Environmental Research,
Journal Year:
2024,
Volume and Issue:
263, P. 120132 - 120132
Published: Oct. 9, 2024
Municipal
wastewater
treatment
plants
(WWTPs)
are
crucial
for
maintaining
good
quality
of
surface
water,
limiting
environmental
pollution.
However,
during
wet-weather
events,
WWTPs
become
an
important
point-source
discharge
due
to
the
activation
bypass,
which
releases
a
mix
untreated
and
stormwater.
This
work
aims
assess
how
WWTP
discharges
(effluent
bypass)
impact
on
receiving
water
body
dry-
wet-weather,
monitoring
78
pollutants
(7
conventional
pollutants,
19
heavy
metals,
52
micropollutants)
in
each
stream
dry-weather,
effluent
bypass
wet-weather),
including
influent
dry-weather
comparison.
The
occurrence,
concentration
levels
variability,
risk
were
addressed,
with
specific
focus
high-resolution
(up
20-min)
sampling
based
expected
relevant
temporal
dynamicity.
A
wider
range
occurred
included
undetected
compounds
influent.
Besides,
greater
inter-events
variability
concentrations
was
observed,
but
smaller
intra-event
only
some
exhibiting
distinct
first-flush
effect.
To
address
challenge
cost-effective
monitoring,
we
explored
applicability
readily
measurable
parameters
(total
suspended
solids
electrical
conductivity)
as
proxies
micropollutants.
Correlations
between
these
pollutant
groups
suggest
promising
path
further
investigation
broader
application.
magnitude
rain
event
also
affected
levels,
volume
clearly
affecting
dilution.
assessment
revealed
significantly
higher
associated
compared
effluent,
especially
terbutryn,
highlighting
urgency
improved
management
strategies.
Overall,
this
study
highlights
contribution
from
WWTPs,
emphasizing
importance
high-frequency
capture
peak
accurately
risk.
The Science of The Total Environment,
Journal Year:
2023,
Volume and Issue:
900, P. 165734 - 165734
Published: July 25, 2023
This
field
study
assessed
the
occurrence,
event
mean
concentrations
(EMCs),
and
removal
of
selected
organic
micro-pollutants
(OMPs),
namely,
polycyclic
aromatic
hydrocarbons
(PAHs),
petroleum
(PHCs),
nonylphenol
(NP),
4-t-octylphenol
(OP),
bisphenol
A
(BPA),
in
a
gross
pollutant
trap
(GPT)-biofilter/sand
filter
stormwater
treatment
train
Sundsvall,
Sweden.
The
effects
design
features
each
unit,
including
pre-sedimentation
(GPT),
sand
medium,
vegetation,
chalk
amendment,
were
investigated
by
comparing
units'
performances.
Overall,
removed
most
OMPs
from
highway
runoff
effectively.
results
showed
that
although
provided
moderate
(<50
%
for
phenolic
substances)
to
high
(50-80
PAHs
PHCs)
OMPs,
adding
vegetated
soil
layer
on
top
considerably
improved
performance
(by
at
least
30
%),
especially
BPA,
OP,
suspended
solids.
Moreover,
GTP
did
not
contribute
significantly.
Uncertainties
efficiencies
PHCs
cells
increased
substantially
when
ratio
influent
concentration
limit
quantification
decreased.
Thus,
accounting
such
uncertainties
due
low
OMP
should
be
considered
evaluating
biofilters.
Water Research,
Journal Year:
2025,
Volume and Issue:
278, P. 123318 - 123318
Published: Feb. 19, 2025
Organic
micropollutants
in
combined
sewer
overflows
(CSOs)
pose
a
potential
risk
to
aquatic
ecosystems.
Previous
studies
mainly
reported
event
mean
concentrations
(EMCs)
and
often
focused
on
small
number
of
substances.
This
study
presents
realistic
exposure
scenarios
using
high-temporal
resolution
(10-minute)
data
from
24
events
at
two
CSO
sites.
We
analyzed
49
dissolved
organic
for
all
198
four
events,
including
pharmaceuticals,
pesticides,
road-related
compounds,
which
we
detected
83
substances
least
once.
From
these,
assessed
the
mixed
chemical
by
applying
acute
quality
criteria
evaluated
how
assessment
outcome
changes
aspects:
temporal
selection
Our
results
reveal
that
total
quotients
(RQtot)
can
vary
greatly
within
with
10-minute
capturing
peak
are
missed
EMCs.
