Photocatalysis and Electrocatalysis Properties of a Keggin-Type Inorganic–Organic Hybrid SiW12O40@Ag DOI Creative Commons

Xinxin Hu,

Tianhui Chen,

Xiaojie Gong

et al.

Inorganics, Journal Year: 2025, Volume and Issue: 13(5), P. 132 - 132

Published: April 25, 2025

An example of an inorganic–organic hybrid compound {[Ag4(SiW12O40)(HBTA)8][Ag4(SiW12O40)(HBTA)8(H2O)]}n·(1) modified by the Keggin-type [SiW12O40]4− polyoxoanion was synthesized hydrothermally, which determined single crystal X-ray diffraction. Two 1-dimensional (1D) chains are present in 1: chain a is connected Ag···Ag interactions and b π···π stacking. Finally, they were extended into 2D 3D supramolecular structures hydrogen bonding. The photodegradation methylene blue (MB) investigated under visible light irradiation, degradation rate reached 99.4% within 200 min. In addition, 1 catalyzes reduction sodium nitrite can be used as potential electrocatalytic material.

Language: Английский

Photocatalysis and Electrocatalysis Properties of a Keggin-Type Inorganic–Organic Hybrid SiW12O40@Ag DOI Creative Commons

Xinxin Hu,

Tianhui Chen,

Xiaojie Gong

et al.

Inorganics, Journal Year: 2025, Volume and Issue: 13(5), P. 132 - 132

Published: April 25, 2025

An example of an inorganic–organic hybrid compound {[Ag4(SiW12O40)(HBTA)8][Ag4(SiW12O40)(HBTA)8(H2O)]}n·(1) modified by the Keggin-type [SiW12O40]4− polyoxoanion was synthesized hydrothermally, which determined single crystal X-ray diffraction. Two 1-dimensional (1D) chains are present in 1: chain a is connected Ag···Ag interactions and b π···π stacking. Finally, they were extended into 2D 3D supramolecular structures hydrogen bonding. The photodegradation methylene blue (MB) investigated under visible light irradiation, degradation rate reached 99.4% within 200 min. In addition, 1 catalyzes reduction sodium nitrite can be used as potential electrocatalytic material.

Language: Английский

Citations

0