Соли органических кислот как восстановители в контролируемой радикальной полимеризации с переносом атома DOI
Ivan D. Grishin,

О. С. Гуляева,

Ю. А. Кузнецова

et al.

Высокомолекулярные соединения С, Journal Year: 2024, Volume and Issue: 66(1), P. 74 - 81

Published: Nov. 11, 2024

Language: Русский

The Future of Free Radical Polymerizations DOI Creative Commons
Shiyong Liu

Chemistry of Materials, Journal Year: 2024, Volume and Issue: 36(4), P. 1779 - 1780

Published: Feb. 27, 2024

ADVERTISEMENT RETURN TO ISSUEPREVEditorialNEXTThe Future of Free Radical PolymerizationsShiyong LiuShiyong LiuSchool Chemistry and Materials Science, Key Laboratory Precision Intelligent Chemistry, University Science Technology China, Hefei, Anhui Province 230026, ChinaMore by Shiyong Liuhttps://orcid.org/0000-0002-9789-6282Cite this: Chem. Mater. 2024, 36, 4, 1779–1780Publication Date (Web):February 27, 2024Publication History Received2 February 2024Published online27 inissue 27 2024https://doi.org/10.1021/acs.chemmater.4c00312Copyright © 2024 American Chemical Society. This publication is available under these Terms Use. Request reuse permissions free to access through this site. Learn MoreArticle Views1088Altmetric-Citations-LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum full text article downloads since November 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated reflect usage leading up last few days.Citations number other articles citing article, calculated Crossref daily. Find more information about citation counts.The Altmetric Attention Score a quantitative measure attention that research has received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence for given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail (822 KB) Get e-AlertscloseSUBJECTS:Hydrogels,Materials,Monomers,Radical polymerization,RAFT polymerization e-Alerts

Language: Английский

Citations

11

Polymers as Efficient Non-Viral Gene Delivery Vectors: The Role of the Chemical and Physical Architecture of Macromolecules DOI Open Access
Majad Khan

Polymers, Journal Year: 2024, Volume and Issue: 16(18), P. 2629 - 2629

Published: Sept. 18, 2024

Gene therapy is the technique of inserting foreign genetic elements into host cells to achieve a therapeutic effect. Although gene was initially formulated as potential remedy for specific problems, it currently offers solutions many diseases with varying inheritance patterns and acquired diseases. There are two major groups vectors therapy: viral vector non-viral therapy. This review examines role macromolecule's chemical physical architecture in delivery, including their design synthesis. Polymers can boost circulation, improve control cargo release through various methods. The prominent examples discussed include poly-L-lysine, polyethyleneimine, comb polymers, brush star well hydrogels natural polymers modifications. While significant progress has been made, challenges still exist stabilization, targeting specificity, cellular uptake. Overcoming cytotoxicity, improving delivery efficiency, utilizing hybrid systems vital factors prospects. comprehensive provides an illuminating overview field, guiding way toward innovative non-viral-based solutions.

Language: Английский

Citations

11

Advances in the textile industry through surface-initiated reversible deactivation radical polymerization: Exploring the latest advances, opportunities, and future directions in precise tailoring textile properties by well-defined polymers DOI
Katarzyna Kisiel, Izabela Zaborniak, Paweł Chmielarz

et al.

Polymer, Journal Year: 2024, Volume and Issue: 306, P. 127206 - 127206

Published: May 28, 2024

Language: Английский

Citations

4

Tailoring polymer architectures to drive molecular sieving in protein-polymer hybrids DOI Creative Commons
Kriti Kapil, Hironobu Murata, Lucca Trachsel

et al.

Sustainable Chemistry and Pharmacy, Journal Year: 2025, Volume and Issue: 45, P. 101988 - 101988

Published: March 14, 2025

Language: Английский

Citations

0

Smart Poly(N-isopropylacrylamide)-Based Hydrogels: A Tour D’horizon of Biomedical Applications DOI Creative Commons

Soumya Narayana,

B.H. Jaswanth Gowda, Umme Hani

et al.

