Induced C−C Coupling by Amorphous‐Crystalline Hybrid Structure for Selective CO2 Photoreduction into C2 Fuels DOI Open Access

Dongpo He,

Guangbing Huang,

Jun Hu

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 21, 2024

Abstract Selective photoreduction of carbon dioxide (CO 2 ) into high‐value C products remains a formidable challenge due to the elusive C−C coupling step. Herein, novel concept is first introduced that an amorphous‐crystalline hybrid structure can galvanize previously inert metal atoms, thereby establishing highly active dual sites. This ingenious configuration promotes coupling, paving way for CO products. Taking Bi MoO 6 nanosheets anchored by amorphous FeOOH species as example, X‐ray photoelectron spectroscopy (XPS) spectra and absorption near edge density functional theoretical (DFT) calculations confirm electron transfer from nanosheets. Thus, introduction activates nonoperative sites construction Bi−Mo sites, verified in situ XPS DFT calculations. Gibbs free energy revealed formation barrier hugely lowed 3.41 0.45 eV thanks presence species. Therefore, FeOOHBi are game changer, delivering sole liquid product, acetic acid, with impressive selectivity ≈86.9%. In contrast, lag behind, only capable producing monoxide photoreduction.

Language: Английский

Electrocatalytic and Photocatalytic CO2 Methanation: From Reaction Fundamentals to Catalyst Developments DOI

Junbo Tian,

Wenqing Xu,

Jiajian Gao

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: 16(9)

Published: Jan. 5, 2024

Abstract Transitioning from fossil fuels to renewable energy sources is demanded due the gradual depletion of petroleum oil/gas and environmental impact carbon dioxide (CO 2 ) emissions into atmosphere. Electrocatalytic photocatalytic CO reduction methane (CH 4 using crucial for sustainable chemical/fuel production greenhouse gas reduction. In recent years, extensive research has focused on understanding fundamental aspects two approaches, such as reaction mechanisms active sites, exploring/designing novel catalytic materials. This review initially discusses fundamentals, including performance evaluation indexes, reactors, mechanisms, understand reactions. Subsequently, various catalyst preparation strategies characterization methods are summarized, trying outline design principle based obtained mechanisms. Finally, challenges perspectives future development in this area discussed presented. It expected provide a comprehensive photo/electrocatalytic methanation, valuable knowledge novice researchers, helpful reference endeavors.

Language: Английский

Citations

4
Unraveling the C–C coupling mechanism on Ni–O–Fe asymmetric sites for photocatalytic nonoxidative coupling of methane DOI
Huimin Li, Zhe Sun, Chenlong Dong

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 487, P. 150582 - 150582

Published: March 20, 2024

Language: Английский

Citations

4
Steering Geometric Reconstruction of Bismuth with Accelerated Dynamics for CO2 Electroreduction DOI
Xiaowen Wang, Yangyang Zhang,

Shao Wang

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(34)

Published: June 5, 2024

Bismuth-based materials have emerged as promising catalysts in the electrocatalytic reduction of CO

Language: Английский

Citations

4
Construction of N-doped copper metal–organic frameworks for promoting photocatalytic carbon dioxide reduction to ethylene DOI
Fan Guo,

Zong-Zheng He,

Peng Wang

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 13, 2024

Language: Английский

Citations

4
Induced C−C Coupling by Amorphous‐Crystalline Hybrid Structure for Selective CO2 Photoreduction into C2 Fuels DOI Open Access

Dongpo He,

Guangbing Huang,

Jun Hu

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 21, 2024

Abstract Selective photoreduction of carbon dioxide (CO 2 ) into high‐value C products remains a formidable challenge due to the elusive C−C coupling step. Herein, novel concept is first introduced that an amorphous‐crystalline hybrid structure can galvanize previously inert metal atoms, thereby establishing highly active dual sites. This ingenious configuration promotes coupling, paving way for CO products. Taking Bi MoO 6 nanosheets anchored by amorphous FeOOH species as example, X‐ray photoelectron spectroscopy (XPS) spectra and absorption near edge density functional theoretical (DFT) calculations confirm electron transfer from nanosheets. Thus, introduction activates nonoperative sites construction Bi−Mo sites, verified in situ XPS DFT calculations. Gibbs free energy revealed formation barrier hugely lowed 3.41 0.45 eV thanks presence species. Therefore, FeOOHBi are game changer, delivering sole liquid product, acetic acid, with impressive selectivity ≈86.9%. In contrast, lag behind, only capable producing monoxide photoreduction.

Language: Английский

Citations

4