Using
EMCs
underestimates
maximum
RQtot
an
median
factor
4.9,
up
6.9.
When
comparing
20
Swiss
Waters
Protection
Ordinance
broader
list
commonly
CSOs
comprehensive
substances,
estimated
increases
between
1.1
2.3-fold.
values
exceed
threshold
1
75
%
requiring
further
dilution
receiving
water
body.
All
three
pollutant
classes
(pharma,
pesticide,
road)
drive
risk,
no
specific
phase
during
overflow
consistently
poses
higher
than
other
phases,
challenges
design
effective
mitigation
measures.
Furthermore,
presented
here
offer
essential
input
future
ecotoxicological
research
as
they
high
short-term
fluctuations
whose
ecological
significance
is
still
largely
unknown.
Water Research,
Journal Year:
2025,
Volume and Issue:
unknown, P. 123547 - 123547
Published: March 1, 2025
Biochar
is
often
promoted
as
an
ideal
amendment
for
stormwater
biofilters;
however,
its
effectiveness
has
rarely
been
tested
under
field
conditions.
This
study
evaluates
the
impact
of
biochar
addition
on
removal
organic
micropollutants
(OMPs)
in
field-scale
biofilters
operating
real-world
conditions
first
time.
The
research
comprised
four
vegetated
biofilter
facilities
(3
-
5
years
old),
two
without
and
with
2.1
wt.
%
(10
vol.
%)
amendment.
Stormwater
filter
material
samples
from
various
locations
after
operation
were
analyzed
a
wide
range
common
emerging
OMPs
found
urban
runoff.
Unlike
hydrophobic
(hydrocarbons,
polychlorinated
biphenyls,
di(2-ethylhexyl)
phthalate),
investigated
demonstrated
low,
or
inconsistent,
hydrophilic
slow-adsorbing
like
bisphenol
A,
monobutyltin,
per-fluoroalkyl
substances
(PFASs).
Although
physiochemical
properties
well-adapted
to
pollutant
removal,
did
not
significantly
improve
OMP
when
compared
status
quo.
can
be
attributed
several
suboptimal
design
interfering
biochar's
sorption
capacity,
namely,
large
particle
size
(D50
∼4
mm)
low
quantity
biochar,
high
levels
competing
agents
(i.e.,
dissolved
oxygen
carbon
(DOC)
cations),
co-contaminants
stormwater,
limited
contact
time,
pore
blockage
(e.g.,
by
DOC
molecules
sediments/minerals),
diminished
surface
porosity,
sometimes
increased
uncertainty
due
influent
concentrations.
Our
findings
complexities
associated
applying
treatment.
Further
biochar-specific
designs
needed
optimize
potential
this
The Science of The Total Environment,
Journal Year:
2023,
Volume and Issue:
894, P. 165028 - 165028
Published: June 21, 2023
Stormwater
runoff
is
a
key
pathway
for
diffuse
pollutants
to
enter
receiving
waters.
Mitigating
measures
include
pollutant
substitution,
restricting
their
release
into
the
urban
technosphere
and
limiting
(re-)mobilisation
of
substances
minimise
negative
impacts
on
Gully
pots
(GPs)
are
one
most
ubiquitous
drainage
infrastructure
components,
providing
both
function
onward
transport
through
in-pot
sedimentation
processes.
In
this
study,
sediments
accumulated
over
one-year
period
were
collected
from
26
GPs
in
catchments
four
land-use
types
Stockholm,
Sweden.
Sediments
analysed
101
organic
eight
substance
groups
(hydrocarbons,
polycyclic
aromatic
hydrocarbons,
alkylphenols,
polychlorinated
biphenyls,
phthalates,
organotins,
per-
polyfluoroalkyl
brominated
fire
retardants)
inform
an
assessment
occurrence
net
accumulation
rates
typical
unit
operation
period.
A
total
63
quantified
at
least
GP,
with
aliphatic
phthalates
organotins
all
GP
sediments,
highlighting
use.
The
identification
14
21
two
pedestrian/bike
path
emphasise
contribution
non-vehicular
sources
loads.
Significantly
higher
mass
4-tert-octylphenol,
4-nonylphenols,
formaldehyde,
dioctyltin
dibutyltin
identified
commercial
catchment
suggesting
need
enhance
source-tracing
quality-control
within
type.
25
exceeding
toxicology-based
threshold
values,
reducing
potential
ecotoxic
recipients.