Chemical Reviews,
Journal Year:
2024,
Volume and Issue:
124(15), P. 9015 - 9080
Published: July 17, 2024
Making
a
measurement
over
millions
of
nanoparticles
or
exposed
crystal
facets
seldom
reports
on
reactivity
single
nanoparticle
facet,
which
may
depart
drastically
from
ensemble
measurements.
Within
the
past
30
years,
science
has
moved
toward
studying
atoms,
molecules,
and
nanoparticles,
one
at
time.
This
shift
been
fueled
by
realization
that
everything
changes
nanoscale,
especially
important
industrially
relevant
properties
like
those
to
electrocatalysis.
Studying
nanoscale
entities,
however,
is
not
trivial
required
development
new
tools.
review
explores
tale
clever
use
old
tools
study
electrocatalysis
entity
level.
We
explore
in
detail
complex
interrelationship
between
method,
electrocatalytic
material,
reaction
interest
(e.g.,
carbon
dioxide
reduction,
oxygen
hydrazine
oxidation,
etc.).
end
with
our
perspective
future
key
focus
what
types
measurements
present
greatest
opportunity
for
fundamental
discovery.
Catalysts,
Journal Year:
2023,
Volume and Issue:
13(10), P. 1346 - 1346
Published: Oct. 5, 2023
The
proton
exchange
membrane
water
electrolyzer
(PEM-WE)
is
a
well-known
green
technology
for
hydrogen
production.
main
obstacle
to
its
development,
on
large
scale,
the
sluggish
kinetics
of
oxygen
evolution
reaction
(OER).
At
present,
design
acid-stable
electrocatalysts
with
low
overpotential
and
excellent
stability
OER
constitutes
an
important
activity
in
electrocatalysis.
This
review
presents
analysis
fundamentals
strategies
advanced
evolution,
mechanisms,
descriptors.
scrutiny
electrocatalysts,
elemental
composition
from
single-
multielemental,
are
presented.
In
addition,
purpose
high-entropy
alloys
(HEAs),
recent
research
strategy,
materials
summarized.
Briefly,
effect
support
materials,
which
beneficial
modulating
electronic
properties
catalysts,
Finally,
prospects
development
acidic
given.
Small Methods,
Journal Year:
2023,
Volume and Issue:
unknown
Published: Dec. 31, 2023
Abstract
Facing
with
serious
carbon
emission
issues,
the
production
of
green
H
2
from
electrocatalytic
hydrogen
evolution
reaction
(HER)
has
received
extensive
research
interest.
Almost
all
kinds
noble
metal
phosphides
(NMPs)
consisting
Pt‐group
elements
(i.e.,
Ru,
Rh,
Pd,
Os,
Ir
and
Pt)
are
highly
active
pH‐universal
electrocatalysts
toward
HER.
In
this
review,
recent
progress
NMP‐based
HER
is
summarized.
It
further
take
typical
examples
for
discussing
important
impact
factors
on
performance
NMPs,
including
crystalline
phase,
morphology,
element
doping.
Moreover,
synthesis
application
hybrid
catalysts
NMPs
other
materials
such
as
transition
phosphides,
oxides,
sulfides
phosphates,
metals
also
reviewed.
Reducing
use
key
idea
electrocatalysts,
while
expanded
functionality
structure‐performance
relationship
noticed
in
part.
At
last,
potential
opportunities
challenges
kind
catalyst
discussed.
Materials Horizons,
Journal Year:
2024,
Volume and Issue:
11(18), P. 4239 - 4255
Published: Jan. 1, 2024
This
review
summarizes
the
design
strategies
of
MXene-based
catalysts
for
HER,
OER,
ORR
and
NRR,
including
surface
modification,
MXene
lattice
substitution,
morphology,
defect
heterostructure
engineering.
Chemical Reviews,
Journal Year:
2024,
Volume and Issue:
124(15), P. 9015 - 9080
Published: July 17, 2024
Making
a
measurement
over
millions
of
nanoparticles
or
exposed
crystal
facets
seldom
reports
on
reactivity
single
nanoparticle
facet,
which
may
depart
drastically
from
ensemble
measurements.
Within
the
past
30
years,
science
has
moved
toward
studying
atoms,
molecules,
and
nanoparticles,
one
at
time.
This
shift
been
fueled
by
realization
that
everything
changes
nanoscale,
especially
important
industrially
relevant
properties
like
those
to
electrocatalysis.
Studying
nanoscale
entities,
however,
is
not
trivial
required
development
new
tools.
review
explores
tale
clever
use
old
tools
study
electrocatalysis
entity
level.
We
explore
in
detail
complex
interrelationship
between
method,
electrocatalytic
material,
reaction
interest
(e.g.,
carbon
dioxide
reduction,
oxygen
hydrazine
oxidation,
etc.).
end
with
our
perspective
future
key
focus
what
types
measurements
present
greatest
opportunity
for
fundamental
discovery.
