Enantioseparation and enantiorecognition DOI Open Access
Ravi Bhushan

Biomedical Chromatography, Journal Year: 2024, Volume and Issue: 39(1)

Published: Nov. 10, 2024

Biomedical ChromatographyVolume 0, Issue 0 e6041 EDITORIAL Enantioseparation and enantiorecognition Ravi Bhushan, Corresponding Author Bhushan [email protected] orcid.org/0000-0001-5098-9759 Department of Chemistry, Indian Institute Technology Roorkee, India Correspondence Roorkee 247667, India. Email: protected]; protected]Search for more papers by this author First published: 10 November 2024 https://doi.org/10.1002/bmc.6041Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare text full-text accessPlease review our Terms Conditions Use check box below share version article.I have read accept Wiley Online Library UseShareable LinkUse link a article with your friends colleagues. Learn more.Copy URL Share linkShare onEmailFacebookxLinkedInRedditWechat REFERENCES R. (2023). Enantioselective chemoselective optical detection chiral organic compounds without resorting chromatography. Chemistry-An Asian Journal, 18(24), e202300825. https://doi.org/10.1002/asia.202300825 10.1002/asia.202300825 CASPubMedGoogle Scholar (2024). Sustainable solutions direct TLC enantioseparation in-home, thought-out, prepared/modified stationary phases. Chromatography, e6000. https://doi.org/10.1002/bmc.6000 10.1002/bmc.6000 PubMedGoogle Han, Y., Kou, M., Zhang, H., Qiu, & Shi, Y.-P. (2025). Chiral fluorescent carbon dots tyrosine enantiomers: Discrimination, mechanism cell imaging. Sensors Actuators B: Chemical, 422, 136677. https://doi.org/10.1016/j.snb.2024.136677 10.1016/j.snb.2024.136677 CASGoogle Liu, J.-Z., Chai, X.-Y., Huang, J., Li, S., C. Ling, Cao, Q.-E., Z. assembly perovskite nanocrystals: Sensitive discrimination amino acid enantiomers. Analytical 96(10), 4282–4289. https://doi.org/10.1021/acs.analchem.3c05941 10.1021/acs.analchem.3c05941 Malik, P., (2018). Development bovine serum albumin bonded silica as phase its application in quantitative enantiomeric resolution. ACS Organic Process Research Development, 22(7), 789–795. https://doi.org/10.1021/acs.oprd.8b00065 10.1021/acs.oprd.8b00065 CASWeb Science®Google Martens, (2014). Purification mixtures enantioselective synthesis: Overlooked errors scientific basis separation achiral environment. Helvetica Chimica Acta, 97, 161–187. https://doi.org/10.1002/ijch.201600086 10.1002/hlca.201300392 Wang, X., Xiang, Qi, C., Chen, Su, Yang, J.-C., Tian, Feng, H.-T., Tang, B. (2022). Visualization resolution AIEgens. Nano, 16(5), 8223–8232. https://doi.org/10.1021/acsnano.2c01981 10.1021/acsnano.2c01981 CASPubMedWeb J.-K., Xiong, L.-X., B.-J., Xie, S.-M., J.-H., Yuan, L.-M. Preparation novel phases based on porous cage thiol-ene click chemistry HPLC. 94, 4961–4969. https://doi.org/10.1021/acs.analchem.1c03626 10.1021/acs.analchem.1c03626 Z., W., Lai, Fu, Dong, Duan, A., Hou, L.-M., Cui, Y. Cyclodextrin incorporation into covalent frameworks enables extensive liquid gas chromatographic enantioseparations. Journal American Chemical Society, 145(34), 18956–18967. https://doi.org/10.1021/jacs.3c05973 10.1021/jacs.3c05973 Volume0, Issue0e6041 ReferencesRelatedInformation

Language: Английский

Fluorescence and Circular Dichroism Dual-Mode Probe for Chiral Recognition of Tyrosine and Its Applications in Bioimaging DOI
Foroozan Feizi, Mojtaba Shamsipur,

Mohamad-Bagher Gholivand

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(36), P. 48058 - 48072

Published: Sept. 2, 2024

Chiral amino acids (AAs) are essential in metabolism and understanding physiological processes, they could be used as biomarkers for the diagnosis of different diseases. In this study, chiral Cdots@Van were prepared by postmodifying an achiral Cdots core with vancomycin recognizing determining enantiomeric excess (ee) tyrosine (Tyr) enantiomers. The fluorescence response is based on "on–off" strategy, quenching percentages d- l-tyrosine. Interestingly, circular dichroism (CD) spectrum responded to only one form Tyr enantiomer, specifically d-Tyr, remained nearly unchanged upon addition l-Tyr. Quantum mechanical (QM) calculations excellent agreement experimental results, confirming stronger binding affinity d-Tyr compared We further investigated recognition ability interconnected particles, which was synthesized using EDC/NHS coupling reaction between molecules without a core. Surprisingly, unlike free molecules, displayed CD spectroscopy, similar what observed Cdots@Van. Crucially, probe has been successfully utilized cell imaging applications.

Language: Английский

Citations

3
Chiral Lead Halide Perovskites in Action: Unlocking Enantiomer Separation Puzzle DOI Open Access
Pallavi Singh,

Rudra Mukherjee,

Anil Kumar

et al.

