Water Science & Technology,
Journal Year:
2024,
Volume and Issue:
89(12), P. 3344 - 3356
Published: June 10, 2024
ABSTRACT
In
this
study,
a
potassium
ferrate
(K2FeO4)-modified
biochar
(Fe–BC)
was
prepared
and
characterized.
Afterwards,
Fe–BC
applied
to
activated
periodate
(PI)
degrade
tetracycline
(TC),
an
antibiotic
widely
used
in
animal
farming.
The
degradation
effects
of
different
systems
on
TC
were
compared
the
influencing
factors
investigated.
addition,
several
reactive
oxygen
species
(ROS)
generated
by
Fe–BC/PI
system
identified,
pathways
analyzed.
Moreover,
reuse
performance
evaluated.
results
exhibited
that
could
remove
almost
100%
under
optimal
conditions
[BC]
=
1.09
g/L,
initial
[PI]
3.29
[TC]
20.3
mg/L.
Cl−,
HCO3−,
NO3−,
humic
acid
inhibited
varying
degrees
due
their
quenching
ROS.
degraded
into
intermediates
even
water
carbon
dioxide
synergistic
effect
ROS
Fe
BC
surface.
reused
four
times,
removal
rate
still
maintained
above
80%,
indicating
stable
nature
Fe–BC.
Recently,
piezoelectric
and
photocatalytic
processes
have
shown
excellent
synergistic
effect
addressing
environmental
remediation
challenges.
Herein,
a
nanoflower-like
Mo
vacancy-modulated
MoS2
(VMo-MoS2)
piezo-photocatalyst
with
different
VMo
densities
has
been
successfully
synthesized
using
one-step
hydrothermal
method.
The
high
density
(12%)
facilitates
the
enhancement
of
activity
but
compromises
its
structural
stability,
resulting
in
unsatisfactory
activity.
Among
all
VMo-MoS2
piezo-photocatalysts,
6%
exhibits
highest
piezo-photocurrent
(15.50
μA
cm-2),
largest
potential
difference
(0.188
V),
best
carbamazepine
(CBZ)
degradation
efficiency
(95.81%)
only
10
min
under
light-ultrasound
action,
exhibiting
remarkable
processes.
performance
originates
from
simultaneous
modulation
charge
distribution
self-polarization
capability
S-Mo-S
structure
by
VMo,
as
confirmed
molecular
theory
calculations
finite-element
simulation
results.
This
work
provides
defect
engineering
strategy
for
achieving
processes,
which
opens
new
research
avenue
design
application
piezo-photocatalyst.
Water Science & Technology,
Journal Year:
2024,
Volume and Issue:
89(12), P. 3344 - 3356
Published: June 10, 2024
ABSTRACT
In
this
study,
a
potassium
ferrate
(K2FeO4)-modified
biochar
(Fe–BC)
was
prepared
and
characterized.
Afterwards,
Fe–BC
applied
to
activated
periodate
(PI)
degrade
tetracycline
(TC),
an
antibiotic
widely
used
in
animal
farming.
The
degradation
effects
of
different
systems
on
TC
were
compared
the
influencing
factors
investigated.
addition,
several
reactive
oxygen
species
(ROS)
generated
by
Fe–BC/PI
system
identified,
pathways
analyzed.
Moreover,
reuse
performance
evaluated.
results
exhibited
that
could
remove
almost
100%
under
optimal
conditions
[BC]
=
1.09
g/L,
initial
[PI]
3.29
[TC]
20.3
mg/L.
Cl−,
HCO3−,
NO3−,
humic
acid
inhibited
varying
degrees
due
their
quenching
ROS.
degraded
into
intermediates
even
water
carbon
dioxide
synergistic
effect
ROS
Fe
BC
surface.
reused
four
times,
removal
rate
still
maintained
above
80%,
indicating
stable
nature
Fe–BC.