Fabrication and structure evolution of porous copper via one-step dealloying of H62 copper-zinc alloy DOI
Qiang Gao, Bing Ye, Wei Huang

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: 1014, P. 178796 - 178796

Published: Jan. 26, 2025

Language: Английский

Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting DOI
Quan Li, Hui Jiang,

Guoliang Mei

et al.

Chemical Reviews, Journal Year: 2024, Volume and Issue: 124(7), P. 3694 - 3812

Published: March 22, 2024

Electrocatalytic water splitting driven by renewable electricity has been recognized as a promising approach for green hydrogen production. Different from conventional strategies in developing electrocatalysts the two half-reactions of (e.g., and oxygen evolution reactions, HER OER) separately, there growing interest designing bifunctional electrocatalysts, which are able to catalyze both OER. In addition, considering high overpotentials required OER while limited value produced oxygen, is another rapidly exploring alternative oxidation reactions replace hybrid toward energy-efficient generation. This Review begins with an introduction on fundamental aspects splitting, followed thorough discussion various physicochemical characterization techniques that frequently employed probing active sites, emphasis reconstruction during redox electrolysis. The design, synthesis, performance diverse based noble metals, nonprecious metal-free nanocarbons, overall acidic alkaline electrolytes, thoroughly summarized compared. Next, their application also presented, wherein anodic include sacrificing agents oxidation, pollutants oxidative degradation, organics upgrading. Finally, concise statement current challenges future opportunities presented hope guiding endeavors quest sustainable

Language: Английский

Citations

229

Advances in MOFs and their derivatives for non‑noble metal electrocatalysts in water splitting DOI

Guoliang Gao,

Xueli Chen, Lu Han

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 503, P. 215639 - 215639

Published: Jan. 8, 2024

Language: Английский

Citations

73

Heteroatom-doped MXenes as electrocatalysts for hydrogen evolution reaction: A review on the recent advances, mechanisms and prospects DOI
Abdul Hanan, Muhammad Nazim Lakhan, Rashmi Walvekar

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 483, P. 149107 - 149107

Published: Jan. 28, 2024

Language: Английский

Citations

52

In Situ Assembly of a Superaerophobic CoMn/CuNiP Heterostructure as a Trifunctional Electrocatalyst for Ampere-Level Current Density Urea-Assisted Hydrogen Production DOI
Reza Andaveh, A. Sabour Rouhaghdam, Abdolvahab Seif

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(7), P. 8717 - 8732

Published: Feb. 7, 2024

Urea electrolysis is a promising energy-efficient hydrogen production process with environmental benefits, but the lack of efficient and sustainable ampere-level current density electrocatalysts fabricated through simple methods major challenge for commercialization. Herein, we present an stable heterostructure electrocatalyst full urea water in convenient time-efficient preparation manner. Overall, superhydrophilic/superaerophobic CoMn/CuNiP/NF exhibits exceptional performance evolution reaction (HER) (-33.8, -184.4, -234.8 mV at -10, -500, -1000 mA cm

Language: Английский

Citations

51

A comprehensive review on the role of hydrogen in renewable energy systems DOI

Ramesh Bhandari,

Niroj Adhikari

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 82, P. 923 - 951

Published: Aug. 6, 2024

Language: Английский

Citations

37

Recent advancements in noble-metal electrocatalysts for alkaline hydrogen evolution reaction DOI

Guoliang Gao,

Guangzhen Zhao, Guang Zhu

et al.

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 109557 - 109557

Published: Jan. 1, 2024

Language: Английский

Citations

21

Recent advances in hydrogen production coupled with alternative oxidation reactions DOI

Guoliang Gao,

Zixu Sun, Xueli Chen

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 509, P. 215777 - 215777

Published: March 26, 2024

Language: Английский

Citations

21

Recent advances of high-entropy electrocatalysts for water electrolysis by electrodeposition technology: a short review DOI
Han-Ming Zhang,

Shao‐Fei Zhang,

Lihao Zuo

et al.

Rare Metals, Journal Year: 2024, Volume and Issue: 43(6), P. 2371 - 2390

Published: March 9, 2024

Language: Английский

Citations

17

Rational design of local microenvironment for electrocatalytic water splitting DOI
Xiang Li,

Wangchuan Zhu,

Yanqun Zhang

et al.

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(14), P. 4080 - 4106

Published: Jan. 1, 2024

This summary describes the effects of wettability, local pH, interfacial water structure, and electrolyte composition on interface reactant compositions, key intermediate adsorption, reaction kinetics.

Language: Английский

Citations

16

Electrocatalytic hydrogen evolution with a copper porphyrin bearing meso-(o-carborane) substituents DOI

Xinyang Peng,

Jinxiu Han,

Xialiang Li

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 59(72), P. 10777 - 10780

Published: Jan. 1, 2023

A newly designed copper complex of 5,15-bis(pentafluorophenyl)-10,20-bis(o-carborane)porphyrin (1) was synthesized and tested for the electrocatalytic hydrogen evolution reaction (HER). In acetonitrile, 1 much more efficient than Cu 5,15-bis(pentafluorophenyl)-10,20-diphenylporphyrin (2) HER by shifting catalytic wave to anodic direction 190 mV. aqueous media, also outperformed 2 achieving higher current densities under smaller overpotentials. This enhancement attributed aromatic strong electron-withdrawing properties o-carborane groups. work is significant address crucial effects meso-(o-carborane) substituents metal porphyrins on boosting HER.

Language: Английский

Citations

24