Langmuir,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 3, 2024
The
advanced
oxidation
process
based
on
S(IV)
has
garnered
increasing
attention,
owing
to
its
efficiency
in
degrading
contaminants.
Here,
a
cobalt-doped
cerium
oxide
catalyst
(Co-CeO
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 1, 2024
Abstract
Many
existing
research
focuses
on
the
differences
or
performance
comparisons
between
single‐atom
small‐sized
nanocluster
catalysts,
but
there
is
a
lack
of
comprehensive
coupling
relationship
structure
and
activity
mechanism
synergy.
This
study
investigates
combined
catalytic
potential
cobalt
single
atoms
(SAs)
nanoclusters
(NCs)
for
enhanced
peroxymonosulfate
(PMS)
activation
to
degrade
norfloxacin
(NFX).
A
novel
Co
SAs‐NCs
/CN/TiO
2
catalyst
synthesized,
featuring
SAs
NCs
uniformly
dispersed
carbon
film
wrapping
TiO
,
degradation
efficiency
NFX
solution
almost
completely
degraded,
with
mineralization
rate
76.35%.
Density
functional
theory
(DFT)
calculations
indicate
that
synergistic
interaction
promotes
more
efficient
PMS
adsorption
significantly
reduces
energy
barrier,
which
enhances
electron
transfer
increases
reactive
oxygen
species
(ROS)
generation.
highlights
robust
versatile
nature
this
system
in
addressing
various
contaminants.
elucidates
providing
new
ideas
advanced
oxidation
processes
(AOPs)
environmental
remediation,
linking
emphasizes
practicality
importance
effectively
long‐term
remediation
water
pollutants.
Advanced Sustainable Systems,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 10, 2025
Abstract
This
work
reports
a
class
of
packable
composite
catalysts
in
form
submillimetric
patchy
particles
which
demonstrate
an
excellent
recyclability.
Those
are
simply
constructed
via
the
hydrothermal
treatment
dense
slurry
hydroxylated
ultrahigh
molecular
weight
polyethylene
(UHMWPE)
and
carbon
nitride
microtubes.
These
large‐sized
can
be
directly
packed
into
tea
bag
made
800
mesh
nylon
filter
cloth.
kind
porous
package
allows
arrival
light
on
meanwhile
significantly
benefits
recovery
photocatalysts
from
polluted
water.
Robust
adhesion
tubular
UHMWPE
powders
is
established
creating
synergies
between
van
der
Waals
force
hydrogen
bonding
for
maintaining
high
degrading
ability
these
even
after
30
cycles.