Silver(I) complexation with N-donor heterocyclic ligands in the presence of boron cluster anions: Synthesis and coordination features

Polyhedron, Journal Year: 2024, Volume and Issue: 263, P. 117209 - 117209

Published: Aug. 30, 2024

Language: Английский

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Coordination ability of the dodecachloro-closo-dodecaborate anion [B12Cl12]2– in silver(I) complexation in the presence of S-donor ligands

Inorganica Chimica Acta, Journal Year: 2024, Volume and Issue: 573, P. 122344 - 122344

Published: Aug. 30, 2024

Language: Английский

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Silver(I) Complexation with N-Donor Heterocyclic Ligands in the Presence of Boron Cluster Anions: Synthesis and Coordination Features

Published: Jan. 1, 2024

Silver(I) complexation with boron cluster anions [BnHn]2– (n = 10, 12) and chelating 1-substituted-2-aldiminebenzimidazoles 1-(1-methylbenzimidazol-2-yl)-N-phenylmetanimine (L1) 1-(1-benzylbenzimidazol-2-yl)-N-cyclohexylmethanimine (L2) in systems AgNO3 / L {Ag2[BnHn]}m L, as well azaheterocyclic ligands 2,2ʹ-bipyridyl (bipy) or 1,10-phenanthroline (phen) the system has been first studied. The effect of organic ligand on composition structures resulting compounds shown. As a result, binuclear complexes [Ag2L2[μ‑BnHn]] bridging various combinations coordination modes (edge-edge edge-face for [B10H10]2– anion, edge–atom nontrivial asymmetric [B12H12]2– anion) have synthesized structurally characterized benzimidazole derivatives L1 L2. When using bipy phen ligands, polymeric {Ag2L[B10H10]}m {Ag2L2[μ-B12H12]}m obtained.

Language: Английский

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Silver(I) Complexes with Azaheterocyclic Ligands (bipy, phen) and Perchloro-closo-Borate Anions [BnCln]2– (n = 10, 12)

Russian Journal of Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 30, 2024

Language: Английский

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