Electrochemical Sensing of Metribuzin Utilizing the Synergistic Effects of Cationic and Anionic Bio-Polymers with Hetero-Doped Carbon DOI Open Access
Thirukumaran Periyasamy, Shakila Parveen Asrafali, Seong‐Cheol Kim

et al.

Polymers, Journal Year: 2024, Volume and Issue: 17(1), P. 39 - 39

Published: Dec. 27, 2024

The development of innovative, cost effective, and biocompatible sensor materials for rapid efficient practical applications is a key area focus in electroanalytical chemistry. In this research, we report on novel sensor, made using unique polybenzoxazine-based carbon combined with amino cellulose hyaluronic acid to produce bio-polymer complex (PBC-ACH) (polybenzoxazine-based acid). This material fabricated the first time enable electroreduction herbicide, metribuzin (MTZ). PBC-ACH presents multiple advantages, including ease fabrication, excellent biocompatibility, low-cost production, making it suitable various applications. optimized experimental conditions, was by modifying glassy electrode (GCE) complex, resulting creation GCE/PBC-ACH electrode. modified demonstrated ability detect MTZ at nanomolar levels, an LoD 13.04 nM, showcasing high sensitivity 1.40 µA µM−1 cm−2. Moreover, exhibited remarkable selectivity, stability, reproducibility terms its electrochemical performance, which are essential features reliable sensing potential mechanism behind detection investigated thoroughly, providing insights into behavior. Additionally, tests real samples validated sensor’s practicality efficiency detecting specific analytes. These findings emphasize as highly effective promising environmental monitoring other fields requiring precise analyte detection.

Language: Английский

Biochar/layered double hydroxides composites as catalysts for treatment of organic wastewater by advanced oxidation processes: A review DOI Creative Commons
Gonggang Liu, Xiuxiu Zhang, Hong‐Wen Liu

et al.

Environmental Research, Journal Year: 2023, Volume and Issue: 234, P. 116534 - 116534

Published: July 1, 2023

Language: Английский

Citations

82

Sonocatalytic degradation of tetracycline hydrochloride with CoFe2O4/g-C3N4 composite DOI Creative Commons
Jingjing Zhang, Yue Zhao, Kai Zhang

et al.

Ultrasonics Sonochemistry, Journal Year: 2023, Volume and Issue: 94, P. 106325 - 106325

Published: Feb. 11, 2023

In this work, different mass percent ratios of CoFe2O4 coupled g-C3N4 (w%-CoFe2O4/g-C3N4, CFO/CN) nanocomposites were integrated through a hydrothermal process for the sonocatalytic eradication tetracycline hydrochloride (TCH) from aqueous media. The prepared sonocatalysts subjected to various techniques investigate their morphology, crystallinity, ultrasound wave capturing activity and charge conductivity. From investigated composite materials, it has been registered that best degradation efficiency 26.71 % in 10 min was delivered when amount 25% nanocomposite. higher than bare g-C3N4. This enriched credited accelerated transfer separation e--h+ pair S-scheme heterojunctional interface. trapping experiments confirmed all three species i.e. •OH, h+ •O2- involved antibiotics. A strong interaction shown up between FTIR study support as photoluminescence photocurrent analysis samples. work will provide an easy approach fabricating highly efficient low-cost magnetic hazardous materials present our environment.

Language: Английский

Citations

69

Synthesis of carbon microsphere-supported nano-zero-valent iron sulfide for enhanced removal of Cr(VI) and p-nitrophenol complex contamination in peroxymonosulfate system DOI

Yin Wang,

Huanhuan Li,

Wannan Xia

et al.

Journal of Molecular Liquids, Journal Year: 2023, Volume and Issue: 390, P. 123089 - 123089

Published: Sept. 22, 2023

Language: Английский

Citations

52

Application of Photocatalysis and Sonocatalysis for Treatment of Organic Dye Wastewater and the Synergistic Effect of Ultrasound and Light DOI Creative Commons
Guowei Wang, Hefa Cheng

Molecules, Journal Year: 2023, Volume and Issue: 28(9), P. 3706 - 3706

Published: April 25, 2023

Organic dyes play vital roles in the textile industry, while discharge of organic dye wastewater production and utilization has caused significant damage to aquatic ecosystem. This review aims summarize mechanisms photocatalysis, sonocatalysis, sonophotocatalysis treatment recent advances catalyst development, with a focus on synergistic effect ultrasound light catalytic degradation dyes. The performance TiO2-based catalysts for photocatalytic, sonocatalytic, sonophotocatalytic systems is compared. With light, generally performs much better than sonocatalysis or photocatalysis alone pollutant degradation, yet it higher energy requirement. Future research directions are proposed expand fundamental knowledge process enhance its practical application degrading wastewater.

