Journal of the American Chemical Society,
Journal Year:
2018,
Volume and Issue:
140(7), P. 2438 - 2441
Published: Feb. 6, 2018
The
emergence
of
new
catalytic
strategies
that
cleverly
adopt
concepts
and
techniques
frequently
used
in
areas
such
as
photochemistry
electrochemistry
has
yielded
a
myriad
organic
reactions
would
be
challenging
to
achieve
using
orthodox
methods.
Herein,
we
discuss
the
strategic
use
anodically
coupled
electrolysis,
an
electrochemical
process
combines
two
parallel
oxidative
events,
complementary
approach
existing
methods
for
redox
transformations.
Specifically,
demonstrate
electrolysis
regio-
chemoselective
chlorotrifluoromethylation
alkenes.
Journal of the American Chemical Society,
Journal Year:
2019,
Volume and Issue:
141(8), P. 3723 - 3732
Published: Feb. 12, 2019
DNA-encoded
library
(DEL)
technology
is
a
powerful
tool
commonly
used
by
the
pharmaceutical
industry
for
identification
of
compounds
with
affinity
to
biomolecular
targets.
Success
in
this
endeavor
lies
sampling
diverse
chemical
libraries.
However,
current
DELs
tend
be
deficient
C(sp3)
carbon
counts.
We
report
unique
solutions
challenge
increasing
both
diversity
these
libraries
and
their
counts
merging
Ni/photoredox
dual
catalytic
C(sp2)-C(sp3)
cross-coupling
as
well
photoredox-catalyzed
radical/polar
crossover
alkylation
protocols
DELs.
The
successful
integration
multiple
classes
radical
sources
enables
rapid
incorporation
set
alkyl
fragments.
Angewandte Chemie International Edition,
Journal Year:
2019,
Volume and Issue:
58(34), P. 11586 - 11598
Published: Jan. 2, 2019
Abstract
Palladium
catalysis
induced
by
visible
light
is
an
emerging
field
of
catalysis.
In
contrast
to
classical
reactions
catalyzed
Pd
complexes
in
the
ground
state,
which
mostly
proceed
through
two‐electron
redox
processes,
mechanisms
these
new
methods
based
on
photoexcited
usually
operate
transfer
a
single
electron.
Such
processes
lead
putative
hybrid
Pd/radical
species,
exhibit
both
radical
and
Pd‐type
reactivity.
This
Minireview
highlights
recent
progress
this
rapidly
growing
area.
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(6), P. 5842 - 5976
Published: Jan. 24, 2022
Benefiting
from
the
impressive
increase
in
fundamental
knowledge,
last
20
years
have
shown
a
continuous
burst
of
new
ideas
and
consequently
plethora
catalytic
methods
for
enantioselective
radical
reactions.
This
review
aims
to
provide
complete
survey
progress
achieved
over
this
latter
period.
The
first
part
focuses
on
use
chiral
organocatalysts,
these
include
catalysts
covalently
linked
substrate
those
that
interact
with
by
weaker
interactions
like
hydrogen
bonds.
second
is
devoted
transition-metal
redox
catalysis
which
organized
according
increasing
atomic
number
first-row
transition
metals
(Ti,
Cr,
Fe,
Mn,
Co,
Ni,
Cu).
Bioinspired
manganese-
iron-mediated
hydroxylations
oxidations
are
also
discussed.
A
specific
section
dedicated
reactivity
Ru,
Rh,
Ir
complexes
as
Lewis
acids
special
focus
at
metal.
Absorption
photons
result
different
events
such
energy
transfer,
single-electron
hydrogen-atom
transfer
facilitating
formation
radicals.
Organocatalysis
has
been
successfully
combined
photocatalysts,
opened
pathways
enlarging
precursors
available.
merger
photocatalysis
organo-
or
metalla-photocatalysis
brought
novelty
allowed
discovery
large
original
transformations.
enzyme-catalyzed
reactions
involving
intermediates
largely
benefit
visible-light
irradiation
included
review.
provides
comprehensive
inventory
goal
detailing
reaction
mechanisms
involved
transformations
any
nonspecialist
could
find
their
own
creativity
invent
yet
unknown
applications.
ACS Catalysis,
Journal Year:
2016,
Volume and Issue:
6(12), P. 8004 - 8008
Published: Oct. 27, 2016
A
Ni/photoredox
dual
catalytic
cross-coupling
is
disclosed
in
which
a
diverse
range
of
(hetero)aryl
bromides
are
used
as
electrophiles,
with
1,4-dihydropyridines
serving
precursors
to
Csp3-centered
alkyl
radical
coupling
partners.
The
reported
method
characterized
by
its
extremely
mild
reaction
conditions,
enabling
access
underexplored
cores.
Journal of the American Chemical Society,
Journal Year:
2018,
Volume and Issue:
140(7), P. 2438 - 2441
Published: Feb. 6, 2018
The
emergence
of
new
catalytic
strategies
that
cleverly
adopt
concepts
and
techniques
frequently
used
in
areas
such
as
photochemistry
electrochemistry
has
yielded
a
myriad
organic
reactions
would
be
challenging
to
achieve
using
orthodox
methods.
Herein,
we
discuss
the
strategic
use
anodically
coupled
electrolysis,
an
electrochemical
process
combines
two
parallel
oxidative
events,
complementary
approach
existing
methods
for
redox
transformations.
Specifically,
demonstrate
electrolysis
regio-
chemoselective
chlorotrifluoromethylation
alkenes.