Biomedical Chromatography, Journal Year: 2025, Volume and Issue: 39(3)

Published: Feb. 7, 2025

Effective enantiomer separation is vital in many important sectors like pharmaceuticals, agrochemicals, food safety, and biomedical imaging, yet conventional methods are costly, slow, chemical intensive. This has sparked interest exploring novel materials chiral lead halide perovskite nanocrystals to address these challenges. newly emerging material combines the superior properties of traditional perovskites with unique attributes chirality, resulting distinct optoelectronic behaviors. perspective provides a discussion on future research opportunities usage LHP NCs for enantiomeric recognition separation. LHPs exhibit extraordinary photophysical properties, easier surface functionalization, range bonding interactions, high area volume ratio that can be used detecting enantiomers. To best our knowledge, use discrimination enantiomers been scarcely reported, presenting opportunity explore their potential

Language: Английский

Citations

0
A lead-free red fluorescent cesium rubidium europium perovskite for the detection of tetracycline by antenna effect DOI

Cheng‐Kang Yang,

Hai-Chi Zhang,

Jing Cheng

et al.

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Journal Year: 2025, Volume and Issue: unknown, P. 126128 - 126128

Published: March 1, 2025

Language: Английский

Citations

0
Aggregation-disaggregation regulated fluorescence resonance energy transfer of perovskite nanocrystals for the detection of ascorbic acid DOI

Qian-Wei Yin,

Ji Wang, Jinzhou Liu

et al.

Microchemical Journal, Journal Year: 2024, Volume and Issue: unknown, P. 111725 - 111725

Published: Sept. 1, 2024

Language: Английский

Citations

2
High-efficiency detection of primary amine-based chiral molecules by a facile aldimine condensation reaction DOI Creative Commons
Yang Yu,

Aiyan Shi,

Tongtong Wang

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(43), P. 31820 - 31824

Published: Jan. 1, 2024

A pH-sensitive fluorane dye was developed to be reacted with chiral molecules through an aldimine condensation reaction. After the mixing operation, features of detected could facilely determined by spectral analysis.

Language: Английский

Citations

0
Enantioseparation and enantiorecognition DOI Open Access
Ravi Bhushan

Biomedical Chromatography, Journal Year: 2024, Volume and Issue: 39(1)

Published: Nov. 10, 2024

Biomedical ChromatographyVolume 0, Issue 0 e6041 EDITORIAL Enantioseparation and enantiorecognition Ravi Bhushan, Corresponding Author Bhushan [email protected] orcid.org/0000-0001-5098-9759 Department of Chemistry, Indian Institute Technology Roorkee, India Correspondence Roorkee 247667, India. Email: protected]; protected]Search for more papers by this author First published: 10 November 2024 https://doi.org/10.1002/bmc.6041Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare text full-text accessPlease review our Terms Conditions Use check box below share version article.I have read accept Wiley Online Library UseShareable LinkUse link a article with your friends colleagues. Learn more.Copy URL Share linkShare onEmailFacebookxLinkedInRedditWechat REFERENCES R. (2023). Enantioselective chemoselective optical detection chiral organic compounds without resorting chromatography. Chemistry-An Asian Journal, 18(24), e202300825. https://doi.org/10.1002/asia.202300825 10.1002/asia.202300825 CASPubMedGoogle Scholar (2024). Sustainable solutions direct TLC enantioseparation in-home, thought-out, prepared/modified stationary phases. Chromatography, e6000. https://doi.org/10.1002/bmc.6000 10.1002/bmc.6000 PubMedGoogle Han, Y., Kou, M., Zhang, H., Qiu, & Shi, Y.-P. (2025). Chiral fluorescent carbon dots tyrosine enantiomers: Discrimination, mechanism cell imaging. Sensors Actuators B: Chemical, 422, 136677. https://doi.org/10.1016/j.snb.2024.136677 10.1016/j.snb.2024.136677 CASGoogle Liu, J.-Z., Chai, X.-Y., Huang, J., Li, S., C. Ling, Cao, Q.-E., Z. assembly perovskite nanocrystals: Sensitive discrimination amino acid enantiomers. Analytical 96(10), 4282–4289. https://doi.org/10.1021/acs.analchem.3c05941 10.1021/acs.analchem.3c05941 Malik, P., (2018). Development bovine serum albumin bonded silica as phase its application in quantitative enantiomeric resolution. ACS Organic Process Research Development, 22(7), 789–795. https://doi.org/10.1021/acs.oprd.8b00065 10.1021/acs.oprd.8b00065 CASWeb Science®Google Martens, (2014). Purification mixtures enantioselective synthesis: Overlooked errors scientific basis separation achiral environment. Helvetica Chimica Acta, 97, 161–187. https://doi.org/10.1002/ijch.201600086 10.1002/hlca.201300392 Wang, X., Xiang, Qi, C., Chen, Su, Yang, J.-C., Tian, Feng, H.-T., Tang, B. (2022). Visualization resolution AIEgens. Nano, 16(5), 8223–8232. https://doi.org/10.1021/acsnano.2c01981 10.1021/acsnano.2c01981 CASPubMedWeb J.-K., Xiong, L.-X., B.-J., Xie, S.-M., J.-H., Yuan, L.-M. Preparation novel phases based on porous cage thiol-ene click chemistry HPLC. 94, 4961–4969. https://doi.org/10.1021/acs.analchem.1c03626 10.1021/acs.analchem.1c03626 Z., W., Lai, Fu, Dong, Duan, A., Hou, L.-M., Cui, Y. Cyclodextrin incorporation into covalent frameworks enables extensive liquid gas chromatographic enantioseparations. Journal American Chemical Society, 145(34), 18956–18967. https://doi.org/10.1021/jacs.3c05973 10.1021/jacs.3c05973 Volume0, Issue0e6041 ReferencesRelatedInformation

Language: Английский

Citations

0