Language: Английский

Citations

47

All-solid-state Z-scheme ZnFe–LDH/rGO/g-C3N5 heterojunction for enhanced sonophotocatalytic degradation of ciprofloxacin: Performance and mechanistic insights DOI

Yeonji Yea,

S.SD. Elanchezhiyan,

R. Saravanakumar

et al.

Environmental Research, Journal Year: 2024, Volume and Issue: 247, P. 118209 - 118209

Published: Jan. 21, 2024

Language: Английский

Citations

18

Enhanced activation of persulfate by magnetic NiFe2O4@CuO coupled with ultrasonic for degradation of oxytetracycline: Activation mechanism and degradation pathway DOI
Hai‐Feng Ji, Yufeng Xu, Hongfei Shi

et al.

Applied Surface Science, Journal Year: 2024, Volume and Issue: 652, P. 159373 - 159373

Published: Jan. 21, 2024

Language: Английский

Citations

17

Preparation of Ag3PO4/CoWO4 S-scheme heterojunction and study on sonocatalytic degradation of tetracycline DOI Creative Commons
Liang Xu,

Ni-Ping Liu,

Hui-Li An

et al.

Ultrasonics Sonochemistry, Journal Year: 2022, Volume and Issue: 89, P. 106147 - 106147

Published: Sept. 1, 2022

In this study, 0.6Ag3PO4/CoWO4 composites were synthesized by hydrothermal method. The prepared materials systematically characterized techniques of scanning electron microscope (SEM), transmission (TEM), X-ray diffractometer (XRD), photoelectron spectroscopy (XPS), N2 adsorption/desorption, and UV–vis diffuse reflectance spectrum (DRS). Furthermore, the sonocatalytic degradation performance towards tetracycline (TC) was investigated under ultrasonic radiation. results showed that, combined with potassium persulfate (K2S2O8), achieved a high efficiency 97.89 % within 10 min, which much better than bare Ag3PO4 or CoWO4. By measuring electrochemical properties, it proposed that mechanism is formation S-scheme heterojunction, increases separation electron-hole pairs (e--h+) generates more electrons holes, thereby enhancing activity. scavenger experiments confirmed hole (h+) primary active substance in degrading TC, free radicals (OH) superoxide anion radical (O2–) auxiliary substances. indicated nanocomposites could be used as an efficient reliable sonocatalyst for wastewater treatment.

Language: Английский

Citations

42

Sonoactivated Nanomaterials: A potent armament for wastewater treatment DOI Creative Commons
Jianfeng Bao,

Shuangshaung Guo,

Dandan Fan

et al.

Ultrasonics Sonochemistry, Journal Year: 2023, Volume and Issue: 99, P. 106569 - 106569

Published: Aug. 29, 2023

The world is currently facing a critical issue of water pollution, with wastewater being major contributor. It comes from different types pollutants, including industrial, medical, agricultural, and domestic. Effective treatment requires efficient degradation pollutants carcinogens prior to discharge. Commonly used methods for include filtration, adsorption, biodegradation, advanced oxidation processes, Fenton oxidation, among others.The sonochemical effect refers the decomposition, reduction, other reactions pollutant molecules in upon ultrasound activation, achieving removal. Furthermore, micro-flow generated by ultrasonic waves creates tiny bubbles eddies. This significantly increases contact area exchange speed dissolved oxygen, thereby accelerating degradation. Currently, ultrasonic-assisted technology has emerged as promising approach due its strong ability, simple cheap equipments, minimal secondary pollution. However, use some limitations, such high energy consumption, lengthy time, limited capacity, stringent quality requirements, unstable effects. To address these issues, combination enhanced nanotechnology proposed shown great potential treatment. Such can greatly improve efficiency resulting an improved performance purification. article presents recent progress development sonoactivated nanomaterials disposal. are systematically classified discussed. Potential challenges future prospects this emerging also highlighted.

Language: Английский

Citations

23

Peroxydisulfate-assisted sonocatalytic degradation of metribuzin by La-doped ZnFe layered double hydroxide DOI Creative Commons

Sultan Akdağ,

Tannaz Sadeghi Rad, Ramazan Keyikoğlu

et al.

Ultrasonics Sonochemistry, Journal Year: 2022, Volume and Issue: 91, P. 106236 - 106236

Published: Nov. 23, 2022

Metribuzin is an herbicide that easily contaminates ground and surface water. Herein, La-doped ZnFe layered double hydroxide (LDH) was synthesized for the first time used degradation of metribuzin via ultrasonic (US) assisted peroxydisulfate (PDS) activation. The LDH had a lamellar structure, average thickness 26 nm, showed mesoporous characteristics, including specific area 110.93 m

Language: Английский

Citations

30

Ultrasonic degradation of tetracycline combining peroxymonosulfate and BiVO4 microspheres DOI

Long Zeng,

Chenghui Wang, Jing Hu

et al.

Journal of Water Process Engineering, Journal Year: 2023, Volume and Issue: 56, P. 104428 - 104428

Published: Oct. 14, 2023

Language: Английский

Citations

19