Green Sample Preparation: Fostering a Sustainable Tomorrow in Analytical Sciences DOI
Héctor Martínez-Pérez-Cejuela, Emanuela Gionfriddo

Analytical Chemistry, Journal Year: 2024, Volume and Issue: 96(20), P. 7840 - 7863

Published: April 30, 2024

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTEvolution of Green Sample Preparation: Fostering a Sustainable Tomorrow in Analytical SciencesH. Martínez-Pérez-CejuelaH. Martínez-Pérez-CejuelaDepartment Chemistry, University at Buffalo, The State New York, York 14260-3000, United StatesMore by H. Martínez-Pérez-CejuelaView Biographyhttps://orcid.org/0000-0002-6456-0846 and E. Gionfriddo*E. GionfriddoDepartment States*[email protected]More GionfriddoView Biographyhttps://orcid.org/0000-0002-1836-1950Cite this: Anal. Chem. 2024, 96, 20, 7840–7863Publication Date (Web):April 30, 2024Publication History Received11 March 2024Accepted22 April 2024Revised20 2024Published online30 inissue 21 May 2024https://pubs.acs.org/doi/10.1021/acs.analchem.4c01328https://doi.org/10.1021/acs.analchem.4c01328review-articleACS PublicationsCopyright © 2024 American Chemical SocietyRequest reuse permissionsArticle Views560Altmetric-Citations-LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum full text article downloads since November 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated to reflect usage leading up last few days.Citations number other articles citing this article, calculated Crossref daily. Find more information about citation counts.The Altmetric Attention Score is quantitative measure attention that research has received online. Clicking on donut icon will load page altmetric.com with additional details score social media presence for given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Extraction,Sample preparation,Solvents,Sorbents,Wastes Get e-Alerts

Language: Английский

Citations

14
Green sorbents in sample preparation techniques – naturally occurring materials and biowastes DOI
Justyna Werner, Robert Frankowski, Tomasz Grześkowiak

et al.

TrAC Trends in Analytical Chemistry, Journal Year: 2024, Volume and Issue: 176, P. 117772 - 117772

Published: May 19, 2024

Language: Английский

Citations

14
Pressurized liquid extraction of organic contaminants in environmental and food samples DOI Creative Commons
Yolanda Jiménez Soriano, V. Andreu, Yolanda Picó

et al.

TrAC Trends in Analytical Chemistry, Journal Year: 2024, Volume and Issue: 173, P. 117624 - 117624

Published: Feb. 28, 2024

Pressurized liquid extraction (PLE) is an automated technique for extracting compounds, including organic contaminants that are strongly bind to the matrix. It provides advantages such as reduced time, decreased solvent and energy consumption, simultaneous multiple extractions, concurrent clean-up capability. This review presents updated overview of most relevant analytical methods applications, focusing on PLE in environmental food matrices. encompasses developments proposed since 2019, building upon previous revision published year. We also address recent advancements emerging technological trends, development selective (SPLE), introduction sequential sample processing systems relevant. In general, demonstrates substantial potential a viable option analysis complex matrices, making it promising greener choice applications.

Language: Английский

Citations

13