Advancing aromatic ketones as aryl electrophiles in versatile cross-coupling reactions DOI
L. XIE, Yan Xu

Chem, Journal Year: 2024, Volume and Issue: 10(9), P. 2633 - 2635

Published: Sept. 1, 2024

Language: Английский

Oxime-palladacycle complex supported on magnetic nanoparticles: a recyclable catalyst for Suzuki-type decarbonylative cross-coupling of esters with aryl boronic acid DOI
Tahshina Begum, Sazida Yasmin Sultana, Hongmei Mou

et al.

Catalysis Science & Technology, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A heterogeneous and recyclable bis-oxime palladacycle-derived silica immobilized palladium catalyst for decarbonylative cross-coupling reactions of esters with arylboronic acid in the presence 2-MeTHF.

Language: Английский

Citations

0
Mannitol‐based CO Surrogate for Palladium‐Catalyzed Alkoxycarbonylation DOI Creative Commons

Z. W. Liu,

Hefei Yang,

Zhipeng Bao

et al.

European Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 6, 2025

Abstract Carbonylative transformation is already been accepted as a powerful toolbox in synthetic chemistry. However, the manipulation of toxic and smell‐less carbon monoxide gas lagged it from wide range applications. Hence developing new efficient CO surrogates become an attractive topic. Herein, we developed novel mannitol‐based surrogate with enhanced loading capacity compared to known organic surrogates. We successfully used palladium‐catalyzed alkoxycarbonylation aryl bromides phenols only 0.5 equivalent required. This newly designed offers additional possibility for further development

Language: Английский

Citations

0
Group 10 metal complexes of the 3,4-bis(dicyclohexylphosphino)thiophene (dcypt) ligand: Synthesis, characterization and catalysis DOI Creative Commons

Vincent Fagué,

Sonia Mallet‐Ladeira, Pascal Guillo

et al.

Inorganica Chimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 122610 - 122610

Published: March 1, 2025

Language: Английский

Citations

0
Configuration Retention in P-Trifluoromethyl Phosphine Enabled Rh(I)-Catalyzed Decarbonylative Coupling of Carboxylates and Boroxines DOI
Shouzhi Zhang, Bo Li, Suhua Li

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: March 25, 2025

As compared with asymmetric catalysis, the memory of chirality provides another promising strategy to introduce chiral centers in light numerous starting materials that can be accessed. Decarboxylative coupling has become an important for C-C or C-X bond formation over decades development its versatility and low cost structural diversity carboxylic acids. However, more general configuration retention this transformation seldom been studied. Here, we report a novel π acceptor-type ligand P-trifluoromethyl phosphine enabled Rh(I)-catalyzed decarbonylative carboxylates boroxines. The α-carbon fully retained chiral, cis-, trans-substrates. Several phosphine-Rh(I) carbonyl complexes were prepared their v(CO) values known complexes, which indicated π-accepting property is reaction.

Language: Английский

Citations

0
Chemoselective Approach to Versatile Acyl Fluorides by Photoinduced Activation of p-Methoxybenzyl Esters DOI

Hee-Chan Jeong,

Hyo‐Jun Lee, Keiji Maruoka

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(37), P. 7956 - 7960

Published: Sept. 11, 2024

A new strategy for the metal-free photoinduced activation of

Language: Английский

Citations

1
Advancing aromatic ketones as aryl electrophiles in versatile cross-coupling reactions DOI
L. XIE, Yan Xu

Chem, Journal Year: 2024, Volume and Issue: 10(9), P. 2633 - 2635

Published: Sept. 1, 2024

Language: Английский

Citations

0