ACS Applied Materials & Interfaces,
Journal Year:
2023,
Volume and Issue:
15(40), P. 46971 - 46981
Published: Sept. 27, 2023
The
exploitation
of
high-performance
supercapacitors
is
crucial
to
promote
energy
storage
technologies.
Benefiting
from
the
three-dimensional
conductive
micronanostructures
and
high
specific
capacity
PPy@CuCo2S4@NF
(polypyrrole/copper
cobalt
sulfide/nickel
foam)
composite
electrode,
this
electrode
exhibits
a
1403.21
C
g-1
at
1
A
capacitance
retention
85.79%
after
10,000
cycles
10
g-1.
assembled
PPy@CuCo2S4@NF//AC
aqueous
hybrid
supercapacitor
(AHSC)
reveals
wide
operating
potential
window
1.5
V
achieves
322.52
86.84%
15,000
AHSC
also
power
density
733.69
W
kg-1
an
67.19
h
kg-1,
surpassing
those
previously
reported
spinel-based
supercapacitors.
Ex
situ
X-ray
diffraction
photoelectron
spectroscopy
results
show
that
CuCo2S4
spinel
structure
changes
CuS2
CoS2
cube
structures,
oxidation
states
Cu
Co
increase
during
charging
discharging
processes.
Density
functional
theory
calculations
suggest
superior
conductivity
for
compared
CuCo2O4,
demonstrating
has
electrochemical
performance.
These
findings
attest
considerable
materials
advanced
applications.
ACS Applied Materials & Interfaces,
Journal Year:
2023,
Volume and Issue:
15(40), P. 46971 - 46981
Published: Sept. 27, 2023
The
exploitation
of
high-performance
supercapacitors
is
crucial
to
promote
energy
storage
technologies.
Benefiting
from
the
three-dimensional
conductive
micronanostructures
and
high
specific
capacity
PPy@CuCo2S4@NF
(polypyrrole/copper
cobalt
sulfide/nickel
foam)
composite
electrode,
this
electrode
exhibits
a
1403.21
C
g-1
at
1
A
capacitance
retention
85.79%
after
10,000
cycles
10
g-1.
assembled
PPy@CuCo2S4@NF//AC
aqueous
hybrid
supercapacitor
(AHSC)
reveals
wide
operating
potential
window
1.5
V
achieves
322.52
86.84%
15,000
AHSC
also
power
density
733.69
W
kg-1
an
67.19
h
kg-1,
surpassing
those
previously
reported
spinel-based
supercapacitors.
Ex
situ
X-ray
diffraction
photoelectron
spectroscopy
results
show
that
CuCo2S4
spinel
structure
changes
CuS2
CoS2
cube
structures,
oxidation
states
Cu
Co
increase
during
charging
discharging
processes.
Density
functional
theory
calculations
suggest
superior
conductivity
for
compared
CuCo2O4,
demonstrating
has
electrochemical
performance.
These
findings
attest
considerable
materials
advanced
applications.