Industrial & Engineering Chemistry Research,
Journal Year:
2024,
Volume and Issue:
63(46), P. 20343 - 20355
Published: Nov. 11, 2024
A
zirconium-based
metal–organic
framework
(UiO-66-NH2)
was
fabricated,
which
then
hybridized
with
TiO2.
The
synthesized
adsorbent
utilized
for
the
adsorption
of
ampicillin
(AMP)
and
lead
(Pb(II))
from
an
aqueous
solution.
main
characterization
analyses
including
Fourier
transform
infrared
(FTIR)
spectroscopy,
X-ray
diffraction
(XRD),
N2
adsorption/desorption
isotherms,
thermogravimetry
(TG),
energy-dispersive
spectroscopy
(EDS),
elemental
mapping,
transmission
electron
microscopy
(TEM),
field-emission
scanning
(FESEM),
water
contact
angle,
XPS
affirmed
correctness
synthesis.
nanocomposite
UiO-66-NH2/TiO2
had
a
high
crystallinity,
surface
area
(1050
m2/g),
stability
up
to
600
°C.
Adsorption
experiments
were
performed
explore
different
parameters
affecting
adsorption.
results
revealed
fast
kinetics
this
adsorbent.
majority
AMP
Pb(II)
adsorbed
in
30
min,
pseudo-second-order
kinetic
model
better
agreement
empirical
data
(R2
≥
0.993).
Furthermore,
Langmuir
isotherm
0.987)
fitted
compared
Freundlich
0.920).
maximum
capacity
625.7
mg/g
gained
769.2
(pH
7
±
0.1
T
=
300
1
K),
1.3
1.5
times
greater,
pristine
UiO-66-NH2.
thermodynamic
study
demonstrated
that
process
AMP/Pb(II)
by
is
spontaneous
exothermic.
allocated
area,
large
number
active
sites,
hydrogen
bonding,
hydrophobic
forces,
electrostatic
interactions,
π–π
interactions.
Finally,
acceptable
reusability
five
regeneration
cycles.
With
its
sustainable
easy
fabrication,
remarkable
performance,
excellent
capability,
emerges
as
highly
effective
industrial
wastewater
treatment
applications.
Practice, progress, and proficiency in sustainability,
Journal Year:
2024,
Volume and Issue:
unknown, P. 254 - 273
Published: July 26, 2024
Machine
learning
(ML)
and
deep
(DL)
focused
on
models
with
many
parameters
arranged
in
artificial
neural
network
architectures
are
increasingly
being
applied
as
powerful
tools
for
change
across
various
scientific
disciplines,
including
but
not
limited
to
oceanography
climate
science.
In
turn,
these
“data
assimilation”
provide
a
critical
path
toward
further
harnessing
the
ocean's
new
data
capacity
improve
how
we
model
predict
climate.
ML
algorithms
have
been
used
solve
variety
of
problems
related
our
oceans
habitat
sea
level
prediction,
wind
wave
front
dressing
alongside
detection
systems
submersible
objects.ML
DL
methods
also
FFR
skill
forecasting
The
use
enables
extraction
interpretation
latent
patterns,
unveiling
untapped
potential
information
available
large
volumes-but-complex
datasets.
This
chapter
focuses
integration
Learning
Deep
precision
modelling
predictions.
Processes,
Journal Year:
2024,
Volume and Issue:
12(9), P. 1905 - 1905
Published: Sept. 5, 2024
In
today’s
ongoing
rapid
urban
expansion,
deforestation
and
climate
changes
can
be
observed
mainly
as
unbalanced
rain
occurrence
during
the
year,
long
seasons
without
any
at
all
unordinary
high
temperatures.
These
adverse
affect
underground
water
levels
availability
of
surface
water.
addition,
quite
a
significant
proportion
drinking
is
used
for
non-drinking
purposes.
With
several
EU
countries
increasingly
suffering
from
droughts,
reusing
quaternary
treated
wastewater
help
address
scarcity.
At
European
level,
Regulation
2020/741
Parliament
Council
25
May
2020
on
minimum
requirements
reuse
was
adopted.
This
regulation
foresees
use
recycled
agricultural
irrigation.
article
provides
an
overview
various
processes,
such
filtration,
coagulation,
adsorption,
ozonation,
advanced
oxidation
processes
disinfection,
treatment
in
order
to
remove
micropollutants
achieve
reuse.
According
literature,
most
effective
method
with
acceptable
financial
costs
combination
membrane
filtration
(UF
or
NF)
UV
disinfection.
are
relatively
well
known
commercially
available.
also
helps
researchers
identify
key
themes
concepts,
evaluate
strengths
weaknesses
previous
studies
determine
areas
where
further
research
needed.
Industrial & Engineering Chemistry Research,
Journal Year:
2024,
Volume and Issue:
63(46), P. 20343 - 20355
Published: Nov. 11, 2024
A
zirconium-based
metal–organic
framework
(UiO-66-NH2)
was
fabricated,
which
then
hybridized
with
TiO2.
The
synthesized
adsorbent
utilized
for
the
adsorption
of
ampicillin
(AMP)
and
lead
(Pb(II))
from
an
aqueous
solution.
main
characterization
analyses
including
Fourier
transform
infrared
(FTIR)
spectroscopy,
X-ray
diffraction
(XRD),
N2
adsorption/desorption
isotherms,
thermogravimetry
(TG),
energy-dispersive
spectroscopy
(EDS),
elemental
mapping,
transmission
electron
microscopy
(TEM),
field-emission
scanning
(FESEM),
water
contact
angle,
XPS
affirmed
correctness
synthesis.
nanocomposite
UiO-66-NH2/TiO2
had
a
high
crystallinity,
surface
area
(1050
m2/g),
stability
up
to
600
°C.
Adsorption
experiments
were
performed
explore
different
parameters
affecting
adsorption.
results
revealed
fast
kinetics
this
adsorbent.
majority
AMP
Pb(II)
adsorbed
in
30
min,
pseudo-second-order
kinetic
model
better
agreement
empirical
data
(R2
≥
0.993).
Furthermore,
Langmuir
isotherm
0.987)
fitted
compared
Freundlich
0.920).
maximum
capacity
625.7
mg/g
gained
769.2
(pH
7
±
0.1
T
=
300
1
K),
1.3
1.5
times
greater,
pristine
UiO-66-NH2.
thermodynamic
study
demonstrated
that
process
AMP/Pb(II)
by
is
spontaneous
exothermic.
allocated
area,
large
number
active
sites,
hydrogen
bonding,
hydrophobic
forces,
electrostatic
interactions,
π–π
interactions.
Finally,
acceptable
reusability
five
regeneration
cycles.
With
its
sustainable
easy
fabrication,
remarkable
performance,
excellent
capability,
emerges
as
highly
effective
industrial
wastewater
treatment
applications.
