Recent Advances in MOF−Based Dual−Atom Catalysts for CO2 Reduction DOI
Wenjie Shi, Tong‐Bu Lu

Chemistry - A European Journal, Journal Year: 2025, Volume and Issue: unknown

Published: April 26, 2025

Abstract In recent years, the development of efficient catalysts for photo−/electro−catalytic CO 2 reduction reaction (CO RR) has become a major research focus due to growing environmental concerns and energy demands. Dual−atom (DACs), composed two metal atoms with suitable metal−metal distance integrated into supports, have shown great promise in enhancing catalytic performance via dual−metal synergistic catalysis (DMSC) effect. This review highlights advancements Metal−organic framework (MOF)−based DACs, which combine high atomic efficiency DACs tunable defined structures loadings. this review, we summarized developments on synthesis strategies MOF−based their applications RR, focusing role DMSC effect improving activity, stability, selectivity. Additionally, also discuss influence local electronic structure, coordination environment, atom interactions performance. aims provide comprehensive understanding MOF − based offers insights future potential sustainable conversion.

Language: Английский

Integrating multifactor for methane purification and storage in topological isomorphic tetranuclear cluster-based iron-organic frameworks DOI
Jiao Lei, Haipeng Li,

Zhang‐Lei Zhong

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: 361, P. 131422 - 131422

Published: Jan. 5, 2025

Language: Английский

Citations

0
Recent progress in metal-organic frameworks (Part II—material application) DOI
Jiandong Pang, Wentao Jiang, Xuewen Zhang

et al.

Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 3, 2025

Language: Английский

Citations

0
Heterogeneous Frustrated Lewis Pair Catalysts: Rational Structure Design and Mechanistic Elucidation Based on Intrinsic Properties of Supports DOI Creative Commons
Jiasi Li, Guangchao Li, Shik Chi Edman Tsang

et al.

Accounts of Chemical Research, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 28, 2025

ConspectusThe discovery of reversible hydrogenation using metal-free phosphoborate species in 2006 marked the official advent frustrated Lewis pair (FLP) chemistry. This breakthrough revolutionized homogeneous catalysis approaches and paved way for innovative catalytic strategies. The unique reactivity FLPs is attributed to base (LB) acid (LA) sites either spatial separation or equilibrium, which actively react with molecules. Since 2010, heterogeneous FLP catalysts have gained increasing attention their ability enhance performance through tailored surface designs improved recyclability, making them promising industrial applications. Over past 5 years, our group has focused on investigating strategically modifying various types solid that are from classic FLPs. We explored systematic characterization techniques unravel underlying mechanisms between active reactants. Additionally, we demonstrated critical role catalysts' intrinsic electronic geometric properties promoting formation stimulating synergistic effects. been greatly enhanced by use advanced such as synchrotron X-ray diffraction, neutron powder photoelectron spectroscopy, extended absorption fine structure, elemental mapping scanning transmission electron microscopy, paramagnetic resonance diffuse-reflectance infrared Fourier transform solid-state nuclear magnetic spectroscopy. These provided deeper insights into structural systems future design catalysts.Understanding distribution overlapping orbitals LA LB pairs essential inducing operando target reallocation external stimuli. For instance, silicoaluminophosphate-type zeolites weak orbital overlap, adsorption polar gas molecules leads heterolytic cleavage Alδ+–Oδ− bond, creating unquenched LA–LB pairs. In a Ru-doped metal–organic framework, Ru–N bond can be polarized metal–ligand charge transfer under light, forming Ru+–N– activation framework represents groundbreaking innovation expands potential existing materials. already employing chemistry dynamically generate products substrates, complete mechanistic interpretation requires thorough examination surrounding environment. hydrogen spillover surfaces improves conversion efficiency suppressing poisoning at metal sites. situ H2–H2O conditions enable production organic chemicals excellent activity selectivity new bifunctional via By highlighting novel featuring induction effects selection elucidate reaction mechanisms, hope this Account will offer strategies designing characterizing research community.

Language: Английский

Citations

0
Synthesis of a (3,7)-Connected Metal–Organic Framework by Post-Synthetic Linker Reorganization for High Iodine Adsorption DOI
Shoujun Wang, Yinghao Xu, Huanhuan Xie

et al.

Crystal Growth & Design, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 5, 2025

Language: Английский

Citations

0
Achiral and chiral metal-organic frameworks (MOFs) as an efficient catalyst for organic synthesis DOI
Narendra Pal Singh Chauhan, Panneerselvam Perumal, Narendra Singh Chundawat

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 533, P. 216536 - 216536

Published: Feb. 26, 2025

Language: Английский

Citations

0
Advances in methanol synthesis via MOF-based catalysts: A comprehensive review and critical analysis DOI

Ali Khatib Juma,

Zulkifli Merican Aljunid Merican, Abdurrashid Haruna

et al.

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114266 - 114266

Published: March 1, 2025

Language: Английский

Citations

0
Binding Sites of Automobile Exhaust Gases on Metal–Organic Frameworks: Advances and Perspectives DOI
Zongsu Han,

K. Yu,

Kunyu Wang

et al.

Energy & Fuels, Journal Year: 2025, Volume and Issue: unknown

Published: March 20, 2025

Automobile exhaust gases are major contributors to air pollution, leading severe challenges in environmental protection and public health. Metal–organic frameworks (MOFs) have emerged as promising adsorbents selectively capture gaseous pollutants due their highly tunable structures, large surface areas, abundant binding sites. This review delves into the diverse sites within MOFs for selective adsorption separation of automobile state-of-the-art technologies situ structural characterization. The roles metal centers, organic linkers, pore environments determining efficiency selectivity systematically analyzed. work provides foundation insights design construction next-generation MOF-based solid sorbents, representing innovative solutions automotive emission control promoting more sustainable transportation systems.

Language: Английский

Citations

0
Controlled encapsulation of metal aggregates in metal–organic framework architectures DOI
Mohamed Abboud, Siti Fatimah, Abdelkarim Chaouiki

et al.

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114383 - 114383

Published: March 1, 2025

Language: Английский

Citations

0
Recent Advances in MOF−Based Dual−Atom Catalysts for CO2 Reduction DOI
Wenjie Shi, Tong‐Bu Lu

Chemistry - A European Journal, Journal Year: 2025, Volume and Issue: unknown

Published: April 26, 2025

Abstract In recent years, the development of efficient catalysts for photo−/electro−catalytic CO 2 reduction reaction (CO RR) has become a major research focus due to growing environmental concerns and energy demands. Dual−atom (DACs), composed two metal atoms with suitable metal−metal distance integrated into supports, have shown great promise in enhancing catalytic performance via dual−metal synergistic catalysis (DMSC) effect. This review highlights advancements Metal−organic framework (MOF)−based DACs, which combine high atomic efficiency DACs tunable defined structures loadings. this review, we summarized developments on synthesis strategies MOF−based their applications RR, focusing role DMSC effect improving activity, stability, selectivity. Additionally, also discuss influence local electronic structure, coordination environment, atom interactions performance. aims provide comprehensive understanding MOF − based offers insights future potential sustainable conversion.

Language: Английский

Citations

0