Gels, Journal Year: 2025, Volume and Issue: 11(3), P. 207 - 207

Published: March 15, 2025

Hydrogels are innovative materials characterized by a water-swollen, crosslinked polymeric network capable of retaining substantial amounts water while maintaining structural integrity. Their unique ability to swell or contract in response environmental stimuli makes them integral biomedical applications, including drug delivery, tissue engineering, and wound healing. Among these, “smart” hydrogels, sensitive such as pH, temperature, light, showcase reversible transitions between liquid semi-solid states. Thermoresponsive exemplified poly(N-isopropylacrylamide) (PNIPAM), particularly notable for their sensitivity temperature changes, transitioning near lower critical solution (LCST) approximately 32 °C water. Structurally, PNIPAM-based hydrogels (PNIPAM-HYDs) chemically versatile, allowing modifications that enhance biocompatibility functional adaptability. These properties enable application diverse therapeutic areas cancer therapy, phototherapy, healing, engineering. In this review, the behavior smart PNIPAM explored, with an emphasis on synthesis methods brief note biocompatibility. Furthermore, PNIPAM-HYDs detailed, along applications skin conditions, ocular diseases, etc. Various delivery routes patents highlighting advancements also examined. Finally, future prospects remain promising, ongoing research focused enhancing stability, responsiveness, clinical applicability. continued development is expected revolutionize technologies, paving way more efficient targeted solutions.

Language: Английский

Citations

0

Tuning the Thermal Properties of Polymethacrylates With Bicyclobutane Monomers DOI Creative Commons
Sewon Oh, Erin E. Stache

Journal of Polymer Science, Journal Year: 2025, Volume and Issue: unknown

Published: April 16, 2025

ABSTRACT Developing novel yet recyclable plastics is necessary as society advances and increases reliance on materials. Using new classes of monomers enables the synthesis unprecedented polymers for applications. Here, we report copolymerization with bicyclo[1.1.0]butane to make strained backbone units analyze thermal property changes based % incorporation monomers. We discover that even low (5%–20%) methyl bicyclobutane‐1‐carboxylate (MBC) poly(methyl methacrylate) (PMMA) degradation temperature while decreasing glass transition temperature. Efficient depolymerization achieved copolymers 20% or fewer MBC under photothermal conversion. Other comonomers (2‐methoxyethyl methacrylate oligo(ethylene glycol) monomethyl ethyl are also copolymerized MBC, assess in their properties, including lower critical solution temperatures (LCSTs). Our work expands understanding how monomer plays a role copolymerization, characteristics, copolymers.

Language: Английский

Citations

0

Heterogenous catalysis for oxygen tolerant photoredox atom transfer radical polymerization and small-molecule dehalogenation DOI Creative Commons
Kriti Kapil, Mingkang Sun, Ting‐Chih Lin

et al.

Polymer Chemistry, Journal Year: 2024, Volume and Issue: 15(41), P. 4264 - 4280

Published: Jan. 1, 2024

Heterogeneous photocatalysts (PCs) have garnered attention for their sustainability and cost-effectiveness.

Language: Английский

Citations

1

Salts of Organic Acids as Reducing Agents in Atom Transfer Controlled Radical Polymerization DOI
Ivan D. Grishin,

O. S. Gulyaeva,

Yu. A. Kuznetsova

et al.

Polymer Science Series B, Journal Year: 2024, Volume and Issue: 66(2), P. 237 - 244

Published: April 1, 2024

Language: Английский

Citations

0

N-Carbazolyl π-Radical and Its Antiaromatic Nitrenium Ion: A Threshold Photoelectron Spectroscopic Study DOI Creative Commons
Mayank Saraswat, Adrian Portela‐Gonzalez, Enrique Mendez‐Vega

et al.

The Journal of Physical Chemistry A, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 26, 2024

Understanding the structure and properties of heterocyclic radicals their cations is crucial for elucidating reaction mechanisms as they serve versatile synthetic intermediates. In this work,

Language: Английский

Citations

0

Соли органических кислот как восстановители в контролируемой радикальной полимеризации с переносом атома DOI
Ivan D. Grishin,

О. С. Гуляева,

Ю. А. Кузнецова

et al.

Высокомолекулярные соединения С, Journal Year: 2024, Volume and Issue: 66(1), P. 74 - 81

Published: Nov. 11, 2024

Language: Русский

Citations

0